全文获取类型
收费全文 | 4765篇 |
免费 | 825篇 |
国内免费 | 733篇 |
专业分类
化学 | 4443篇 |
晶体学 | 65篇 |
力学 | 16篇 |
综合类 | 27篇 |
数学 | 44篇 |
物理学 | 1728篇 |
出版年
2024年 | 10篇 |
2023年 | 73篇 |
2022年 | 145篇 |
2021年 | 152篇 |
2020年 | 232篇 |
2019年 | 197篇 |
2018年 | 142篇 |
2017年 | 165篇 |
2016年 | 252篇 |
2015年 | 233篇 |
2014年 | 242篇 |
2013年 | 446篇 |
2012年 | 320篇 |
2011年 | 261篇 |
2010年 | 222篇 |
2009年 | 268篇 |
2008年 | 260篇 |
2007年 | 350篇 |
2006年 | 259篇 |
2005年 | 227篇 |
2004年 | 198篇 |
2003年 | 237篇 |
2002年 | 207篇 |
2001年 | 216篇 |
2000年 | 160篇 |
1999年 | 112篇 |
1998年 | 121篇 |
1997年 | 124篇 |
1996年 | 86篇 |
1995年 | 77篇 |
1994年 | 58篇 |
1993年 | 49篇 |
1992年 | 45篇 |
1991年 | 36篇 |
1990年 | 29篇 |
1989年 | 16篇 |
1988年 | 17篇 |
1987年 | 12篇 |
1986年 | 8篇 |
1985年 | 4篇 |
1984年 | 7篇 |
1982年 | 4篇 |
1981年 | 4篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1978年 | 9篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1973年 | 3篇 |
1972年 | 4篇 |
排序方式: 共有6323条查询结果,搜索用时 15 毫秒
21.
Kyung Hwa Hong Jong Lyoul Park In Hwan Sul Ji Ho Youk Tae Jin Kang 《Journal of Polymer Science.Polymer Physics》2006,44(17):2468-2474
Polyvinyl alcohol (PVA) nanofibers containing Ag nanoparticles were prepared by electrospinning PVA/silver nitrate (AgNO3) aqueous solutions, followed by short heat treatment, and their antimicrobial activity was investigated for wound dressing applications. Since PVA is a water soluble and biocompatible polymer, it is one of the best materials for the preparation of wound dressing nanofibers. After heat treatment at 155 °C for 3 min, the PVA/AgNO3 nanofibers became insoluble, while the Ag+ ions therein were reduced so as to produce a large number of Ag nanoparticles situated preferentially on their surface. The residual Ag+ ions were reduced by subsequent UV irradiation for 3 h. The average diameter of the Ag nanoparticles after the heat treatment was 5.9 nm and this value increased slightly to 6.3 nm after UV irradiation. It was found that most of the Ag+ ions were reduced by the simple heat treatment. The PVA nanofibers containing Ag nanoparticles showed very strong antimicrobial activity. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2468–2474, 2006 相似文献
22.
Backman Ulrika Jokiniemi Jorma K. Auvinen Ari Lehtinen Kari E.J. 《Journal of nanoparticle research》2002,4(4):325-335
We have prepared spherical non-agglomerated silver nanoparticles by an evaporation–condensation–dilution/cooling technique. Silver was evaporated from a crucible in a tubular flow reactor. A porous tube diluter was used to quench the carrier gas at the outlet of the reactor to enhance the formation of small particles and to suppress agglomeration and other particle growth mechanisms. The number size distribution of the prepared particles was measured with a differential mobility analyser–condensation nucleus counter combination and the size and the shape of the particles were analysed with transmission electron microscope. The system was modelled using a sectional aerosol dynamics computer code to estimate the importance of different aerosol processes. In all conditions the particles obtained were non-agglomerated and spherical. The mean particle diameter varied from 4 to 10-nm depending on boundary conditions. From the modelling studies it can be concluded that the nucleation rate is the most important parameter controlling the final particle size. 相似文献
23.
利用密度泛函理论研究了Al12N和Al12B团簇的原子结构和电子性质,通过各种异构体的比较,发现两种掺杂团簇的最低能量结构都是完好的二十面体(Ih)结构,N(B)原子占据在二十面体的中心.高对称性团簇形成稀疏离散的电子态密度和大的电子能隙.在Al-N之间发生较大的电荷转移.因此我们建议把Al12N团簇看作是碱金属超原子,Al12B团簇看作是卤素超原子,用来构造团簇组装固体. 相似文献
24.
25.
In order to determine the energetic driving forces for surface segregation in bimetallic clusters, we use a combined approach coupling numerical simulations within an N-body interatomic potential and a lattice-gas model. This approach, which has been used successfully to study both the superficial segregation in semi-infinite alloys and the intergranular segregation, allows us to determine the relative contributions of the three elementary driving forces for the different sites of the cluster surface (vertices, edges and facets) in both dilute limits for the Cu-Ag system. We show that the segregation hierarchy based on broken-bond arguments (preferential segregation to the vertex sites, less to edge sites, and least to facet sites) is not at all universal. In particular, unusual hierarchies are predicted when the sizes of the constituents are strongly different. Furthermore, we compare the segregation driving forces for cubo-octahedral and icosahedral clusters. They are similar for the vertex sites and edge sites, whereas they differ significantly for the sites of the triangular facets. The segregation of the species with the largest atomic radius (Ag) is indeed largely enhanced in the icosahedral structure due to dilations of the orthoradial distances. 相似文献
26.
Feng S.-W. Tsai C.-Y. Cheng Y.-C. Liao C.-C. Yang C.C. Lin Y.-S. Ma K.-J. Chyi J.-I. 《Optical and Quantum Electronics》2002,34(12):1213-1219
A side-bump feature in a photoluminescence (PL) spectrum of an InGaN compound was widely observed. With reasonable fitting to PL spectra with three Gaussian distributions, the temperature variations of the peak positions, integrated PL intensities, and peak widths of the main and first side peaks of three InGaN/GaN multiple quantum well samples with different nominal indium contents are shown and interpreted. The existence of the side peaks is attributed to phonon–replica transitions. The variations of the peak position separations and the decreasing trends of the first side peak widths beyond certain temperatures in those samples were explained with the requirement of phonon momentum condition for phonon–replica transitions. In the sample with 25% nominal indium content, the phonon–replica transition could become stronger than the direct transition of localized states. 相似文献
27.
Tamotsu Kohyama 《Journal of statistical physics》1991,63(3-4):637-651
A class of simple two-dimensional cellular automata with particle conservation is proposed for easy simulations of interacting particle systems. The automata are defined by the exchange of states of neighboring cells, depending on the configurations around the cells. By attributing an energy to a configuration of cells, we can select significant rules from the huge number of possible rules and classify them into several groups, based on the analogy with a binary alloy. By numerical calculations, cluster growth is found in two kinds of phases which reveal gas-solid coexistence and liquid droplets. Normalized scaling functions are obtained, and dynamical scaling is examined. 相似文献
28.
Shoaib Ahmad 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,18(3):309-318
The mechanisms and processes of the formation of the regenerative soot in a graphite hollow cathode discharge that produces
and emits carbon clusters are presented. Mass spectrometry with a specially designed E×B velocity filter analyzes the entire range of the charged clusters from C
1 to ∼C
4300. The state of the carbon vapour within the source is evaluated by using the characteristic line emissions from the carbonaceous
discharge whose formative mechanisms depend upon the kinetic and potential sputtering of the sooted cathode. The carbonaceous
discharge generates atomic and ionic C and its clusters C
m (m≥ 2), noble gas metastable atoms and ions, energetic electrons and photons in the cavity of the graphite hollow cathode. The
parameters of soot formation and its recycling depend critically on the discharge parameters, the geometry of the hollow cathode
and 3D profile of the cusp magnetic field contours.
Received 2nd July 2001 and Received in final form 10 September 2001 相似文献
29.
Vaporizing solid samples of metals and semiconductors with a YAG Laser is a method well suited for producing molecules and
clusters of those materials. The clusters are examined by either laser-induced fluorescence (LIF) or mass spectroscopic methods.
The technique is valuable for both gas phase and matrix studies. The method is described and some applications, studying either
the structure of small metal molecules or their reactions, are reviewed, with emphasis on our recent results from the LIF
studies of LiBe, Al2 and the reaction of Al with oxygen, yielding A12O. For larger clusters, Ion Cyclotron Resonance is an extremely valuable method, as we demonstrate by its application to the
reactions of small charged silicon clusters with strong oxidising agents. 相似文献
30.