首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   10960篇
  免费   1341篇
  国内免费   946篇
化学   3784篇
晶体学   140篇
力学   1630篇
综合类   131篇
数学   1775篇
物理学   5787篇
  2024年   15篇
  2023年   103篇
  2022年   301篇
  2021年   319篇
  2020年   307篇
  2019年   244篇
  2018年   269篇
  2017年   372篇
  2016年   337篇
  2015年   327篇
  2014年   438篇
  2013年   985篇
  2012年   593篇
  2011年   748篇
  2010年   559篇
  2009年   621篇
  2008年   617篇
  2007年   671篇
  2006年   612篇
  2005年   516篇
  2004年   540篇
  2003年   483篇
  2002年   413篇
  2001年   324篇
  2000年   313篇
  1999年   259篇
  1998年   279篇
  1997年   254篇
  1996年   216篇
  1995年   160篇
  1994年   147篇
  1993年   118篇
  1992年   123篇
  1991年   80篇
  1990年   76篇
  1989年   62篇
  1988年   66篇
  1987年   41篇
  1986年   46篇
  1985年   55篇
  1984年   42篇
  1983年   18篇
  1982年   39篇
  1981年   21篇
  1980年   21篇
  1979年   28篇
  1978年   20篇
  1977年   9篇
  1976年   12篇
  1973年   10篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
51.
1IntroductionInthispaper,weconsidertheinitial-boundaryvalueproblem,where"o(x)isnon-negativesmoothfunctionsatisfying"o.(0)=0,"o.(1)=1'Whenconsideringtheblow-upofsolution,thefollowingproblemarisenaturally:Doesblow-upoccur?Howdoesthesolutionapproachtheblow-uptime'!Andwilersisthehotspotlocated(blow-upset)?WelookattheheatequationwithanonlillearboundaryconditiollHerefiisaboundeddomaininR",p>1isarealnumber.IthasbeenknownforalongtimethattheDroblelil(1.1).(1.2)withAL(~,0)--'no(x)doesnothaveaglobals…  相似文献   
52.
本文将布拉格方程推广应用到高聚物的结构研究中,得到了经不同剂量辐照的聚乙烯单晶的长周期,并辅以示差扫描量热法研究了γ-射线辐照对聚乙烯单晶结构的影响.  相似文献   
53.
We make a new proposal to describe the very low temperature susceptibility of the doped Haldane gap compound Y2BaNi1-xZnxO5. We propose a new mean field model relevant for this compound. The ground state of this mean field model is unconventional because antiferromagnetism coexists with random dimers. We present new susceptibility experiments at very low temperature. We obtain a Curie-Weiss susceptibility χ( T ) ∼ C /(Θ + T ) as expected for antiferromagnetic correlations but we do not obtain a direct signature of antiferromagnetic long range order. We explain how to obtain the “impurity” susceptibility ( T ) by subtracting the Haldane gap contribution to the total susceptibility. In the temperature range [1 K, 300 K] the experimental data are well fitted by T ( T ) = C imp 1 + T imp / T . In the temperature range [100 mK, 1 K] the experimental data are well fitted by T ( T ) = A ln( T / T c ), where T c increases with x. This fit suggests the existence of a finite Néel temperature which is however too small to be probed directly in our experiments. We also obtain a maximum in the temperature dependence of the ac-susceptibility ( T ) which suggests the existence of antiferromagnetic correlations at very low temperature. Received 17 July 2001  相似文献   
54.
A new and rather trivial model is suggested with mechanism that implies simultaneous violation of the zeroth and the second laws of thermodynamics. Mathematically rigorous quantum theory reduces to a trivial application of the Golden rule formula. It yields exciton on-energy-shell diffusion caused by bath-nonassisted excitation hopping between tails of different exciton site levels ε1 < ε2 broadened by bath-assisted finite life-time effects. The elastic character of the hopping implies 1 ↔ 2-symmetric transfer rate W. Thus the net diffusion exciton flow W(P 1 - P 2) and also, as argued, the net energy flow are possible due to different near-to-equilibrium exciton populations P 1 > P 2. As the sites are provided with two different baths, the population imbalance and the flows survive even for slightly different local bath temperatures T 1 < T 2 < T 1ε21. Thus spontaneous exciton and also energy flows against temperature step become possible, in contradiction with the Clausius form of the second law. Violations of both the laws disappear in the high-temperature, i.e. classical limit Received 16 May 2001 and Received in final form 20 September 2001  相似文献   
55.
An experimental study was performed to understand the nucleate boiling heat transfer of water–CuO nanoparticles suspension (nanofluids) at different operating pressures and different nanoparticle mass concentrations. The experimental apparatus is a miniature flat heat pipe (MFHP) with micro-grooved heat transfer surface of its evaporator. The experimental results indicate that the operating pressure has great influence on the nucleate boiling characteristics in the MFHP evaporator. The heat transfer coefficient and the critical heat flux (CHF) of nanofluids increase greatly with decreasing pressure as compared with those of water. The heat transfer coefficient and the CHF of nanofluids can increase about 25% and 50%, respectively, at atmospheric pressure whereas about 100% and 150%, respectively, at the pressure of 7.4 kPa. Nanoparticle mass concentration also has significant influence on the boiling heat transfer and the CHF of nanofluids. The heat transfer coefficient and the CHF increase slowly with the increase of the nanoparticle mass concentration at low concentration conditions. However, when the nanoparticle mass concentration is over 1.0 wt%, the CHF enhancement is close to a constant number and the heat transfer coefficient deteriorates. There exists an optimum mass concentration for nanofluids which corresponds to the maximum heat transfer enhancement and this optimum mass concentration is 1.0 wt% at all test pressures. The experiment confirmed that the boiling heat transfer characteristics of the MFHP evaporator can evidently be strengthened by using water/CuO nanofluids.  相似文献   
56.
The thermochemical transformation of electrostatically formed complexes of methyl orange (MO) with polycations containing primary amine groups such as ammonium salts afforded new polymers with a high concentration of covalently bound 4‐N,N‐dimethylaminoazobenzene groups in the side chain. Poly(allylamine hydrochloride) and poly(β‐aminoethylene acrylamide hydrochloride) were employed as support polycations for MO. The transformation of sulfonate–ammonium ion pairs into sulfonamide bonds, via heating at an elevated temperature, was supported by the polymer properties before and after the thermal treatment. The polymer structure changes were monitored with elemental analysis, Fourier transform infrared, 1H NMR, and ultraviolet–visible absorption spectroscopy, and thermogravimetric analysis. The spacer length between the backbone and azobenzene structures used as side chains strongly influenced the polymer properties before and after the heat‐induced reaction. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5898–5908, 2006  相似文献   
57.
A way of determining the flexibility of wood-pulp fibres is developed, which involves i) a precise measurement of the topology of single-fibres by using a confocal laser scanning microscope and ii) the measurement of the elastic modulus of the fibres by using a single-fibre fatigue cell. Reported in this paper are the initial results of tests carried out on black spruce fibres, which have been subjected to three different levels of mechanical refining energy, namely ∼1100, 2300, and 3500 kWh/t. It is found that the fibre flexibility rises significantly between the first and second energy levels, but it does not change to the same degree between the second and third ones. The described procedure of measuring the flexibility of fibres may be used to establish the appropriate refiner energy necessary for the production of a specific grade of paper. Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 42, No. 1, pp. 115–128, January–February, 2006.  相似文献   
58.
绕圆柱体自由表面磁流体流动和传热的研究   总被引:1,自引:0,他引:1  
本文对在不同雷诺数下,绕圆柱体的磁流体自由表面流动及传热进行了模拟,分析了磁场对绕流圆柱尾迹和涡分离的影响,获得了两种雷诺数下的电磁力密度、流场和温度场分布。结果表明,磁场不仅影响了流动的形态,而且对湍流有抑制作用,降低了自由表面的更新机制,从而减少了传热能力;在相同的Hartmann数下,相比低雷诺数下的流动换热情况,高雷诺数下的湍流不能被完全抑制,自由表面与尾迹的相互作用也较强,因而自由表面换热也较强。  相似文献   
59.
It is conceptually proposed that the total entropy of polymer solution is contributed from two distinct parts: the positional and the oomformational. The former can be represented analytically, while the latter can be simulated with the random self-avoiding walk model on the simple cubic lattice for multichain systems. The obtained results indicated that both the conformational entropy and the mixing heat are consistent with the scaling laws wry well.  相似文献   
60.
An evolutionary method for optimization of plate buckling resistance   总被引:9,自引:0,他引:9  
Optimization of plate buckling resistance is very complicated, because the in-plane stress resultants in the prebuckled state of a plate are functions of thickness distribution. This paper discusses the problem of finding the optimum thickness distribution of isotropic plate structures, with a given volume and layout, that would maximise the buckling load. A simple numerical method using the finite-element analysis is presented to obtain the optimum thickness distribution. Optimum designs of compression-loaded rectangular plates with different boundary conditions and plate aspect ratios are obtained by using the proposed method. Optimum designs from earlier studies and the methods of buckling analysis used to attain these results are discussed and compared with the designs from the proposed method. This paper also examines the reliability of the optimality criterion generally used for plate buckling optimization, which is based on the uniform strain energy density.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号