火花源质谱法定量分析高纯氧化钬和氧化镥中痕量元素

本文采用相对灵敏度因子，研究了９９．９９９％－９９．９９９９％的Ｈｏ２Ｏ３和Ｌｕ２Ｏ３中４０余种杂质元素的火花源定量分析方法，讨论了谱线干扰。做了加入回收及生理性实验，大多数元素的相对标准偏差在３０％以内，检测下限为０．００ｘμｇ／ｇ。     

Determination of radiation power of the solar-simulated light source

Calorimetric method for the determination of radiation power of the solar-simulated light sources has been proposed. The application of the differential scanning calorimetry guarantees very high sensitivity (1 mW) of the measuring property, independent of the wavelength (within 300-1200 nm). The applied method yields reliable calibration curves of the radiation power vs. wavelength with good accuracy. This revised version was published online in July 2006 with corrections to the Cover Date.     

Electrocatalytic Processes in Lithium Power Sources

Most important electrocatalytic processes that occur in primary and secondary (rechargeable) lithium power sources are briefly considered.     

H nuclear magnetic resonance spectroscopy analysis for simultaneous determination of levodopa, carbidopa and methyldopa in human serum and pharmaceutical formulations

A method utilizing NMR spectroscopy has been developed to confirm the identity and quantity of levodopa, carbidopa and methyldopa in human serum and pharmaceutical preparations. The method is based on 500 MHz proton NMR spectra of individual catecholamine molecules. Qualitative and quantitative analyses are based on resonance characteristics of the functional groups present in their structures and the integral ratio of selected signals belonging to different compounds with respect to those of an internal standard, respectively. Experiments are performed to validate the quantitative NMR method, and the linearity and reproducibility of the proposed method are verified. The detection limit of the proposed method was estimated as 4.2, 1.7 and 1.6  μg ml⁻¹ for levodopa, carbidopa and methyldopa, respectively. The recovery studies performed on human serum samples ranged from about 82-96% with relative standard deviations of <4%. The method was also applied successfully to the determination of each active compound in real pharmaceutical samples, and compared with the results obtained by the reference methods. The method is rapid, precise, accurate, and suitable for routine analyses.     

气液双热源耦合换热器性能研究

设计了一种由管翅式换热器和套管式换热器耦合而成的气液双源耦合式换热器,该换热器可以实现一种介质同时与气态热源和液态热源进行同步耦合换热.对该换热器进行了详细的介绍,并对其耦合换热特性及该换热器在耦合热源热泵空调中应用时的制热工况进行了的性能测试.研究结果证明,使用该气液双热源耦合式换热器的耦合热源热泵空调系统,气液双热...     

一种高功率掺铒光纤超荧光光源

通过优化掺铒光纤各种参量,用一个980 nm激光二极管作抽运源,采用单程结构,在一根光纤后向获得功率高达31.74 mW(15.02 dBm)的C-波段ASE输出的同时,其前向得到了功率为10.14 mW(10.06 dBm)的L-波段ASE输出.通过简单连接组合可得到输出覆盖C＋L波段(1525~1620 nm)功率＞36 mW的掺铒光纤宽带光源.     

层状介质上时空展源瞬变电磁响应的计算方法研究

在瞬变电磁法的实际应用中,由于发射回线和发射波形的不规则性而导致其发射源成为时空展源. 展源效应的忽略会造成正反演和数据解释的差错,因此开展展源效应的研究对于瞬变电磁法的实际应用具有重要的意义. 对于空间展源,本文以磁偶极子的响应为基响应,应用有源空间的互易定理和第二类曲线积分,提出了一种可基于发射回线数值坐标求取任意形状发射回线响应的计算方法. 同时对于时间展源,以阶跃波形的响应为基响应,对阶跃响应的特性进行了分析,提出了一种对发射信号进行非均匀采样的高效时间域计算方法,解决了对数采样的基响应与高密度采样的发射波形之间进行常规卷积时所面临的时间与精度之间的矛盾. 通过对层状大地上展源响应的模拟仿真和对比验证显示了本文所提出方法的正确性. 最后本文考察了几种常见时空展源在常规近似前后响应的差别,并给出了相关结论. 关键词： 分层介质 展射电源 互易定理 非均匀采样     

On the calculation of group characters

It is known that characters of irreducible representations of finite Lie algebras can be obtained using the Weyl character formula including Weyl group summations which make actual calculations almost impossible except for a few Lie algebras of lower rank. By starting from the Weyl character formula, we show that these characters can be re-expressed without referring to Weyl group summations. Some useful technical points are given in detail for the instructive example of G₂ Lie algebra.     

Direct detection of explosives on solid surfaces by mass spectrometry with an ambient ion source based on dielectric barrier discharge

Trace amounts of explosives on solid surfaces were detected by mass spectrometry at ambient conditions with a new technique termed dielectric barrier discharge ionization (DBDI). By the needle-plate discharge mode, a plasma discharge with energetic electrons was generated, which could launch the desorption and ionization of the explosives from solid surfaces. Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), 2,4,6-trinitrotoluene (TNT), and pentaerythritol tetranitrate (PETN) were desorbed directly from the explosives-contaminated surface by DBDI, forming the typical anions of [TNT](-), [TNT - H](-), [RDX + NO(2)](-), [PETN + ONO(2)](-), and [RDX + ONO(2)](-). The ions were transferred into the MS instrument for analysis in the negative ion mode. The detection limit of present method was 10 pg for TNT (m/z 197, S/N 8 : 1), 0.1 ng for RDX (m/z 284, S/N 10 : 1), and 1 ng for PETN (m/z 260, S/N 12 : 1). The present method allowed the detection of trace explosives on various matrices, including paper, cloth, chemical fiber, glass, paints, and soil. A relative standard deviation of 5.57% was achieved by depositing 100 pg of TNT on these matrices. The analysis of A-5, a mixture of RDX and additives, has been carried out and the results were consistent with the reference values. The DBDI-MS method represents a simple and rapid way for the detection of explosives with high sensitivity and specificity, which is especially useful when they are present in trace amounts on ordinary environmental surfaces.     

基于两种光源的诱发态量子密钥分配性能分析

单光子的衰减特性及其易受干扰的缺点限制了纯单光子量子系统的传输码率及距离.弱相干光脉冲(WCP)光源和准单光子源(HSPS)则具有更高的实用价值.本文将这两种光源和诱发态方案相结合并采用Lütkenhaus和Gottesman-Lo- Lütkenhaus-Preskill (GLLP)两种数据后处理方法进行性能分析.仿真结果表明:HSPS在传输距离上要优于WCP,对应相同传输距离时系统量子误码率(QBER)要小些,但相对密钥生成率低. 关键词： 量子密钥分配 诱发态 WCP光源 HSPS光源