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171.
Kazimierz Nikodem 《Aequationes Mathematicae》1991,42(1):182-189
Summary LetX be a real vector space,D a convex subset ofX and (Y, K) an order complete ordered vector space. The following sandwich theorem holds: Iff: D Y is midconvex,g: D Y {– } is midconcave andg f onD, then there exists a Jensen mappingh: D Y {– } such thatg h f onD. Using this theorem we show that a mappingf: D Y is midconvex if and only if it has Jensen support at every point ofD. Moreover, ifX is a Baire topological vector space and (Y, K) is an ordered topological vector space satisfying some additional conditions, then a mappingf: D Y is continuous whenever it has continuous Jensen support at every point ofD. As an application of these results we obtain the equality of some set-classes connected with additive and midconvex operators.Dedicated to the memory of Alexander M. Ostrowski on the occasion of the 100th anniversary of his birth 相似文献
172.
Xingang Kong Jiarui Zhang Jianfeng Huang Jiayin Li Yi Qin Ting Zhao Qi Feng 《中国化学快报》2019,30(3):771-774
SnNb2O6 and Sn2Nb2O7 nanosheets were synthetized via microwave assisted hydrothermal method, and innovatively employed as anode materials for lithium-ion battery. Compared with Sn2Nb2O7 and the previously reported pure Sn-based anode materials, the SnNb2O6 electrode exhibited outstanding cycling performance. 相似文献
173.
Jos-Ramon Galan-MascarosAlexandra M. Z. Slawin J. Derek WoollinsDavid J. Williams 《Polyhedron》1996,15(24):4603-4605
The X-ray structure of [S4N3]Cl reveals three independent molecules, which all display π-facial interactions between the Cl− and the pseudo-aromatic [S4N3]+ rings to produce a structure containing “inverse sandwich” systems. 相似文献
174.
Noncovalent interactions play a pivotal role in regulating protein conformation, stability and dynamics. Among the quantum mechanical (QM) overlap-based noncovalent interactions, is the best understood with studies ranging from small molecules to -turns of model proteins such as GB1. However, these investigations do not explore the interplay between multiple overlap interactions in contributing to local structure and stability. In this work, we identify and characterize all noncovalent overlap interactions in the -turn, an important secondary structural element that facilitates the folding of a polypeptide chain. Invoking a QM framework of natural bond orbitals, we demonstrate the role of several additional interactions such as and that are energetically comparable to or larger than . We find that these interactions are sensitive to changes in the side chain of the residues in the -turn of GB1, suggesting that the may not be the only component in dictating -turn conformation and stability. Furthermore, a database search of and in the PDB reveals that they are prevalent in most proteins and have significant interaction energies (∼1 kcal/mol). This indicates that all overlap interactions must be taken into account to obtain a comprehensive picture of their contributions to protein structure and energetics. Lastly, based on the extent of QM overlaps and interaction energies, we propose geometric criteria using which these additional interactions can be efficiently tracked in broad database searches. 相似文献
175.
Secondary structure motifs in nucleic acid probes generally impair intended hybridization reactions and so efforts to predict and avoid such structures are commonly employed in probe design schemes. Another key facet of probe design that has received much less attention, however, is that secondary structure at targeted probe binding site regions may also impair hybridization. Thus, evaluation of both probe and target site secondary structures together should improve hybridization prediction and design effectiveness. Several challenges confound this goal, including imperfect empirical rules and parameters underlying predictions and the fact that folding algorithms scale poorly with respect to sequence length. Here, we attempt to quantify the consequences of target site structure on predicted hybridization using sequences sampled from the human genome. We also provide a methodology for choosing a reasonable “window size” around target sites that is as small as possible without compromising folding algorithm prediction accuracy. 相似文献
176.
Ivan panik Jan Krupcik Ivan Skacani Jaap De Zeeuw Mario Galli Pat Sandra 《Journal of separation science》1997,20(12):688-692
The separation of isomers and enantiomers of branched C10-C12 phenylalkanes by gas chromatography on fused silica capillary columns coated with some modified β- and γ-cyclodextrins was studied. It was shown that the separation of positional isomers of C10-C12 phynylalkanes on modified cyclodextrin capillary columns is not better than that on a column coated with modified polyethylene glycol. Differences were found in the enantioselectivity of modified β- and γ-cyclodextrins for the separation of C10-C12 secondary phenylalkane enantiomers. While alkylderivatives of β-CDs resolve enantiomers of 3-phenylalkanes, alkyl derivatives of γ-CD resolve enantiomers of 2-phenylalkanes. Since shape selectivity factors of modified cyclodextrins have indicated no inclusion of the considered solutes in cyclodextrin cavities, enantioselective interactions most probably occur on the outer sphere of cyclodextrins. 相似文献
177.
构建微生物细胞工厂是化学品、生物能源以及药物分子可持续生产的可行性策略。然而,微生物的代谢复杂、调控严谨,制约着目标产物高效合成。蛋白质组学和代谢组学可以从系统生物学角度分析酶和代谢物组分,从而理解复杂的生物系统,为微生物代谢工程改造提供重要线索。该文介绍了蛋白质组学和代谢组学在微生物代谢工程中的应用,包括基因组尺度代谢模型构建、菌株生物合成优化、指导菌株耐受性改造、限速步骤预测、植物次级代谢途径挖掘,从而为微生物合成天然产物提供新的基因或途径。在此基础上,该文还展望了生物大数据未来的发展方向。 相似文献
178.
A. Neumaier 《Geometriae Dedicata》1979,8(2):189-205
Zusammenfassung Es werden zwei neue Koordinatisierungsmethoden für affine Ebenen gegeben, und zwar durch homogene bzw. stark balancierte Tupelsysteme. Ihre Brauchbarkeit wird u.a. demonstriert an einer Charakterisierung der Kollineationsgruppen einer affinen Ebene mit der Eigenschaft (R) Für alle i l
enthält der Stabilisator von i nur Perspektivitäten mit Zentrum i. Außerdem wird der Satz bewiesen: Für eine Elation der geraden Ordnung d in einer projektiven Ebene der Ordnung v gilt 2d|v. Dieses Resultat impliziert schon bekannte Ergebnisse von Hughes (d=2) und Hall.
We give two new coordinatization methods for affine planes by means of homogeneous (resp. strong balanced) tuple systems. Their usefulness is demonstrated by proving a characterization of collineation groups of an affine plane with the property (R): The stabilizer of every i l contains only perspectivities with centre i. Besides, we prove: If a projective plane of order v contains an elation of even order d then 2d|v. This implies known results of Hughes (d=2) and Hall.相似文献
179.
Min Jiang Junliang Chen Dr. Yuanyuan Ma Prof. Wei Luo Prof. Jianping Yang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(36):9320-9327
Recently, the frequency of combining MXene, which has unique properties such as metal-level conductivity and large specific surface area, with silicon to achieve excellent electrochemical performance has increased considerably. There is no doubt that the introduction of MXene can improve the conductivity of silicon and the cycling stability of electrodes after elaborate structure design. However, most exhaustive contacts can only improve the electrode conductivity on the plane. Herein, a MXene@Si/CNTs (HIEN-MSC) composite with hierarchical interpenetrating electroconductive networks has been synthesized by electrostatic self-assembly. In this process, the CNTs are first combined with silicon nanoparticles and then assembled with MXene nanosheets. Inserting CNTs into silicon nanoparticles can not only reduce the latter‘s agglomeration, but also immobilizes them on the three-dimensional conductive framework composed of CNTs and MXene nanosheets. Therefore, the HIEN-MSC electrode shows superior rate performance (high reversible capacity of 280 mA h−1 even tested at 10 A g−1), cycling stability (stable reversible capacity of 547 mA h g−1 after 200 cycles at 1 A g−1) and applicability (a high reversible capacity of 101 mA h g−1 after 50 cycles when assembled with NCM622 into a full cell). These results may provide new insights for other electrodes with excellent rate performance and long-cycle stability. 相似文献
180.
Hüseyin Göktepe 《中国化学会会志》2013,60(2):218-222
Dy doping and carbon coating are adopted to synthesize a LiFePO4 cathode material in a simple solution environment. The samples were characterized by X‐ray diffraction (XRD) and scanning electron microscopy (SEM). Their electrochemical properties were investigated by cyclic voltammetry (CV) and galvanostatic charge‐discharge tests. An initial discharge capacity of 153 mAh/g was achieved for the LiDy0.02Fe0.98PO4/C composite cathode with a rate of 0.1 C. In addition the electronic conductivity of Dy doped LiFePO4/C was enhanced to 1.9 × 10?2 Scm?1. The results suggest that the improvement of the electrochemical properties are attributed to the dysprosium doping and carbon coating which facilitates the phase transformation between triphylite and heterosite during cycling. XRD data indicate that doping did not destroy the lattice structure of LiFePO4. To evaluate the effect of Dy substitution, cyclic voltammetry was used at room temperature. prepared. From Cv measurement a more symmetric curve with smaller interval between the cathodic and anodic peak current was obtained by Dy substitution. This denoted a decreasing of polarization with Dy substitution, which illustrated an enhancement of electrochemical performances. 相似文献