Quartz as a pressure sensor in the infrared

The pressure dependence of the 795 cm^?1 mode of quartz has been measured in the infrared up to 20 GPa at 300 and 400 K. For the measurements, which are impossible with a laser light, on photo sensitive or biological samples, we propose to use the pressure dependence of this mode as a pressure gauge.     

Effect of β-Nucleating Agent on the Crystallization,Mechanical Properties,and Heat Resistance of Injection-Molded Isotactic Polypropylene

Injection-molded β-isotactic polypropylene (β-iPP) was prepared with a commercial β-nucleating agent (NT-A). The effect of NT-A on the crystallization, mechanical properties, and heat resistance of β-iPP was investigated by differential scanning calorimetry (DSC), wide-angle X-ray diffraction (WAXD), polarized light microscopy (PLM), and mechanical and heat deflection tests. DSC and WAXD analysis showed that the content of β-crystals in the nucleated iPP was higher than that of pure iPP, and the content of β-crystals of the core was higher than that of the skin. PLM observations showed that injection-molded iPP had an obvious skin-core structure. NT-A induced abundant β-crystals and resulted in small spherulites which improved the Izod notched impact strength. When the content of NT-A was 0.075wt%, the Izod notched impact strength reached a maximum, 2.6 times more than that of pure iPP. The heat distortion temperature was also improved by NT-A.     

动态调整出水温度的高效制冷方法研究

通过数学方法较为精确地建立了吸收式制冷机需满足负荷要求的数学模型,确立了蒸发器冷冻水出口温度与室外温度之间的关系式。进而建立了吸收式出水温度控制系统的动态特性模型,并采用并联程序法对水温控制系统进行仿真。     

四级自动复叠系统压力保护装置的试验研究

针对五元混合工质四级自动复叠制冷循环系统启动压力过高和降温速率缓慢的问题,搭建了试验装置;设计了适合四级自动复叠循环系统的一种压力保护装置;分析了对系统压缩机吸排气压力和降温特性的影响。试验结果表明:所设计的压力保护装置能起到优化压缩机吸排气压力、加快降温速率的作用。     

Recyclable gold nanoparticle catalyst for the aerobic alcohol oxidation and C-C bond forming reaction between primary alcohols and ketones under ambient conditions

A recyclable gold catalyst is synthesized from readily available reagents by immobilizing gold nanoparticles in aluminum oxyhydroxide support through a simple sol-gel method. The catalyst showed the high activity even at room temperature in the aerobic oxidation of various alcohols and in the coupling reaction between primary alcohols and ketones.     

Investigation on LCST behavior of a new amorphous/crystalline polymer blend: Poly(n‐methyl methacrylimide)/poly(vinylidene fluoride)

The liquid–liquid phase‐separation (LLPS) behavior of poly(n‐methyl methacrylimide)/poly(vinylidene fluoride) (PMMI/PVDF) blend was studied by using small‐angle laser light scattering (SALLS) and phase contrast microscopy (PCM). The cloud point (T_c) of PMMI/PVDF blend was obtained using SALLS at the heating rate of 1 °C min^?1 and it was found that PMMI/PVDF exhibited a low critical solution temperature (LCST) behavior similar to that of PMMA/PVDF. Moreover, T_c of PMMI/PVDF is higher than its melting temperature (T_m) and a large temperature gap between T_c and T_m exists. At the early phase‐separation stage, the apparent diffusion coefficient (D_app) and the product (2Mk) of the molecules mobility coefficient (M) and the energy gradient coefficient (k) arising from contributions of composition gradient to the energy for PMMI/PVDF (50/50 wt) blend were calculated on the basis of linearized Cahn‐Hilliard‐Cook theory. The kinetic results showed that LLPS of PMMI/PVDF blends followed the spinodal decomposition (SD) mechanism. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 1923–1931, 2008     

低温地板辐射采暖系统的传热分析与仿真

建立了低温地板辐射供暖系统的传热过程的数学模型,用有限元法对数学模型进行求解。以一个动态仿真程序得出了不同供回水平均温度和排管间距下的地板表面最高温度和单位面积的热流量,阐明了系统的舒适和节能特性,为工程设计提供了理论依据。     

New rational fraction approximating formulas for the temperature integral

Three rational fraction approximations for the temperature integral have been proposed using the pattern search method. The validity of the new approximations has been tested by some numerical analyses. Compared with several published approximating formulas, the new approximations is more accurate than all approximations except the approximations proposed by Senum and Yang in the range of 5≤E/RT≤100. For low values of E/RT, the new approximations are superior to Senum-Yang approximations as solutions of the temperature integral.     

无源高温超导磁浮轴承两种方案比较

无源磁浮轴承的优点是结构简单、造价低廉、无需有源控制。文中探讨了两种无源磁浮轴承的方案 ;对两种方案的悬浮力、悬浮品质因数、悬浮刚度与悬浮稳定性进行了讨论、计算、比较 ;并且讨论了两种方案的优缺点及应用。比较结果表明 ,方案 1更适合于小型的飞轮储能系统 ,方案 2较适合于大中型飞轮储能系统。     

Further Study of A-Related Quantum Interference of П-State Diatomic on Collision-Induced Rotational Energy Transfer

In our previous theoretical studies [Meng-Tao Sun, Yong-Qing Lee, and Feng-Cai Ma, Chem. Phys.Lett. 371 (2003) 342], we have reported the quantum interference on collision-induced rotational energy transfer on CO (A1П, v = 3) with inert gases, which originates from the difference between the two A-related collision potential energy surfaces. The interference angle, which measures the degree of coherence, is presented in this paper. Based on the time-dependent first order Born approximation, taking into account the anisotropic Lennard-Jones interaction potentials, the relation of the interference angle with the factors, including experimental temperature, partner, and rotational quantum number, are obtained. The changing tendencies with them are discussed. This theoretical model is important to understanding and performing this kind of experiment.