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991.
Dr. Kai Buckenmaier Prof. Dr. Klaus Scheffler Dr. Markus Plaumann Paul Fehling Prof. Dr. Johannes Bernarding Dr. Matthias Rudolph Dr. Christoph Back Prof. Dr. Dieter Koelle Prof. Dr. Reinhold Kleiner Prof. Dr. Jan-Bernd Hövener Dr. Andrey N. Pravdivtsev 《Chemphyschem》2019,20(21):2823-2829
The development of hyperpolarization technologies enabled several yet exotic NMR applications at low and ultra-low fields (ULF), where without hyperpolarization even the detection of a signal from analytes is a challenge. Herein, we present a method for the simultaneous excitation and observation of homo- and heteronuclear multiple quantum coherences (from zero up to the third-order), which give an additional degree of freedom for ULF NMR experiments, where the chemical shift variation is negligible. The approach is based on heteronuclear correlated spectroscopy (COSY); its combination with a phase-cycling scheme allows the selective observation of multiple quantum coherences of different orders. The nonequilibrium spin state and multiple spin orders are generated by signal amplification by reversible exchange (SABRE) and detected at ULF with a superconducting quantum interference device (SQUID)-based NMR system. 相似文献
992.
为了使科考数据的存储和管理适应未来科学考察动态化、多样化发展的需要,在全面分析多源科考数据特点的基础上,结合成熟的数据库管理系统SQL Server以及空间数据库引擎ArcSDE,对多源科考数据的存储组织结构和可视化管理进行了分析和研究,提出了一套多源科考数据管理方案.设计并实现了西南印度洋多金属硫化物科学考察数据管理系统,该系统主要由多源科考数据的统一存储管理和可视化空间操作等功能模块组成,具有良好的适应性和扩展性,可满足实际应用需求. 相似文献
993.
通过对2005~2015年长三角地区26个城市旅游发展效率的DEA测度, 再运用空间自相关及面板数据回归分析, 结果发现: (1)2005~2015年长三角地区城市旅游发展综合效率呈上升趋 势; (2)长三角地区城市旅游效率空间分异为规模效率主导型、纯技术效率主导型和规模技术双作用型, 城市旅游效率具有显著空间自相关性; (3)长三角旅游发展效率影响因素排序为政府宏观调控、经济发展水平及城市居民消费水平, 影响程度在浙、苏、皖具有差异性. 相似文献
994.
动态微粒场诊断用全息光路的设计与分析 总被引:1,自引:0,他引:1
本文分析了动态微粒场测试的特点,设计了一种适合于动态微粒场用脉冲激光全息诊断的全息光路,并从理论上进行了分析。使用这种全息光路记录的微粒场全息图,当用记录参考光,而不是它的共轭光照明再现时,就能获得微粒的实象,因而,使得参考光类型的选择更加灵活。同时,由于光路设计上还考虑了参物光之间的空间相干性的匹配,故降低了对激光器横模的要求。 相似文献
995.
The boundary value problem of the quark-gluon plasma kinetic equations is analyzed by using the derivative expansion method. The dispersion relation in the linear approximation indicates that there is no collisionless spatial damping, but it reflects that the nonlinear interaction between the eigenwaves in it is very important. By taking account of the nonlinear interactions of waves, the resonance condition between the secondary waves and the particles in quark-gluon plasma can be fulfilled which will result in the spatial damping. The nonlinear spatial collisionless damping rate for the longitudinal secondary color waves in the long wavelength limit has been calculated numerically. 相似文献
996.
Mean squared prediction error in the spatial linear model with estimated covariance parameters 总被引:4,自引:0,他引:4
The problem considered is that of predicting the value of a linear functional of a random field when the parameter vector of the covariance function (or generalized covariance function) is unknown. The customary predictor when is unknown, which we call the EBLUP, is obtained by substituting an estimator j for in the expression for the best linear unbiased predictor (BLUP). Similarly, the customary estimator of the mean squared prediction error (MSPE) of the EBLUP is obtained by substituting j for in the expression f for the BLUP's MSPE; we call this the EMSPE. In this article, the appropriateness of the EMSPE as an estimator of the EBLUP's MSPE is examined, and alternative estimators of the EBLUP's MSPE for use when the EMSPE is inappropriate are suggested. Several illustrative examples show that the performance of the EMSPE depends on the strength of spatial correlation; the EMSPE is at its best when the spatial correlation is strong.This research was partially supported by a University of Iowa Old Gold Fellowship (Zimmerman) and by the NSF under grant DMS-8703083 (Cressie). 相似文献
997.
Coherent transitions of charge carriers between the conduction and valence bands of a semiconductor medium are essential for the operation of a semiconductor laser. In this paper, we study how such interband coherence can be set up by an injection current and a coherent pump-field. In the absence of the pump-field, the injection current is the only source to establish the interband coherence in a semiconductor laser system. A laser threshold is obtained, which shows that a strongly coupled high-Q microcavity has a low threshold value. However, when an external pump-field serving as another mechanism to create the interband coherence is applied, the threshold value of the injection current can be lowered and it vanishes for sufficiently strong field. Besides, if the pump-field exceeds a threshold value, it is even possible to achieve a bistability in the inversionless region. Some fundamental macroscopic properties, including polarization, absorption and dispersion for the semicoductor system, are also obtained analytically. 相似文献
998.
The multivariate master equation for a general reaction-diffusion system is solved perturbatively in the stationary state, in a range of parameters in which a symmetry-breaking bifurcation and a Hopf bifurcation occur simultaneously. Thestochastic potential U is, in general, not analytic. However, in the vicinity of the bifurcation point and under precise conditions on the kinetic constants, it is possible to define a fourth-order expansion ofU around the bifurcating fixed point. Under these conditions, the domains of existence of different attractors, including spatiotemporal structures as well as the spatial correlations of the fluctuations around these attractors, are determined analytically. The role of fluctuations in the existence and stability of the various patterns is pointed out. 相似文献
999.
1000.