Efficient modification with flexible spacing coating for in situ reversible assembly of semirigid macroscopic objects through hierarchical metal coordination

Macroscopic supramolecular assembly plays a key role to bridge the fundamental researches on molecular recognition to the potential applications as supramolecular materials. However, the challenge remains to promote the research from soft hydrogel system to semirigid objects or building blocks. Herein, the concept of flexible spacing coating was employed to modify the model polydimethylsiloxane building blocks, and reversible macroscopic assembly was successfully realized through introducing highly directional, dynamic, and reversible coordinate interactions as driving forces. The driving force for the macroscopic assembly was confirmed by introducing highly competitive ethylene diamine tetra acetic acid solution as an orthodox system to disassemble the assembled blocks. Moreover, the coordinate interaction was further understood through unique in situ measurements of binding forces between building blocks during assembly process. This work of macroscopic supramolecular assembly provides an in situ visible platform, which is significant to clarify the highly fascinating and facile coordinate interactions on the macroscopic assembly behavior.     

宽孔距爆破破碎机理的研究

通过分析爆破试验结果,建立了以成梁假设为基础的宽孔距爆破破碎机理模型。提出了以孔间裂缝扩展速度Ｖｐ和裂缝扩宽速度Ｖｓ表达的岩石破坏准则,并通过实验进行了验证。     

765THE CUT-AND-TRY METHOD IN DETERMINING THE SATURATE SPACING OF TRANSVERSE CRACKS OF COMPOSITE LAMINATES

I.IntroductionTransversecracksfirstoccurinthe9o"plyandspreadalongtheentirewidth.Withstaticorcyclicloadadding,thenumberoftransversecracksinthepliescontinuous1yincreases,lastinguntilthedistributionofcracksreachesasaturatestate.Theoccurrenceoftransversecrack…     

Ultra low head–disk spacing measurement using dual beam polarisation interferometry

In this paper, a dual-beam normal incidence polarisation interferometer is proposed to measure the flying height or head–disk spacing. Using this interferometer, the head–disk spacing can be measured both in magnetic real disk condition and in glass disk condition. It has the advantage of both the currently popular intensity interferometry method and the oblique incidence polarisation interferometry method. With this polarisation interferometer, not only the flying height can be measured down to contact without losing accuracy, but the pitch and roll of the head-slider can also be detected dynamically. The optical parameters of the head-slider can also be determined. Design details and experimental study are presented.     

4f结构间距失调对达曼类滤波器输出脉冲特性的影响

 研究了4f结构的飞秒脉冲时空变换整形装置在各元件间距不等的情况下对脉冲输出特性的影响,理论分析了间距失调效应对等间距和不等间距达曼光栅滤波器的脉冲输出特性的影响。结果表明4f结构间距失调后无论是能量还是平均度都不如等间距高,中心脉冲能量变小,其它级次脉冲生出更多旁瓣;失调量越小,输出的脉冲质量越高,对于f为12 cm的装置,当失调量小于1 cm时,对输出脉冲影响较小。     

Temperature‐dependent location of a weakly segregated block copolymer in binary blends of block copolymers

The phase behaviors of binary blends of poly(styrene‐b‐butadiene) block copolymers were investigated by a small‐angle X‐ray scattering technique. The blends were composed of weakly segregated one in a random micellar phase and the other in a cylindrical phase with similar molecular weights and complementary volume fractions. Morphologies, domain spacings, and order–disorder transition temperatures of the blends indicated that the junctions of the constituent block copolymers share the interface at low temperatures. The domain spacing decreased as temperature increased in a blend with a small amount of the weakly segregated block copolymer. In the cases of the blends with a large amount of the weakly segregated constituent, domain spacing increased with increasing temperature. These results implied that some of the weakly segregated block copolymer moved from the interface to one microdomain at higher temperatures. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014 , 52, 470–476     

磷钨酸插层MgAl水滑石层间距的调变及催化酯化脱酸性能

通过改变离子交换温度和时间合成了具有不同层间距的磷钨酸(H_3PW_(12)O_(40),HPW)插层MgAl水滑石(LDHs),采用XRD、FT-IR、Raman、~(31)P MAS NMR、ICP-AES和Hammett指示剂-正丁胺滴定法等表征其性质,并研究其对模型原油的催化酯化脱酸性能。高的离子交换温度有利于形成较大的层间距(d_(003)约1.46 nm),较长的交换时间有利于形成较小的层间距(d_(003)约1.05 nm)。不同的层间距源自HPW在层间不同的存在形式,P_2W_(18)O_(62)~(6-)以C_2轴倾斜于层板和PW_(11)O_(39)~(7-)以C_2轴垂直于层板的方式排列于层间时,形成d_(003)约1.46 nm的层间距;PW_(12)O_(40)~(3-)与层板发生嫁接,并以C_2轴垂直于层板的方向排列于层间时,形成d_(003)约1.05 nm的层间距。层间P_2W_(18)O_(62)~(6-)和PW_(11)O_(39)~(7-)能产生更高比例的中强酸中心,同时大的层间距有利于反应物扩散进入层间与酸中心接触,能够提高LDHs的催化酯化脱酸性能。     

简并谱的涨落统计特征分析

通过引入权重的方式,使简并谱的积累函数形式上连续递增,并用带权重的多元线性拟合提取涨落谱,由此建立一套适用于分析简并谱的NNS分布、谱刚度、能谱分维函数等涨落统计特征的方法,并具体分析了H2O、NH3及CH4分子的振动能谱进行涨落统计特征分析:发现它们的规则谱和约化非简并谱的涨落统计特征均已非Poigson化;而且约化非简并谱的非Poisson化程度较规则谱明显,即前者的能级斥力较后者大;此外,随着简并度的增加,H2O、NH3、CH4的涨落统计特征由非Poisson型向近Poisson型过渡.     

Phase behaviour and structural properties of two members of biphenylyl benzoate chiral mesogenic series

ABSTRACT

Phase behaviour and structural properties of two members of biphenylyl benzoate chiral mesogenic series (2F3R and 3F3R) have been investigated. While both the compounds exhibit SmC* phase over a wide temperature range, 2F3R forms orthogonal SmA* from tilted SmC* on heating but 3F3R melts directly to the isotropic phase. The SmA* phase of 2F3R is found to have de vries characteristics with small effective layer contraction. Both the samples on cooling form hexagonal SmF* phase below SmC* phase. On further cooling soft crystal like hexagonal SmJ* phase is formed in 2F3R, undergoing a change in the tilt direction, but in 3F3R, SmG* phase is formed without any change in the tilt direction. A coexistence phase of (SmC*+SmF*) is also observed in a certain temperature range. Slight differences in the dipole moment and molecular conformation of the two molecules give rise to a subtle change in the intermolecular interaction and play an important role in the appearance of different phases in the two compounds. Cell parameters of SmF*, SmG*, SmJ* phases have also been determined. Layer spacings, tilt angles, average intermolecular spacings and correlation lengths have been measured. How some of these properties compare with other members of the series has been discussed.     

不同形状孔阵屏蔽效应的分析

 屏蔽效应的研究对于防御电磁干扰，保证电子系统的正常工作是非常重要的。计算了屏蔽腔上开有不同形状的孔阵时对屏蔽效应的影响，分析比较了各种不同孔间距对屏蔽效应的影响。计算结果表明，圆形孔阵的穿透系数最小，方形孔阵次之，蜂巢形孔阵较大，但频谱分布基本一致。而对于哑铃形孔阵，由于孔面形状差异较大，孔面处磁流分布变化也较大，不仅穿透系数比前三者都大，而且高频时穿透系数的频率分布也发生较大改变。另外，随着孔阵中孔间距变大，孔之间的互耦减弱，耦合进屏蔽腔内的场强也变小。