New stationary phase polarity parameters considering the electric intermolecular interactions in gas chromatographic column

Summary The possibility of evaluation of the parameters representing the dispersive solute-solvent interactions is presented. B_N and B_s values can be used to describe the liquid phase polarity and to predict the retention indices of alcohols when the model polyxyethylene glycol dialkyl ethers and their sulphur analogs are used as stationary phases. The possibility of the first ionization potentials estimation is also presented.     

油页岩的~(13)C-NMR特征及FLASHCHAIN热解模拟研究

采用固体13C-NMR核磁共振技术表征了甘肃窑街矿区油页岩的碳骨架结构,分析并计算了油母质团簇化学结构参数,包括团簇平均碳原子数、芳碳原子数、脂碳原子数及芳环数。在热重红外分析仪(TG-FTIR)上进行了油页岩的热解实验,得到了热解产物的生成规律。结合样品的团簇化学结构参数,采用基于油页岩结构的FLASHCHAIN模型模拟其热解产物的生成过程;模拟结果与TG-FITR实验数据符合较好,印证了模型预测的合理性。     

不同压电分流电路对声子晶体梁带隙的影响

通过在匀质基体梁上周期性对贴连有分流电路的压电片,可以形成一维声子晶体结构.不同分流电路将决定梁的带隙特性.电阻分流电路能够对梁的模态共振有一定的抑制作用,而且可以通过改变压电效应的强弱使Bragg带隙结构发生变化.LC分流电路会使梁产生局域共振带隙,其带隙是由压电片激励LC电路产生电磁振荡形成.引入电阻后会使LC电路的共振作用变弱,使得带隙衰减幅值变小,但可以扩宽带隙频率范围.     

广义Woods-Saxon势的转移共振

本文严格求解了一维广义Woods-Saxon势的薛定谔方程,导出了用超几何函数表达的散射态波函数,获得了转移和反射系数的解析表达式。利用波函数的连续性条件,计算了在广义Woods-Saxon势中运动粒子的转移和反射系数。特别地,详细分析了转移共振和广义Woods-Saxon势的参数关系,展示了发生转移共振的条件。     

基于加速度响应控制时MTMD的地震特性

研究了由多个刚度和阻尼保持为常量且频率呈线性分布的TMD形成的MTMD的地震特性。基于虚拟激励法和Kanai Tajimi及Clough Penzien地震谱 ,建立了结构 MTMD系统的加速度传递函数 ,进而导出了设置MTMD时结构的加速度动力放大系数 (ADMF)明确表达式。于是MTMD的优化准则选择为 :结构最大加速度动力放大系数的最小值的最小化 [Min .Min .Max .ADMF]。通过最优搜寻得MTMD的最优频率间隔、平均阻尼比、调谐频率比和相应的控制有效性指标。选择结构受控频率与地震卓越频率比的不同取值 ,研究地震卓越频率对MTMD最优参数及有效性的影响     

Rod‐Like Nano‐Light Harvester

Imitating the natural “energy cascade” architecture, we present a single‐molecular rod‐like nano‐light harvester (NLH) based on a cylindrical polymer brush. Block copolymer side chains carrying (9,9‐diethylfluoren‐2‐yl)methyl methacrylate units as light absorbing antennae (energy donors) are tethered to a linear polymer backbone containing 9‐anthracenemethyl methacrylate units as emitting groups (energy acceptors). These NLHs exhibit very efficient energy absorption and transfer. Moreover, we manipulate the energy transfer by tuning the donor–acceptor distance.

     

Fluorescence resonance energy transfer in doubly-quantum dot labeled IgG system

The mouse immunoglobulin G (mouse IgG) as a kind of bio-molecule was labeled with two different luminescent colloidal semiconductor quantum dots (QDs), green-emitting CdTe quantum dots and red-emitting CdTe quantum dots in this work. As a result of the fluorescence resonance energy transfer (FRET) between the two different sizes nanoparticles with mouse IgG as the binding bridge, a significant enhancement of the emission of the red-emitting CdTe quantum dots and the corresponding quenching of the emission of green-emitting CdTe quantum dots were observed. The relationship between the concentration of the mouse immunoglobulin G and the fluorescence intensity ratio (I_a/I_d) of acceptors and donors was studied also. Under optimal conditions, the calibration graph is linear over the range of 0.1–20.0 mg/L mouse IgG.     

Interplay between out-of-plane magnetic plasmon and lattice resonance for modified resonance lineshape and near-field enhancement in double nanoparticles array

Two-dimensional double nanoparticle （DNP） arrays are demonstrated theoretically, supporting the interaction between out-of-plane magnetic plasmons and in-plane lattice resonances, which can be achieved by tuning the nanoparticle height or the array period due to the height-dependent magnetic resonance and the periodicity-dependent lattice resonance. The interplay between the two plasmon modes can lead to a remarkable change in resonance lineshape and an improvement on magnetic field enhancement. Simultaneous electric field and magnetic field enhancement can be obtained in the gap region between neighboring particles at two resonance frequencies as the interplay occurs, which presents “open” cavities as electromagnetic field hot spots for potential applications on detection and sensing. The results not only offer an attractive way to tune the optical responses of plasmonic nanostructure, but also provide further insight into the plasmon interactions in periodic nanostructure or metamaterials comprising multiple elements.     

Site selection NMR study on electronic state in and near vortex core of YBa2Cu4O8

We report a site-selective ¹⁷O spin-lattice relaxation rate T₁⁻¹ in the vortex state of YBa₂Cu₄O₈. We found that T₁⁻¹ at the planar sites exhibits an unusual nonmonotonic NMR frequency dependence. Based on T₁⁻¹ in the vortex core region, we establish strong evidence that the local density of states within the vortex core is strongly reduced.     

负偏压下Ag@AgBr/Ni膜电极光电催化降解罗丹明B的性能和机理

用电化学方法制备Ag@Ag Br/Ni表面等离子体薄膜电极,以扫描电子显微镜(SEM)、X射线衍射(XRD)和紫外-可见漫反射光谱(UV-Vis DRS)对薄膜的表面形貌、晶相结构、光吸收特性进行了表征,在负偏压和可见光作用下,以罗丹明B为模拟污染物对薄膜的光催化活性和稳定性进行了测定,采用电化学技术和向溶液中加入活性物种捕获剂的方法对薄膜光电催化降解机理进行了探索。结果表明:最佳工艺下制备的Ag@Ag Br/Ni膜电极是由表面沉积纳米Ag的纳米晶Ag Br颗粒构成的薄膜,具有显著的表面等离子共振效应。薄膜具有优异的光电催化活性和良好的催化稳定性,在最佳负偏压和可见光照射下反应12 min,薄膜光电催化罗丹明B(c=5 mg·L~(-1))的降解率是多孔Ti O2(P25)/ITO纳米薄膜的10.2倍。相对于未加偏压的光催化,降解率提高了2.0倍;在保持薄膜光催化活性基本不变的前提下可循环使用5次。电极表面纳米Ag粒子的等离子体共振对于光阴极反应(导带反应)的活化作用是光电催化活性提高的重要原因。提出了负偏压下Ag@Ag Br/Ni表面等离子体薄膜光电催化降解罗丹明B的反应机理。