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21.
The kinetics of electroreduction of Pd(II) complexes with -alanine, Pd(ala)2, is studied on a rotating Pd disk electrode in solutions of pH 8–13 containing large excess of -alanine and various supporting electrolytes (NaF, Na2SO4, NaClO4). On a Pd electrode, complexes Pd(ala)2 undergo reduction at potentials much more negative than on an Hg electrode. This is attributed to the chemisorption of water on the Pd electrode, which hampers adsorption of Pd(ala)2 that take part in the slow electrochemical stage. As with the Hg electrode, perchlorate ions hinder the Pd(ala)2 reduction on a Pd electrode. Studying adsorption of Pd(ala)2 on a Pd electrode is hampered by parallel processes of hydrogen adsorption and absorption. 相似文献
22.
In this paper, calculating the molecular internal rotating steric factor of polymers by the radiation crosslinking method is studied and a relationship between the molecular internal rotating steric factor (σ) and crosslinking parameter βis established~([1]) by taking account of the effect of polymer chain flexibility on βvalue, σvalue of polymer obtained by this method is in agreement with that given with other method. 相似文献
23.
Elastic Analysis of Anisotropic Functionally Graded Rotating Disks With Non-Uniform Thicknesses北大核心CSCD 下载免费PDF全文
研究了任意梯度变化的变厚度各向异性转动圆盘的弹性问题.假设圆盘绕刚性轴匀速转动,其材料性能和厚度沿径向任意梯度变化.考虑圆盘在中心转轴处受位移约束,外侧自由,根据各向异性转动圆盘的平衡微分方程,得到关于径向应力的Fredholm积分方程,继而通过对Fredholm积分方程进行数值求解,得到结构的位移场和应力场.对具体梯度变化情况仅需代入相应梯度变化进行求解即可.数值算例部分,通过假设厚度、弹性模量等参数为特殊的幂函数形式,将由Fredholm积分方程求出的数值解与对应的精确解进行对比,以及针对常见的Voigt模型,将由该方法算得的数值解和ANSYS有限元计算结果进行对比,验证了该方法的准确性和精度.其次,针对Voigt模型,重点分析了厚度变化、材料性能梯度参数、各向异性度等对应力场和位移场的影响.提出了针对材料性能和厚度沿径向呈任意梯度变化的圆盘结构弹性分析方法,将为优化功能梯度圆盘的结构和材料参数、有效调整构件应力分布、提高结构安全性,提供强有力的工具;算例分析结果对功能梯度圆盘在复杂条件下的结构安全设计有重要的理论指导意义. 相似文献
24.
A. I. Dikusar O. O. Redkozubova S. P. Yushchenko L. B. Kriksunov D. Harris 《Russian Journal of Electrochemistry》2003,39(10):1073-1077
Experimental study of the distribution of local rates of electrochemical micromachining in the presence of photoresist masks in various hydrodynamic conditions (macroscopically nonuniform rotating disk electrode, sprayer flow, an electrode placed into a cell with chaotic bulk electrolyte mixing) shows that the maximum etching localization is achieved at the control of the dissolution rate by the mass transport rate (at achieving the anodic limiting current). The localization enhancement as compared to the primary current distribution takes place in the case of a turbulent flow at hydrodynamic conditions where the removal of dissolution products from the undercutting region is hindered. These conditions (electrochemical reaction limited by the ion mass transport rate, high resistance to the mass transport in the undercutting region) are necessary for the localization enhancement using a pulsed anodic–cathodic treatment. 相似文献
25.
Richard J. Wiener Philip W. Hammer Charles E. Swanson David C. Samuels Russell J. Donnelly 《Journal of statistical physics》1991,64(5-6):913-926
Taylor-Couette flow subject to a Coriolis force is studied experimentally and numerically. In the experiment, the Couette apparatus is mounted on a turntable with the axis of the cylinders orthogonal to the rotation vector of the turntable. The Coriolis force stabilizes the fluid against the onset of Taylor vortices and alters the velocity fields, both above and below the transition from the initial flow. At small dimensionless turntable frequencies, the transition yields time-independent Taylor vortices which are tilted with respect to the cylinder axis. At larger there is a direct transition to turbulence. We determine the first-order correction to the classical Couette initial flow, to account for the effects of the Coriolis force, by expanding in powers of. We present numerical results for the axial velocity (the only nonvanishing correction term to order) in the infinite-cylinder approximation. 相似文献
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A nanofluid is composed of a base fluid component and nanoparticles, in which the nanoparticles are dispersed in the base fluid. The addition of nanoparticles into a base fluid can remarkably improve the thermal conductivity of the nanofluid, and such an increment of thermal conductivity can play an important role in improving the heat transfer rate of the base fluid. Further, the dynamics of non-Newtonian fluids along with nanoparticles is quite interesting with numerous industrial applications... 相似文献
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研究了真空状态下保温60 min不同退火温度对镜面纯铁的表面粗糙度、表面形貌及晶粒取向的影响。结果表明:在纯铁的多晶型性转变温度点以下,面均方根粗糙度随退火温度的升高而缓慢增大;在多晶型性转变温度及以上发生突变,从面均方根粗糙度为4~5 nm的镜面突变到700 nm;用扫描电子显微镜(SEM)观察样品表面,发现在810 ℃出现再结晶细小晶粒。研究了原材料及860~960 ℃之间几个温度点的X射线衍射{200}晶面极图,结果发现:晶粒在860 ℃开始择优取向,随温度升高,取向越来越明显;再结晶对表面粗糙度的影响不大,晶粒的择优取向使得晶粒在不同方向的膨胀系数不同,以及多晶型性转变导致体积的变化使得晶粒之间挤压造成晶粒之间的凹凸不平和表面较深较粗的晶界,这是造成粗糙度突变的主要原因。 相似文献
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