全文获取类型
收费全文 | 866篇 |
免费 | 158篇 |
国内免费 | 117篇 |
专业分类
化学 | 685篇 |
晶体学 | 7篇 |
力学 | 36篇 |
综合类 | 19篇 |
数学 | 188篇 |
物理学 | 206篇 |
出版年
2024年 | 1篇 |
2023年 | 10篇 |
2022年 | 24篇 |
2021年 | 32篇 |
2020年 | 30篇 |
2019年 | 39篇 |
2018年 | 13篇 |
2017年 | 36篇 |
2016年 | 49篇 |
2015年 | 36篇 |
2014年 | 62篇 |
2013年 | 88篇 |
2012年 | 56篇 |
2011年 | 58篇 |
2010年 | 38篇 |
2009年 | 48篇 |
2008年 | 45篇 |
2007年 | 51篇 |
2006年 | 60篇 |
2005年 | 45篇 |
2004年 | 42篇 |
2003年 | 40篇 |
2002年 | 40篇 |
2001年 | 21篇 |
2000年 | 23篇 |
1999年 | 26篇 |
1998年 | 17篇 |
1997年 | 19篇 |
1996年 | 16篇 |
1995年 | 12篇 |
1994年 | 11篇 |
1993年 | 12篇 |
1992年 | 3篇 |
1991年 | 6篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1987年 | 8篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1977年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有1141条查询结果,搜索用时 187 毫秒
141.
在线反向拍卖在当今的经济社会发展中扮演越来越重要的角色,其主要应用于采购招标领域。而在实际的采购拍卖中有关商品属性和供应商信息等方面常会存在一定程度的不确定性,且这些不确定性的刻画又存在着多种模糊表述形式,这些都将增加采购方的风险预期和竞标供应商赢者确定的难度。为此,本文基于前景理论及模糊集理论,研究了同时存在精确数、区间数、三角模糊数、梯形模糊数和语义模糊术语五种属性描述方式的在线多属性反向拍卖的赢者确定问题,提出了一种更具一般性的混合不确定情景下的在线多属性反向拍卖赢者(中标者)确定方法。最后,通过数值算例和比较分析验证了本文所提方法的合理性与有效性,并通过稳健性分析进一步说明方法的稳定性和适用性。 相似文献
142.
Working within Bishop‐style constructive mathematics, we examine some of the consequences of the anti‐Specker property, known to be equivalent to a version of Brouwer's fan theorem. The work is a contribution to constructive reverse mathematics (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
143.
In this paper, we give the definition of weak WT2-class of differential forms, and then obtain its weak reverse Holder inequality. As an application, we give an alternative proof of the higher integrability result of weakly A-harmonic tensors due to B. Stroffolini. 相似文献
144.
产品回收逆向物流网络设计问题的两阶段启发式算法 总被引:1,自引:0,他引:1
针对产品回收逆向物流网络设计问题,设计了一种嵌套了模拟退火算法的两阶段启发式算法。第一阶段确定回收点的选址-分配-存储的联合决策;第二阶段确定回收中心的选址-运输的联合决策,两个阶段相互迭代,从而实现最优解的搜索。通过与遗传算法比较,证明了两阶段启发式算法是一种有效的算法。 相似文献
145.
Let L =△ + V be a SchrSdinger operator in Rd, d ≥ 3, where the nonnegative potential V belongs to the reverse HSlder class Sd. We establish the BMOL-boundedness of Riesz transforms З/ЗxiL-1/2, and give the Fefferman-Stein type decomposition of BMOL functions. 相似文献
146.
In this paper we consider the SchrSdinger operator -△G + W on the nilpotent Lie group G where the nonnegative potential W belongs to the reverse H51der class Bq1 for some q1 ≥ D and D is the dimension at infinity of G. The weighted L^p -L6q estimates for the operators W^a(-△G + W)^-β and W^a△G(-△G + W)^-β are obtained. 相似文献
147.
Jun Cao Lifen Zhang Xiaowu Jiang Chun Tian Xiaoning Zhao Qi Ke Xiangqiang Pan Zhenping Cheng Xiulin Zhu 《Macromolecular rapid communications》2013,34(22):1747-1754
An iron‐mediated reverse ATRP of methyl methacrylate (MMA) is successfully carried out in water in the absence of any dispersants, using a water‐soluble 2,2′‐azobis(2‐methylpropionamidine) dihydrochloride (V‐50) as the initiator and the stabilizer, and using an oil‐soluble N,N‐butyldithiocarbamate ferrum (Fe(S2CN(C4H9)2)3) as the catalyst without adding any additional ligands. Micron‐sized PMMA particles with UV light‐sensitive ‐S2CN(C4H9)2 end group are obtained, and monomer droplet nucleation and suspension polymerization mechanism are proposed. Polymerization results demonstrated typical “living”/controlled characteristics of ATRP: first‐order polymerization kinetics, linear increase of molecular weights with monomer conversion and narrow molecular weight distributions for the resultant PMMA particles. NMR spectroscopy and chain‐extension experiments under UV light irradiation confirm the attachment and livingness of UV light‐sensitive ‐S2CN(C4H9)2 group in the chain end.
148.
Formation of reverse micelles in the water–hexane–AOT system has been investigated by molecular dynamics simulations. In order to optimize calculation strategy, the starting spatial disposition of components was assumed to be random. Such an approach was found to provide a lower dependence of final results on initial conditions as compared to the calculations using pre-assembled reverse micelles as a starting geometry. The calculated structural parameters of reverse micelles (such as their shape, size, and distribution of components) were found to agree with the available experimental data. 相似文献
149.
150.
Paulo A. R. Pires Muhammad Imran Carina Loffredo Paulo M. Donate Daniel Previdi Omar A. El Seoud 《Journal of Physical Organic Chemistry》2013,26(3):280-285
The effects of solvents on chemical phenomena (rate and equilibrium constants, spectroscopic transitions, etc.) are conveniently described by solvation free‐energy relationships that take into account solvent acidity, basicity and dipolarity/polarizability. The latter can be separated into its components by manipulating the UV–vis spectra of two solvatochromic probes, 2‐(N,N‐dimethylamino)‐7‐nitrofluorene (DMANF) and a di‐(tert‐butyl)‐tetramethyl docosanonaen probe (ttbP9) whose synthesis is laborious and expensive. Recently, we have shown that the natural dye β‐carotene can be conveniently employed instead of ttbP9 for the determination of solvent polarizability (SP) of 76 molecular solvents and four ionic liquids. In the present work, we report the polarizabilities of further 24 solvents. Based on the solvatochromism of β‐carotene and DMANF, we have calculated solvent dipolarity (SD) for 103 protic and aprotic molecular solvents, and ionic liquids. The dependence of SD and SP on the number of carbon atoms in the acyl‐ or alkyl group of several homologous series (alcohols; 2‐alkoxyethanols; carboxylic acid‐ anhydrides, and esters, ionic liquids) is calculated and briefly discussed. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献