荧光法研究对-二甲氨甲基-杯[8]芳烃与二苯胺磺酸钠包结作用

用荧光法研究了水溶性对-二甲氨甲基-杯[8]芳烃与二苯胺磺酸钠的相互作用。发现当对-二甲氨甲基-杯[8]芳烃加入到二苯胺磺酸钠溶液时,二苯胺磺酸钠的荧光峰发生了明显的蓝移,荧光增强,可能的作用机理是二苯胺磺酸钠中的磺酸根与对-二甲氨甲基-杯[8]芳烃中带正电的氮原子之间有较强的静电作用,二苯胺磺酸钠进入了对-二甲氨甲基-杯[8]芳烃的疏水空腔。同时研究了几种有机溶剂对包结物的荧光强度的影响,初步探讨了其作用机理。     

Preparation and characterization of titania based nanowires

A new method for preparation of titania nanowires with diameter around 10 nm and length up to 2–3 μm is described. The precursor was prepared from sodium titanate by adding ethylene glycole (EG) and heating at temperature of 198°C for 6 h under reflux. The sodium titanate glycolate formed by this way aggregated into 1D nanostructures and was subsequently transformed into titania glycolate during a chemical treatment with 98% sulfuric acid. Titania nanowires with variable amount of anatase and rutile were prepared by heating to temperatures in the range 350–1000°C. The precursor as well as titania based samples were characterized by X-ray diffraction, Infrared spectroscopy, Scanning electron microscopy, High resolution transmission microscopy, Thermogravimetry, Differential thermal analysis, Evolved gas analysis and Emanation thermal analysis. The nitrogen adsorption/desorption was used for surface area and porosity determination. The photoactivity of the prepared titania samples was assessed by the photocatalytic decomposition of 4-chlorophenol in an aqueous slurry under UV irradiation of 365 nm wavelength.     

Adsorption of sodium ions and hydrated sodium ions on a hydrophobic graphite surface via cation-π interactions

Using density functional theory computation, we show that sodium ions and hydrated sodium ions can be strongly adsorbed onto a hydrophobic graphite surface via cation-π interactions. The key to this cation-π interaction is the coupling of the delocalized π states of graphite and the empty orbitals of sodium ions. This finding implies that the property of the graphite surface is extremely dependent on the existence of the ions on the surface, suggesting that the hydrophobic property of the graphite surface may be affected by the existence of the sodium ions.     

自适应光学中扩展信标波前探测的研究与实验

讨论了一种基于Hartmann Shack (H S)传感器的扩展信标相关波前探测方法。通过在传统H S探测光路的物平面上加入视场光阑消除了子孔径像斑的重叠问题 ,并利用一种快速相关算法计算各像斑的相对位移 ,进而得到各子孔径波前的相对斜率。光学实验研究证实了该相关波前探测方法能够较精确地测算出波前像差 ,从而使目前使用最多的H S传感器具有扩展信标波前探测能力     

Mechanical and corrosion resistance of hydrophilic sphene/titania composite coatings on titanium and deposition and release of cefazolin sodium/chitosan films

The mechanical and corrosion resistance of hydrophilic sphene/titania composite coatings on titanium formed by a hybid technique of microarc oxidation (MAO) and heat-treatment were investigated. The results indicated that the heat-treatment could improve the hardness, elastic modulus, elastic recovery and corrosion resistance of the MAO coatings, and reinforce the interface bonding between MAO coatings and titanium. A cefazolin sodium/chitosan drug film was prepared on the coating surfaces. The drug load procedures such as the addition of chitosan obviously increased the sustained-release ability of drug films. In addition, the increase of cefazolin sodium concentration could increase the accumulative release concentration of cefazolin sodium. The sustaining-release ability of drug films deposited on the MAO and heat-treated MAO coatings is similar. In the interior of drug film, the physical and chemical bonding reactions such as Coulombic interactions, van der Waals force and H-bonding etc. could be produced, through the chemical group interactions such as -OH and -NH₂ groups of chitosan with -CO of cefazolin sodium.     

Investigation of thermal evolution of nanodomain structures in nonlinear barium sodium niobate crystals

By the 90°elastic light scattering investigation and far field observation in the range of 20-800℃,the relation between behavior of light scattering anomalies and evolution of nanodomain structures in lattice of barium sodium niobate(Ba2NaNb5O15,BSN)crystal was clarified.The correlation between anomalies on the temperature curves of the elastic light scattering intensity and temperature transformations of nanodomains was studied by X-ray and electron microscope methods.Phase transition near 500℃ and movement in field of scattering light could be explained by appearance of a new incommensurate phase.     

Structure and Mechanical Properties of 50/50 NR/SBR Blend/Pristine Clay Nanocomposites

A blend/clay nanocomposites of 50/50 (wt%) NR/SBR was prepared via mixing the latex of a 50/50 NR/SBR blend with an aqueous clay dispersion and co‐coagulating the mixture. The structure of the nanocomposite was characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). Nanocomposites containing less than 10 phr clay showed a fully exfoliated structure. After increasing the clay content to 10 phr, both nonexfoliated (stacked layers) and exfoliated structures were observed in the nanocomposites. The results of mechanical tests showed that the nanocomposites presented better mechanical properties than clay‐free NR/SBR blend vulcanizate. Furthermore, tensile strength, tensile strain at break, and hardness (shore A) increased with increasing clay content, up to 6 phr, and then remained almost constant.     

基于SERS光谱的银溶胶溶液中腺嘌呤的定量分析

碱基是构成核酸的物质基础。碱基的含量分析对于生物体的生理活动及新陈代谢过程研究具有重要意义。本文利用表面增强拉曼散射(SERS)光谱技术研究了腺嘌呤在相对稳定的银溶胶溶液中的SERS光谱信号强度与浓度的定量关系。研究表明添加聚合物作为稳定剂的银溶胶具有良好的稳定性。进一步研究表明, 在1×10-4~ 1×10-3mol ·L-1的浓度范围内, 以吡啶作为内标, 分析物腺嘌呤与内标物特征谱峰强度之比与腺嘌呤的浓度之间呈现良好的线性关系。     

Untersuchungen von Mischvorgängen bei der Herstellung technischer Kohleprodukte unter Anwendung der Methode der radioaktiven Markierung

Es werden die Ergebnisse von Mischverfahren für Kohlepulver, Pech und andere Komponenten mitgeteilt, die unter Markierungen mit ²⁴Na-Benzoat im Laboratorium (Mischvolumen etwa 1 Liter) und im Betrieb (Mischvolumen etwa 100 Liter) durchgführt wurden. Die Experimente dienten dem Vergleich der Vergleich der Wirksamkeit verschiedener Mischmaschinen, der Ermittlung optimaler Mischzeiten und der Bestimmung des Verhaltens einzelner Komponenten beim Mischprozeβ. Dis mittels Szintillationszählung gewonnenen Meβwerte werden dabei mit einem Ergebnisdrucker registriert und mit Hilfa einer Rechenanlage mathematisch ausfewertet.     

Contributions to the Optimization of a Caprolactam Production Plant by Radiotracer Techniques

Residence time spectra and material distributions in an operating caprolactam production plant were measured by means of sodium 24, bromine 82 and technetium 99m. The results of the tracerexperiments contributed to an optimization of the plant.