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161.
Roy Rotstein Samir Mitragotri Martin Moskovits Daniel E. Morse 《Journal of Polymer Science.Polymer Physics》2014,52(9):611-617
The synthesis and characterization of highly ordered three‐dimensional photonic crystals have been the subjects of intense study over the past two decades due to the unique ability of these structures to control light at the nanoscale. Building on that work in recent years, increasing interest is now focused on the unique optical properties of disordered and quasi‐ordered photonic structures. We present a study of the effects of shape anisotropy and disorder on the specular reflection properties of polymer‐based colloidal films comprised of rod‐shaped subunits of varying aspect ratio. We characterize the specular reflectance properties of these films as a function of their increasing levels of disorder, demonstrating progressive transition from resonant reflection to diffuse reflection. The onset of the diffuse reflection is governed by particle size. © 2014 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys. 2014 , 52, 611–617 相似文献
162.
163.
By the introduction of methoxycarbonyl‐methoxy groups and hydroxyl groups into a pillar structure, a pillararene entirely with two types of functional groups was successfully prepared, which can form a stable 1:1 complex with a bis(imidazolium) salt in CHCl3/acetone solution (V:V=1:1). 相似文献
164.
Rujie Wang Xiaoming Yan Xuemei Wu Gaohong He Lin Du Zhengwen Hu Ming Tan 《Journal of Polymer Science.Polymer Physics》2014,52(16):1107-1117
Modification of proton conductive channels (PCCs) in Nafion has been achieved with the assistance of 3, 4‐dimethylbenzaldehyde (DMBA). During annealing, ionic clusters develop from small isolated spheres (1.72 nm) to wide continuous channels (5.15 nm), and the crystallinity of Nafion/DMBA membranes is also improved from 17% to 32% as shown by X‐ray diffraction. Molecular dynamic simulation reveals that hydrogen bonding and hydrophobic interaction between DMBA and Nafion work synergistically to achieve better phase separation. The morphology–property relationship shows that, versus various PCCs width, the corresponding proton conductivities vary greatly from 0.079 to 0.139 S/cm at 80 °C. By carefully tuning the width of PCCs, the proton conductivity shows an improvement of 22–34% as compared with pristine Nafion. A significant enhancement on the maximum power density is achieved for the membrane electrode assembly on Nafion/DMBA‐8h (as high as 1018 mW/cm?2), yielding an enhancement of 39% on pristine Nafion‐8h (730 mW/cm?2). © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014 52, 1107–1117 相似文献
165.
Jun Jason Luo 《Mathematische Nachrichten》2019,292(5):1032-1042
Recently Lipschitz equivalence of self‐similar sets on has been studied extensively in the literature. However for self‐affine sets the problem is more awkward and there are very few results. In this paper, we introduce a w‐Lipschitz equivalence by repacing the Euclidean norm with a pseudo‐norm w. Under the open set condition, we prove that any two totally disconnected integral self‐affine sets with a common matrix are w‐Lipschitz equivalent if and only if their digit sets have equal cardinality. The main methods used are the technique of pseudo‐norm and Gromov hyperbolic graph theory on iterated function systems. 相似文献
166.
Santosh Kumar Sejy Lee Reju George Thomas Seung‐Jea Lee Hong‐Joon Lee In‐Kyu Park Yong Yeon Jeong Tae‐Ho Yoon Dong‐Chan Shin Jae‐Suk Lee 《Journal of polymer science. Part A, Polymer chemistry》2019,57(11):1165-1172
Self‐emulsion polymerization (SEP), a green route developed by us for the polymerization of amphiphilic monomers, does not require any emulsifier or an organic solvent except that the water‐soluble initiators such as 2,2′‐azobis[2‐(2‐imidazolin‐2‐yl)propane]dihydrochloride (VA‐044) and potassium persulfate (KPS) are only used. We report here the polymer nanoscaffolds from a number of amphiphilic monomers, which can be used for in situ encapsulation of a variety of nanoparticles. As a demonstration of the efficacy of these nanoscaffolds, the synthesis of a biocompatible hybrid nanoparticle (nanohybrid), prepared by encapsulating Fe3O4 magnetic nanoparticle (Fe3O4 MNPs) in poly(2‐hydroxyethyl methacrylate) in water, for MRI application is presented. The nanohybrid prepared following the SEP in the form of an emulsion does not involve the use of any stabilizing agent, crosslinker, polymeric emulsifier, or surfactant. This water‐soluble, spherical, and stable nanohybrid containing Fe3O4 MNPs of average size 10 ± 2 nm has a zeta potential value of ?41.89 mV under physiological conditions. Magnetic measurement confirmed that the nanohybrid shows typical magnetic behavior having a saturation magnetization (Ms) value of 32.3 emu/g and a transverse relaxivity (r2) value of 29.97 mM?1 s?1, which signifies that it can be used as a T2 contrast agent in MRI. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 相似文献
167.
Bingyan Jiang Lei Zhang Jie Yan Qingquan Huang Bing Liao Hao Pang 《Journal of polymer science. Part A, Polymer chemistry》2014,52(17):2442-2453
A series of well‐defined thermoresponsive graft polymers with different lengths and graft densities, poly(glycidyl methacrylate)‐graft‐poly(N‐isopropylacrylate) (PGMA‐g‐PNIPAM), were successfully prepared by combination of controlled/living free radical polymerization and click chemistry. Effects of grafting length and density on the thermoresponsive behavior, aggregating mean diameter, and self‐assembly morphology are systematically investigated. The thermosensitive characteristics of graft polymers in aqueous solution prove that the length and graft density had positive co‐relationship with the lower critical solution temperature value and mean diameter of micelles as well as the size distribution, while the effect of graft length of polymers is more significant than that of density. Transmission electron microscopy analysis shows that the conformations of PGMA45‐g‐PNIPAM20 and PGMA45‐g‐PNIPAM46 with longer length and bigger grafting density in aqueous solutions are spherical nanoparticles with the increasing trend of the diameters, while that of PGMA45‐g‐PNIPAM(73, 50%) shows a spherical‐like morphology, which indicates that the graft length and density have a significant effect on the mean diameter of micelle but not on the self‐assembly morphology. These results reveal that to obtain desired thermoresponsive behavior and self‐assembly morphology of functional polymers, it is essential to design and fabricate the structure of graft polymers with proper length and graft density. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 2442–2453 相似文献
168.
Florent Jasinski Emeline Lobry Lénaïg Lefevre Abraham Chemtob Céline Croutxe‐Barghorn Xavier Allonas Adrien Criqui 《Journal of polymer science. Part A, Polymer chemistry》2014,52(13):1843-1853
The use of UV light to initiate emulsion polymerization processes is generally overlooked, whilst extensive literature exists on photocuring of monomer films. In this study, the unique potential of UV light to produce at ambient temperature polyacrylate latexes without initiator was exploited. Although radical initiators are utilized at low concentration, their cost, toxicity, and odor provide incentives for finding alternatives. Starting with concentrated (30 wt %) and low scattering acrylate miniemulsions (droplet diameter <100 nm), it was demonstrated that acrylate self‐initiation can promote an efficient and fast photopolymerization in micrometer‐scale reactor (spectrophotometric cell) and lab‐scale photoreactor. Herein, all kinetic, colloidal, and mechanistic aspects involved in the self‐initiation of acrylate miniemulsion were extensively examined to provide a complete picture. In particular, the effects of droplet size, initiating wavelength, optical path, and irradiance on the course of the polymerization were thoroughly discussed. A diradical self‐initiation pathway is the most likely mechanism. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1843–1853 相似文献
169.
Yunhua Chen Nicholas Ballard Oliver D. Coleman Ian J. Hands‐Portman Stefan A. F. Bon 《Journal of polymer science. Part A, Polymer chemistry》2014,52(12):1745-1754
We demonstrate that the volume phase transition temperature (VPTT) of copolymer microgel particles made from N‐isopropylacrylamide (NIPAm) and methacryloyl hydrazide (MH) can be tailored in a reversible manner upon the reaction of the hydrazide functional groups with aldehydes. The microgels were synthesized by precipitation polymerization in water. Due to the water‐soluble nature of the MH monomer, the VPTT at which the microgel particles contract shifts to higher values by increasing the incorporated amounts of methacryloyl hydrazide from 0 to 5.0 mol %. The VPTT of the copolymer microgel dispersions in water can be fine‐tuned upon addition of hydrophobic/hydrophilic aldehydes, which react with the hydrazide moiety to produce the hydrazone analogue. This hydrazone formation is reversible, which allows for flexible, dynamic control of the thermo‐responsive behavior of the microgels. The ability to “switch” the VPTT was demonstrated by exposing hydrophilic streptomycin sulfate salt incubated microgel particles to an excess of a hydrophobic aldehyde, that is benzaldehyde. The temperature at which these microgels contracted in size upon heating was markedly lowered in these aldehyde exchange experiments. Transformation into benzaldehyde hydrazone derivatives led to assembly of the microgel particles into small colloidal clusters at elevated temperatures. This control of supracolloidal cluster formation was also demonstrated with polystyrene particles which had a hydrazide functionalised microgel shell. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1745–1754 相似文献
170.
Tabito Ikezaki Reishi Matsuoka Kenichi Hatanaka Naoko Yoshie 《Journal of polymer science. Part A, Polymer chemistry》2014,52(2):216-222
We synthesized biobased poly(2,5‐furandimethylene succinate‐co‐butylene succinate) [P(FS‐co‐BS)] copolymers by polycondensation of 2,5‐bis(hydroxymethyl)furan, 1,4‐butanediol, and succinic acid. These copolymers could be crosslinked to form network polymers by means of a reversible Diels–Alder reaction with bis‐maleimide. The thermal properties, mechanical properties, and healing abilities of the P(FS‐co‐BS)s and the network polymers were investigated. The mechanical properties of the network polymers depended on the comonomer composition of the P(FS‐co‐BS)s and the maleimide/furan ratio in the network polymers. Some of the copolymers exhibited healing ability at room temperature, and their healing efficiency was enhanced by solvent or heat. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 216–222 相似文献