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141.
Wilson A. Cañas-Marín Julián D. Ortiz-Arango Uriel E. Guerrero-Aconcha Claudia P. Soto-Tavera 《Fluid Phase Equilibria》2007
The ability of Soave–Redlich–Kwong cubic equation of state (SRK EoS) to predict densities and thermodynamic derivative properties such as thermal expansivity, isothermal compressibility, calorific capacity, and Joule–Thompson coefficients, for two gas condensates over a wide range of pressures (up to 110 MPa) was studied. The predictions of the EoS were compared to Monte Carlo simulation data obtained by Lagache et al. [M.H. Lagache, P. Ungerer, A. Boutin, Fluid Phase Equilibr. 220 (2004) 221]. Two completely different alpha functions for the SRK EoS attractive term were used and their respective effects on the predictions of such properties were analyzed. Also, two different forms of the crossed terms of the attractive parameter, aij, and three expressions of the crossed terms of the repulsive parameter, bij, were combined in different ways, and predictions were carried out. Little sensitivity of the properties on the chosen alpha function, except for the calorific capacities, was found in the systems studied. The most commonly used combination rules to model phase behavior of reservoir fluids, i.e. geometric and arithmetic forms of aij and bij, respectively, predicted very deficient results for these fluids at extreme conditions, specially for density calculations. 相似文献
142.
Roderich Tumulka 《Foundations of Physics》2007,37(2):186-197
In a recent paper Conway and Kochen, Found. Phys. 36, 2006, claim to have established that theories of the Ghirardi-Rimini-Weber
(RW) type, i.e., of spontaneous wave function collapse, cannot be made relativistic. On the other hand, relativistic GRW-type
theories have already been presented, in my recent paper, J. Stat. Phys. 125, 2006, and by Dowker and Henson, J. Stat. Phys.
115, 2004. Here, I elucidate why these are not excluded by the arguments of Conway and Kochen.
相似文献
143.
Ryohei Tsuda Sayaka Kaino Hisashi Kokubo Shin-Ichiro Imabayashi Masayoshi Watanabe 《Colloids and surfaces. B, Biointerfaces》2007,56(1-2):255-Optics
Redox properties of phenothiazine-labeled poly(ethyl glycidy ether)-block-poly(ethylene oxide) (PT-EGEn-b-EOm) are reversibly changed by core-shell micelle formation. In the temperature range higher than the critical micellization temperature (cmt), the anodic potential of PT group positively shifts and concomitantly its anodic current decrease, or levels off compared to those of the reference polymer PT-EOm without the thermo-responsive EGEn segment. The former alteration is caused by incorporation of hydrophobic PT groups into a core of the micelle and the latter by the decrease in the diffusion coefficient of PT groups due to formation of the core-shell micelles. The cmt value and the temperature-dependent alteration in the redox properties strongly depend on the polymer structure, especially the length of thermo-responsive EGEn segment. The electrochemically determined hydrodynamic radii of the polymer aggregates seem to be overestimated, compared to the values reported for the aggregates of other thermo-responsive polymers with similar molecular weights, implying the presence of electrochemically inactive PT groups in the copolymers having longer thermo-responsive segments. 相似文献
144.
In this paper we describe the design and manufacture of an axial-torsion test specimen, and provide relationships needed when
conducting stress-strain characterization experiments with the specimen. The specimen is a short hollow cylinder of rubber
bonded between two steel mounting rings, in which simultaneous axial and shear strains are produced via independently controlled
axial and twist displacements. We present calculations for the strain-displacement and stress-load relationships, and strain
energy density. These relationships have been established and validated via a combination of analytical and experimental techniques,
and finite element analysis. We have investigated the extent and effects of strain and stress field non-uniformity in the
test specimen. The specimen design is sufficiently simple that a closed-form expression for the strain-displacement relationship
has been successfully developed. 相似文献
145.
Jae-Yeon Lee Eugene Lubarsky Ben T. Zinn 《Proceedings of the Combustion Institute》2005,30(2):1757-1764
This paper describes an experimental investigation of the feasibility of using “slow” active control approaches, which “instantaneously” change liquid fuel spray properties, to suppress combustion instabilities. The objective of this control approach was to break up the feedback between the combustion process heat release and combustor pressure oscillations that drive the instability by changing the characteristics of the combustion process (e.g., the characteristic combustion time). To demonstrate the feasibility of such control, this study used a proprietary fuel injector (NanomiserTM), which can vary its fuel spray properties, to investigate the dependence of acoustics–combustion process coupling, i.e., the driving of combustion instabilities, upon the fuel spray properties. This study showed that by changing the spray characteristics it is possible to significantly damp combustion instabilities. Furthermore, using combustion zone chemiluminescence distributions, which were obtained by Abel’s deconvolution synchronized with measured acoustic data, it has been shown that the instabilities were mostly driven midway between the combustor centerline and wall, a short distance downstream from the flame holder, where the mean axial flow velocity is approximately zero in the vortex near the flame holder. The results of this study strongly suggest that a “slow” active control system that employs controllable fuel injectors could be effectively used to prevent the onset of detrimental combustion instabilities. 相似文献
146.
A new approach to identify the independent amplitudes along with their partial wave multipole expansions, for photo-and electro-production
is suggested, which is generally applicable to mesons with arbitrary spin-parity. These amplitudes facilitate direct identification
of different resonance contributions.
相似文献
147.
Masaharu Asano Jinhua Chen Yasunari Maekawa Takahiro Sakamura Hitoshi Kubota Masaru Yoshida 《Journal of polymer science. Part A, Polymer chemistry》2007,45(13):2624-2637
A novel process comprising the UV‐induced photografting of styrene into poly(tetrafluoroethylene) (PTFE) films and subsequent sulfonation has been developed for preparing proton‐conducting membranes. Although under UV irradiation the initial radicals were mainly generated on the surface of the PTFE films by the action of photosensitizers such as xanthone and benzoyl peroxide, the graft chains were readily propagated into the PTFE films. The sulfonation of the grafted films was performed in a chlorosulfonic acid solution. Fourier transform infrared and scanning electron microscopy were used to characterize the grafted and sulfonated membranes. With a view to use in fuel cells, the proton conductivity, water uptake, and mechanical properties of the prepared membranes were measured. Even through the degree of grafting was lower than 10%, the proton conductivity in the thickness direction of the newly prepared membranes could reach a value similar to that of a Nafion membrane. In comparison with γ‐ray radiation grafting, UV‐induced photografting is very simple and safe and is less damaging to the membranes because significant degradation of the PTFE main chains can be avoided. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2624–2637, 2007 相似文献
148.
J. MALINEN O. NEVANLINNA V. TURUNEN Z. YUAN 《数学学报(英文版)》2007,23(4):745-748
Let T be a bounded linear operator in a Banach space, with σ(T)={1}. In 1983, Esterle-Berkani' s conjecture was proposed for the decay of differences (I - T) T^n as follows: Eitheror lim inf (n→∞(n+1)||(I-T)T^n||≥1/e or T = I. We prove this claim and discuss some of its consequences. 相似文献
149.
150.
In this paper, we consider questions related to the structure of inverse matrices of linear bounded operators acting in infinite-dimensional complex Banach spaces. We obtain specific estimates of elements of inverse matrices for bounded operators whose matrices have a special structure. Matrices are introduced as special operator-valued functions on an index set. The matrix structure is described by the behavior of the given function on elements of a special partition of the index set. The method used for deriving the estimates is based on an analysis of Fourier series of strongly continuous periodic functions. 相似文献