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91.
92.
黏胶废液对福建无烟煤水蒸气催化气化的动力学和补偿效应 总被引:2,自引:0,他引:2
采用黏胶废液为催化剂,对福建尤溪无烟粉煤在常压热分析仪中的水蒸气催化气化动力学进行了研究。在850℃~950℃测定了黏胶废液催化剂添加量(NaOH浓度为计算基准)从0~12%时的碳转化率随气化时间的变化,表明黏胶废液具有提高碳转化率和气化速率的作用,同时确定了该黏胶废液催化剂的加载饱和浓度。基此得出的尤溪无烟粉煤水蒸气催化气化反应动力学符合缩芯模型,并给出相应的动力学参数。进而分析表明,该催化气化过程存在明显的补偿效应,最后给出黏胶废液对尤溪无烟粉煤水蒸气催化气化包括补偿效应的动力学方程。 相似文献
93.
Chen Rong Kazuya Mitsuji Xue Songtao Yoshihiro Sugimura Masanori Izumi 《Acta Mechanica Solida Sinica》1999,12(2):144-154
The purpose of this paper is to study the dynamic behavior of soft ground including a porous layer by considering the porosity
change. In order to take the porosity change into account, the concept of the volume fraction, which has been proposed in
continuum mechanics, is introduced. The constitutive equations presented by Bowen are applied to the analysis of the porous
media. According to Bowen's theory, the porosity is considered as a variable called the volume fraction and has its own constitutive
equation. The constitutive equation of the volume fraction has thermoelastic equation coefficients and is determined by the
strains of the solid and the fluid. This means that the compressibilities of the solid and the fluid are considered. When
the special condition is assumed, Bowen's theory can contain Biots's theory, which has been applied in earthquake engineering.
The wave propagation in the ground including a porous layer, modeled by Bowen's theory, is studied and compared with that
of Biot's theory. One-dimensional attenuation and surface amplitude are calculated. The effect of the volume fraction is discussed
with respect to the compressibilities of the solid and the fluid. 相似文献
94.
95.
Heavy tailed durations of regional rainfall 总被引:1,自引:0,他引:1
Durations of rain events and drought events over a given region provide important information about the water resources of
the region. Of particular interest is the shape of upper tails of the probability distributions of such durations. Recent
research suggests that the underlying probability distributions of such durations have heavy tails of hyperbolic type, across
a wide range of spatial scales from 2 km to 120 km. These findings are based on radar measurements of spatially averaged rain
rate (SARR) over a tropical oceanic region. The present work performs a nonparametric inference on the Pareto tail-index of
wet and dry durations at each of those spatial scales, based on the same data, and compares it with conclusions based on the
classical Hill estimator. The results are compared and discussed.
The authors express sincere thanks to the Mathematisches Forschungsinstitut Oberwolfach (MFO) for facilitating their collaboration
under a “Research in Pairs” project hosted at MFO during March 5–25, 2006. The research of the second and third authors was supported by the project
LC06024. 相似文献
96.
Tung‐Kung Wu Cheng‐Hsiang Chang Yuan‐Ting Liu Tsai‐Ting Wang 《Chemical record (New York, N.Y.)》2008,8(5):302-325
The oxidosqualene cyclases (EC 5.4.99‐) constitute a family of enzymes that catalyze diverse cyclization/rearrangement reactions of (3S)‐2,3‐oxidosqualene into a distinct array of sterols and triterpenes. The relationship between the cyclization mechanism and the enzymatic structure is extremely complex and compelling. This review covers the historical achievements of biomimetic studies and current progress in structural biology, molecular genetics, and bioinformatics studies to elucidate the mechanistic and structure–function relationships of the Saccharomyces cerevisiae oxidosqualene‐lanosterol cyclase‐catalyzed cyclization/rearrangement reaction. © 2008 The Japan Chemical Journal Forum and Wiley Periodicals, Inc. Chem Rec 8: 302–325; 2008: Published online in Wiley InterScience ( www.interscience.wiley.com ) DOI 10.1002/tcr.20157 相似文献
97.
Self‐excited oscillation can be induced due to the interaction between condensation process and local transonic condition in condensing flow, which is an important problem in wet steam turbine. With an Eulerian/Eulerian numerical model, the self‐excited oscillation of wet steam flow is investigated in a supersonic turbine cascade. Owing to supercritical heat addition to the subsonic flow in the convergent part of the cascade, the oscillation frequency decreases with increased inlet supercooling. Mass flow rate increases in the oscillating flow due to the greater supersaturation in condensation process, while the increase will be suppressed with the flow oscillation. Higher inlet supercooling leads to the fact that the condensation process moves upstream and the loss increases. Moreover, some predictions of oscillation effects on outflow angle and aerodynamic force are also presented. Finally, heterogeneous condensations with inlet wetness and periodic inlet conditions, as a result of the interference between stator and rotor, are discussed. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
98.
Jin Mu Zhenfang Gu Lei Wang Zhiqing Zhang Hua Sun Shi-Zhao Kang 《Journal of nanoparticle research》2008,10(1):197-201
MnS nanocrystals with different phases and shapes were prepared through solvothermal synthesis. The products were characterized
by X-ray diffraction (XRD), transmission electron microscope (TEM), UV–vis absorption and photoluminescence (PL) spectra.
The solvent and reaction time played an important role in controlling the phase and shape of MnS nanocrystals. The possible
mechanism of the shape evolution was investigated, which revealed that the crystal growth along the unique c axis of γ-MnS resulted in the rod-like MnS at the primary period, and the tetrahedral crystal seed of β-MnS with zincblende structure resulted in the interlinking of MnS rods, so the zigzag and three-branched and palm-like MnS
appeared; with increasing reactive time the thermodynamically stable spherical α-MnS was favored through the Ostwald ripening process. The PL results showed that the intensity of γ-MnS was much weaker than that of α-MnS, and the trap state emissions of γ-MnS at 470 and 482 nm, respectively, disappeared, which might be ascribed to the difference of the shapes between the sphere
and the rod or branch. 相似文献
99.
S. Freni N. Mondello S. Cavallaro G. Cacciola V.N. Parmon V.A. Sobyanin 《Reaction Kinetics and Catalysis Letters》2000,71(1):143-152
A two-layer fixed-bed catalytic reactor for hydrogen production by steam reforming of ethanol is proposed. In this reactor ethanol is first converted to acetaldehyde over a Cu-based catalyst and then acetaldehyde is converted to a hydrogen-rich mixture over a Ni-based catalyst. It is shown that the use of such type of reactor prevents coke formation and provides hydrogen yields closed to equilibrium. 相似文献
100.
湿法脱硫浆液中Hg的还原机制研究 《燃料化学学报》2017,45(6):755-760
针对燃煤电厂湿法脱硫浆液中Hg2+易被还原的特性,研究Hg2+在模拟湿法脱硫系统中的迁移机制,考察了浆液温度、pH值以及SO32-、Cl-、Ca2+、Mg2+浓度等因素对Hg2+还原性能的影响。结果表明,Hg2+还原率随着浆液中SO32-浓度的增大而降低;pH值对Hg2+的还原呈先增加后降低的趋势,在pH值为5.5时还原率最高;温度的升高不利于浆液中稳定的二价汞盐络合物存在,导致Hg2+还原率增加;Ca2+、Mg2+以及Cl-浓度的增加有利于形成稳定化合物,从而抑制Hg2+的还原。 相似文献