Stimulated infrared emission under excitation of condensed molecular dielectrics with giant pulses of a ruby laser

Stimulated infrared (IR) emission from a condensed dielectric medium under exposure to a giant pulse of a ruby laser is reported. This effect was predicted in the theoretical paper [1]. Experimental studies were carried out for a number of molecular liquids in two experimental geometries. In the first case (“in transmission” geometry) the propagation direction of the detected IR radiation coincided with that of the exciting radiation. In the second case IR radiation generated was detected in the opposite direction. The angle of divergence of IR radiation was found to be of 10⁻² rad, while the conversion efficiency with respect to the pumping intensity depended on the type of molecular liquid and varied in the range of 0.05–0.6%. Possible microscopic mechanisms of generation of IR radiation under pumping of the dielectric medium with visible or ultraviolet (UV) radiation are analyzed.     

基于MDA法计算水雾粒子红外隐身粒径

水雾隐身技术是一种较为理想且经济适用的目标特征信号控制技术。本文从辐射传输方程出发,考虑水雾粒子的本身辐射和散射,提出以红外表观透射率评价水雾粒子的红外隐身性能。应用Modified Differential Approximation(MDA)法结合MIE理论,计算了水雾粒子红外表观透射率随水雾粒子浓度和粒径的变化关系,得到水雾粒子最佳红外隐身粒径。结果表明:水雾粒子的红外表观透射率随粒子浓度的增加而减小,但当粒子的浓度增加到一定值时,红外表观透射率基本保持不变;水雾粒子的红外表观透射率随粒径的增加先减小后增大,当探测波段为3～5μm时,水雾粒子的最佳红外隐身粒径为6μm;而探测波段为8～12μm时,水雾粒子的最佳红外隐身粒径为12μm。     

基于改进的分块压缩感知红外图像重建

针对基于压缩感知理论的红外图像重建问题,提出一种基于改进的分块压缩感知红外图像重建方法。该方法首先对原始红外图像进行分块,并对每个子块用相同的观测矩阵进行随机观测,获得少量的观测数据;然后利用谱图小波变换优异的稀疏特性,将其引入平滑投影Landweber算法进行迭代优化重建,同时采用混合中值滤波进行处理以增加图像的平滑度和减少块伪影,最后输出满足要求的高质量红外图像。实验结果表明,在相同采样率下,该方法对于不同类型红外图像的重建性能均优于目前广为采用的一些小波压缩感知方法,可获得更高质量的红外图像。     

近红外漫反射光谱法快速测定苦参和白土苓药材中多指标成分的含量

建立近红外光谱(near infrared spectroscopy,NIRS)法快速测定复方苦参注射液原料药材苦参和白土苓中多指标成分含量的方法,探讨其在中成药原料质量保障系统中的应用可行性。以HPLC法测定苦参中氧化苦参碱、氧化槐果碱、苦参碱和槐果碱以及白土苓中大泽米苷的含量为对照值;采用近红外漫反射模式采集样品光谱,比较不同建模波段及光谱预处理方法的建模效果,优选出最佳建模参数;采用偏最小二乘法分别建立白土苓中大泽米苷和苦参中氧化苦参碱与苦参碱总量、槐果碱与氧化槐果碱总量的近红外定量分析模型,并对模型进行评价。结果显示,HPLC测定的88批白土苓中大泽米苷和75批苦参中氧化苦参碱与苦参碱总量、槐果碱与氧化槐果碱总量分别0.36~12.88,8.87~66.31和2.30~15.11mg·g-1。所建立的三组指标成分的NIRS定量校正模型性能良好,各模型校正集内部交叉验证R2为0.902 5,0.949 1,0.913 7,RMSECV为0.961,2.45,0.724mg·g-1;验证集外部验证R2 0.981 7,0.982 6,0.960 9,RMSEP为0.693,2.27,0.658mg·g-1。建立了快速定量苦参和白土苓中多指标成分的含量的近红外分析方法,所建立的定量分析模型能够满足复方苦参注射液大生产对大批量原料样品化学信息快速获取的需求。     

近红外光谱技术快速鉴别地沟油与食用植物油的研究

地沟油检测是我国食品安全最为关注的话题之一,它给人们的生活健康带来了极大的危害。国内现有的检测手段也仅停留在定性检测水平上,只能确定地沟油的有无,还难以进行定量检测。本实验利用近红外光谱技术与光纤传感技术相结合的新方法对勾兑混合油中地沟油的含量进行了定量分析。将煎炸老油与九三大豆油按照一定的体积比进行勾兑,共计50个样本,采集其近红外透射光谱,分别采用偏最小二乘法(PLS)和BP人工神经网络建立了煎炸老油含量的定量分析模型,校正集决定系数分别为0.908和0.934,验证集决定系数分别为0.961和0.952,均方估计残差(RMSEC)为0.184和0.136,预测均方根误差(RMSEP)都为0.111 6,符合应用要求,同时还结合主成分分析法(PCA)对煎炸老油与食用植物油进行了鉴别,识别准确率为100%。实验研究证明近红外光谱技术不仅可以准确快速的定性分析地沟油, 还能定量的检测地沟油的含量,在油脂的检测方面具有很大的应用前景。     

基于数学形态学的弱点状运动目标的检测

提出了一种新的基于数学形态学的红外图像序列中弱点状运动目标的非参数检测算法。采用数学形态学抑制背景杂波干扰和增强目标,用沿时间轴投影和二维空域搜索代替复杂的时空三维搜索形成组合帧,然后在每条可能的轨迹上将进行目标能量累加,实现了一种快速检测前跟踪(TBD)检测算法。仿真实验表明:在恒虚警概率条件下,该检测算法能高效地检测信噪比约为2的弱点状运动目标,检测性能对噪声分布不敏感,能精确地得到目标的即时位置和速度信息,适合于实时图像处理和目标探测,具有很高的实用价值。     

红外光学材料折射率温度系数测量装置

本文介绍一台红外光学材料折射率温度系数测量装置。该装置是由温控系统、精密测角系统、光学系统和电器控制系统等组成的一台高精度全自动化测量系统，采用改进的自准直法测量折射率温度系数值。该装置达到的主要技术指标：工作波长为2～12μm，温度范围为-50～150℃，测量不确定度为3%，可满足各种红外光学材料折射率温度系数测量的要求。利用该装置对红外材料锗折射率温度系数值进行了测量，并对测量数据进行了报道。     

First high-resolution analysis of the 4ν1+ν3 band of nitrogen dioxide near 1.5 μm

The high-resolution absorption spectrum of the 4ν₁+ν₃ band of the ¹⁴N¹⁶O₂ molecule was recorded by CW-Cavity Ring Down Spectroscopy between 6575 and 6700 cm⁻¹. The assignments involve energy levels of the (4,0,1) vibrational state with rotational quantum numbers up to K_a=8 and N=48. A large majority of the spin-rotation energy levels were reproduced within their experimental uncertainty using a theoretical model which takes explicitly into account the Coriolis interactions between the spin-rotational levels of the (4,0,1) vibrational state and those of the (4,2,0) and of (0,9,0) dark states, the anharmonic interactions between the (4,2,0) and (0,9,0) states together with the electron spin-rotation resonances within the (4,0,1), (4,2,0) and (0,9,0) states. Precise vibrational energies, rotational, spin-rotational, and coupling constants were determined for the {(4,2,0), (0,9,0), (4,0,1)} triad of interacting states. Using these parameters and the value of the transition dipole-moment operator determined from a fit of a selection of experimental line intensities, the synthetic spectrum of the 4ν₁+ν₃ band was generated and is provided as Supplementary Material.     

Infrared absorption spectra and structure of TiO2-SiO2 composites

The composites xTiO₂-(1−x)SiO₂ (x = 0.1, 0.5, 0.9) were obtained by coprecipitation from solutions of alkoxides: tetraethoxysilane (TEOS) and titanium tetraisopropoxide (TIPT). Intermolecular interaction of the components of the composite is apparent in the IR absorption spectra in the 928–952 cm⁻¹ region, and is connected with bending vibrations of the Si-O-Ti bond. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 5, pp. 724–728, September–October, 2008.