全文获取类型
收费全文 | 4844篇 |
免费 | 705篇 |
国内免费 | 555篇 |
专业分类
化学 | 2727篇 |
晶体学 | 103篇 |
力学 | 555篇 |
综合类 | 61篇 |
数学 | 848篇 |
物理学 | 1810篇 |
出版年
2024年 | 5篇 |
2023年 | 42篇 |
2022年 | 112篇 |
2021年 | 168篇 |
2020年 | 152篇 |
2019年 | 140篇 |
2018年 | 125篇 |
2017年 | 204篇 |
2016年 | 242篇 |
2015年 | 202篇 |
2014年 | 239篇 |
2013年 | 438篇 |
2012年 | 267篇 |
2011年 | 278篇 |
2010年 | 230篇 |
2009年 | 296篇 |
2008年 | 339篇 |
2007年 | 303篇 |
2006年 | 303篇 |
2005年 | 255篇 |
2004年 | 230篇 |
2003年 | 207篇 |
2002年 | 179篇 |
2001年 | 151篇 |
2000年 | 172篇 |
1999年 | 113篇 |
1998年 | 115篇 |
1997年 | 103篇 |
1996年 | 85篇 |
1995年 | 76篇 |
1994年 | 65篇 |
1993年 | 44篇 |
1992年 | 25篇 |
1991年 | 25篇 |
1990年 | 21篇 |
1989年 | 17篇 |
1988年 | 16篇 |
1987年 | 15篇 |
1986年 | 15篇 |
1985年 | 19篇 |
1984年 | 13篇 |
1983年 | 7篇 |
1982年 | 13篇 |
1981年 | 6篇 |
1980年 | 5篇 |
1979年 | 9篇 |
1978年 | 8篇 |
1976年 | 3篇 |
1973年 | 4篇 |
1969年 | 1篇 |
排序方式: 共有6104条查询结果,搜索用时 546 毫秒
11.
We provide a rigorous derivation of an asymptotic formula for perturbations in the eigenvalues caused by the presence of a finite number of inhomogeneities of small diameter with conductivity different from the background conductivity. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
12.
Hana Macková Daniela Králová Daniel Horák 《Journal of polymer science. Part A, Polymer chemistry》2007,45(24):5884-5898
The aim of this study was to develop novel thermally responsive polymer microspheres with magnetic properties. Dispersion and inverse emulsion copolymerization of N‐isopropylacrylamide (NIPAAm) and N,N′‐methylenebisacrylamide (MBAAm) was investigated in the presence of γ‐Fe2O3 nanoparticles. The resulting microspheres were characterized in terms of morphology, size, polydispersity, iron content, and temperature‐dependent swelling using optical microscopy, transmission electron microscopy, scanning electron microscopy, QELS, and AAS. The effects of several variables, such as the concentration of γ‐Fe2O3, MBAAm crosslinking agent, Span 80 surfactant, 2,2′‐azobis(2‐methyloctanenitrile) (AMON) initiator, and polymerization temperature on the properties of the microspheres were studied. Swelling and thermoresponsive behavior of the microspheres containing γ‐Fe2O3 nanoparticles were also investigated. The microspheres contained about 8 wt % of iron. The presence of magnetic nanoparticles and their concentration changes did not have any significant effect on the temperature sensitivity of the composites. The particles gradually shrink into an increasingly collapsed state when the temperature is raised to 40 °C since the increase in temperature weakens the hydration and PNIPAAm chains gradually become more hydrophobic, which leads to the collapse of the particles. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5884–5898, 2007 相似文献
13.
Burn‐in is a widely used method to improve the quality of products or systems after they have been produced. In this paper, we consider the problem of determining the optimal burn‐in time and optimal work size maximizing the long‐run average amount of work saved per time unit in the computer applications. Assuming that the underlying lifetime distribution of the computer has an initially decreasing or/and eventually increasing failure rate function, an upper bound for the optimal burn‐in time is derived for each fixed work size and a uniform (with respect to the burn‐in time) upper bound for the optimal work size is also obtained. Furthermore, it is shown that a non‐trivial lower bound for the optimal burn‐in time can be derived if the underlying lifetime distribution has a large initial failure rate. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
14.
Shu‐Ling Huang Wei‐Kuo Chin W. P. Yang 《Journal of Polymer Science.Polymer Physics》2004,42(18):3476-3486
The tetramethoxysilane (TMOS)/2‐hydroxylethyl methacrylate (HEMA) hybrid gels were synthesized with acid and base catalysts, via the in situ polymerization of HEMA, with and without the cosolvent methanol. With methanol in the TMOS/HEMA sol, the enhanced esterification and depolymerization reactions of the silanols resulted in a slower growth of silica particles. The silica particles that were synthesized with an acid catalyst were less than 40 nm. The thermal resistance of the poly(2‐hydroxyethyl methacrylate) (PHEMA) chains was enhanced by the addition of colloidal silica. The Fourier transform infrared characterizations and the exothermal peaks on the differential scanning calorimetry traces of these hybrid gels indicated chemical hybridization occurring as a result of condensation of the colloid silica and PHEMA at higher temperatures. Hence, the residual weight content of the hybrid gel after its synthesis with the base catalyst was even higher than the content of TMOS in the hybrid sol. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3476–3486, 2004 相似文献
15.
Study on the Superhydrophilicity of the SiO2-TiO2 Thin Films Prepared by Sol-Gel Method at Room Temperature 总被引:2,自引:0,他引:2
Dasen Ren Xiaoli Cui Jie Shen Qun Zhang Xiliang Yang Zhuangjian Zhang Lu Ming 《Journal of Sol-Gel Science and Technology》2004,29(3):131-136
Nanoscale SiO2-TiO2 composite thin films with the thickness of about 100 nm were prepared by sol-gel method at room temperature in air. The chemical states of the elements on the surface and near the surface were measured by XPS. The results showed that the Ti on/near the surface of the thin films existed not only as TiO2 but also as Ti2O3. Part of the TiO2 was changed to Ti2O3 after UV irradiation. The crystalline structure of the TiO2 in the SiO2-TiO2 thin films was anatase with the crystallite size of 14–20 nm. It was found that the thin film prepared at room temperature in air has good superhydrophilic property and has strong adherence to the substrate. 相似文献
16.
17.
A. B. Vasil’eva A. A. Plotnikov 《Computational Mathematics and Mathematical Physics》2006,46(5):762-767
A singularly perturbed parabolic equation with a nonlinear right-hand side of a special form is examined. A numerical analytical study of such equations is performed. 相似文献
18.
Longlan Cui Hong Xu Ping He Keiko Sumitomo Yoshinori Yamaguchi Hongchen Gu 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5285-5295
A hybrid emulsion polymerization was formulated for synthesizing Fe3O4/polystyrene composite latex. This system, containing binary droplets that are magnetic (Mag)‐droplets with a diameter of 100–200 nm and styrene (St)‐droplets with a diameter of 3–4 μm, was obtained by mixing Mag‐miniemulsion and St‐macroemulsion. With extremely low surfactants concentration (?critical micelle concentration, CMC), the nucleated loci are selectively controlled in the Mag‐droplets, as the result of smaller droplet size and larger surface ratio. Both water‐soluble potassium persulfate (KPS) and oil‐soluble 2,2′‐azobis(2‐isobutyronitrile) was adopted to initiate the polymerization. In the presence of KPS, magnetic polystyrene latices with particles size of 60–200 nm, narrow size distribution, and high magnetite content (86 wt % measured by TGA) were attained successfully. The synthesized magnetic Fe3O4/polystyrene latices assembled into well‐ordered hexagonal structure in the surface of a carbon supported copper grid. The influence of various parameters on various aspects of the as‐synthesized Fe3O4/polystyrene was investigated in detail: type of initiator on composite morphology, feed ratio of Mag‐miniemulsion and St‐macroemulsion on magnetite content, and hydrophobic agent or amount of surfactant on size and size distribution. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5285–5295, 2007 相似文献
19.
Junxiang Xu 《Proceedings of the American Mathematical Society》2007,135(3):805-814
In this paper we consider a class of non-conservative dynamical system with small perturbation. By the KAM method we prove existence of Floquet invariant tori under the weakest non-resonant conditions.
20.