多量子阱激光二极管质子辐射效应及其退火特性

研究5和2 MeV质子对法布里-珀罗（FP）腔结构及分布反馈（DFB）结构的多量子阱激光二极管的辐射效应,结果显示：在5×1012～5×1013 cm-2质子注量范围内,随着注量的增大,激光二极管阈值电流逐渐增大,电流-电压特性的低压区电流渐渐增大。由60Coγ总剂量实验结果推断:质子对实验器件的损伤源于质子位移效应。采用Trim程序的模拟结果表明：在2 MeV质子射程以内,2 MeV质子要比5 MeV质子产生的空位数多。这使得相同辐照注量下,2 MeV质子要比5 MeV质子导致的阈值电流增大更多,损伤更为严重。激光二极管辐射损伤存在着正向偏置退火效应,FP和DFB结构的二极管具有相似的加电退火规律,均可拟合成指数衰减形式,退火曲线可以分成退火常数不同的几段进行拟合。正向偏置退火效应使得辐照期间,处于加电状态的激光二极管比处于短路状态的激光二极管退化程度有所减弱。     

狭义相对论教学中的几个问题

本文讨论了相对论教学中几个方面的问题,包括常见例子的问题,洛伦兹变换的方便形式,同时相对性例子在另一参考系的讨论,长度测量在另一参考系看到的现象,时间延缓及运动参考系各点时间不同和光的多普勒效应的简单推导.通过不同过程在不同参考系中的讨论,掌握在运动系讨论问题的方法,以及同一过程在不同惯性系内的不同表现,而所有现象的测量结论在洛伦兹变换下保持不变.     

随机耦合模型在高功率微波效应中的应用

分析了微波混沌腔体系统中关键部位感应电压的统计问题,介绍了随机耦合模型在高功率微波效应研究中的计算方法和应用,并以计算机机箱为实验系统,开展了电磁波耦合入计算机机箱腔体的电磁干扰问题研究,对其电路板上关键部位感应电压的统计计算和实验结果进行了比较,其结果基本一致。随机耦合模型在波混沌系统中感应电压的统计探讨为高功率微波效应、电磁兼容等研究提供了一种新的思路。     

Investigation of the Effect of Substituents on Electronic and Charge Transport Properties of Benzothiazole Derivatives

A series of new benzothiazole-derived donor–acceptor-based compounds (Comp1–4) were synthesized and characterized with the objective of tuning their multifunctional properties, i.e., charge transport, electronic, and optical. All the proposed structural formulations (Comp1–4) were commensurate using FTIR, ¹H NMR, ¹³C NMR, ESI-mass, UV–vis, and elemental analysis techniques. The effects of the electron-donating group (-CH₃) and electron-withdrawing group (-NO₂) on the optoelectronic and charge transfer properties were studied. The substituent effect on absorption was calculated at the TD-B3LYP/6-31+G** level in the gas and solvent phases. The effect of solvent polarity on the absorption spectra using various polar and nonpolar solvents, i.e., ethanol, acetone, DMF, and DMSO was investigated. Light was shed on the charge transport in benzothiazole compounds by calculating electron affinity, ionization potential, and reorganization energies. Furthermore, the synthesized compounds were used to prepare thin films on the FTO substrate to evaluate the charge carrier mobility and other related device parameters with the help of I-V characteristic measurements.     

空间硬X射线调制望远镜

用宇宙作为物理实验室,探索在地球上无法企及的条件下,例如极早期宇宙或黑洞视界附近强引力场中的物理规律,已成为新世纪物理学和天文学共同的前沿课题;空间天文观测是其中一个最重要的研究途径.自主研制和发放空间硬X射线调制望远镜(HXMT),实现中国空间天文卫星零的突破,是中国《“十一·五”空间科学发展规划》的目标之一. HXMT 将实现宽波段X射线 (1—250 keV) 巡天,其中在硬X射线波段具有世界最高灵敏度和空间分辨率,发现大批被尘埃遮挡的超大质量黑洞和未知类型天体,探测宇宙硬X射线背景辐射;HXMT还将通过对黑洞和其他高能天体宽波段X射线时变和能谱的观测,研究致密天体极端物理条件下的动力学和辐射过程. 基于成像技术创新提出HXMT项目迄今已有15年,能不能抓住技术创新所提供的科学机遇仍然是一个严重的挑战.     

磁绝缘稳态电路编码中等效电感和等效电容的计算

从层流模型出发,根据线电压和线电流,给出了磁绝缘稳态时传输线极间的电磁场分布的解析表达式。在此基础上,计算了考虑空间电子效应后处于磁绝缘稳态的传输线等效分布电感和电容,以改进磁绝缘稳态的电路单元模型。利用该方法,模拟计算了Z加速器的MITL-A在磁绝缘稳态时的等效分布电感和电容。结果表明,等效分布电容随空间电子效应的增强而变大,而等效分布电感随空间电子效应的增强而变小;且线电压越低,等效分布电感和电容随空间电子效应的增强变化越快。     

福柯论“医院空间”的政治权力运作

聚焦空间权力的“空间理论”是福柯政治哲学的重要组成部分,而对“医院空间”问题的探讨则集中体现出其政治哲学的独特性和现实性。然而,国内外学界对这一具有独特地理学思想维度的空间理论的研究还有待进一步的深入。在福柯看来,18世纪末,空间问题之所以成了医学的根本问题,是由于医学训诫和管治技术在医院空间内运作和医学对环境的持续干预,医院实现了从收容空间向医疗空间的转型,临床医学和疾病分类政治学随之诞生,人口健康也随之成为政治权力的根本目标。从医院空间、家庭空间到城市空间甚至人类空间,医学话语与医学权力的交织关系愈来愈复杂和拓展。世界成了医院,治理成了治疗。虽然福柯医学空间思想明确提醒我们警惕、防备进而反抗在医院空间乃至社会空间中运作的过度权力,并断然拒绝“社会矫形外科学”的权力运作,这是建设性的,但福柯所说“世界成了一个大疯人院”与其泛权力论一样夸大其辞。在当今社会的空间化、网格化治理中,只有各方政治力量达成动态平衡才是付出最小代价的合理治理。     

大气湍流对空间光耦合至单模光纤的影响

根据弱湍理论,考虑湍流强度闪烁、孔径平均效应、湍流波前畸变及耦合系统跟踪误差的影响,导出了空间光到单模光纤的平均耦合效率及耦合功率起伏方差模型。根据Hufnagel-Valley 5/7折射率结构模型,对下行连接及上行连接的平均耦合效率及耦合功率起伏进行了研究。仿真结果表明,对于下行连接,随着地面接收天线孔径的增大,相对功率起伏先是由于孔径平均效应而减小,而后由于湍流波前畸变的影响而逐渐增大;对于上行连接,可忽略湍流波前畸变及孔径平均效应的影响。     

A Molecular-Wide and Electron Density-Based Approach in Exploring Chemical Reactivity and Explicit Dimethyl Sulfoxide (DMSO) Solvent Molecule Effects in the Proline Catalyzed Aldol Reaction

Modelling of the proline (1) catalyzed aldol reaction (with acetone 2) in the presence of an explicit molecule of dimethyl sulfoxide (DMSO) (3) has showed that 3 is a major player in the aldol reaction as it plays a double role. Through strong interactions with 1 and acetone 2, it leads to a significant increase of energy barriers at transition states (TS) for the lowest energy conformer 1a of proline. Just the opposite holds for the higher energy conformer 1b. Both the ‘inhibitor’ and ‘catalyst’ mode of activity of DMSO eliminates 1a as a catalyst at the very beginning of the process and promotes the chemical reactivity, hence catalytic ability of 1b. Modelling using a Molecular-Wide and Electron Density-based concept of Chemical Bonding (MOWED-CB) and the Reaction Energy Profile–Fragment Attributed Molecular System Energy Change (REP-FAMSEC) protocol has shown that, due to strong intermolecular interactions, the HN-C-COOH (of 1), CO (of 2), and SO (of 3) fragments drive a chemical change throughout the catalytic reaction. We strongly advocate exploring the pre-organization of molecules from initially formed complexes, through local minima to the best structures suited for a catalytic process. In this regard, a unique combination of MOWED-CB with REP-FAMSEC provides an invaluable insight on the potential success of a catalytic process, or reaction mechanism in general. The protocol reported herein is suitable for explaining classical reaction energy profiles computed for many synthetic processes.     

Mechanism Study on Nanoparticle Negative Surface Charge Modification by Ascorbyl Palmitate and Its Improvement of Tumor Targeting Ability

Surface charge polarity and density influence the immune clearance and cellular uptake of intravenously administered lipid nanoparticles (LNPs), thus determining the efficiency of their delivery to the target. Here, we modified the surface charge with ascorbyl palmitate (AsP) used as a negatively charged lipid. AsP-PC-LNPs were prepared by dispersion and ultrasonication of AsP and phosphatidylcholine (PC) composite films at various ratios. AsP inserted into the PC film with its polar head outward. The pK_a for AsP was 4.34, and its ion form conferred the LNPs with negative surface charge. Zeta potentials were correlated with the amount and distribution of AsP on the LNPs surface. DSC, Raman and FTIR spectra, and molecular dynamics simulations disclosed that AsP distributed homogeneously in PC at 1–8% (w/w), and there were strong hydrogen bonds between the polar heads of AsP and PC (PO²⁻), which favored LNPs’ stability. But at AsP:PC > 8% (w/w), the excessive AsP changed the interaction modes between AsP and PC. The AsP–PC composite films became inhomogeneous, and their phase transition behaviors and Raman and FTIR spectra were altered. Our results clarified the mechanism of surface charge modification by AsP and provided a rational use of AsP as a charged lipid to modify LNP surface properties in targeted drug delivery systems. Furthermore, AsP–PC composites were used as phospholipid-based biological membranes to prepare paclitaxel-loaded LNPs, which had stable surface negative charge, better tumor targeting and tumor inhibitory effects.