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121.
《Particuology》2023
The energy density of Li-ion batteries is closely related to the capacity and average voltage of cathode materials. Unfortunately, current cathode materials either have low capacity or voltage, which limits the development of high-energy-density Li-ion batteries. This has given challenge to many attempts to develop new cathode materials with high capacity and voltage. In this study, we find that Li easily inserts into the (111) plane of SiC in the presence of Si, and a well-organized Li-rich SiC twin crystal is formed. Ultraviolet–visible diffuse reflectance spectra and electrochemical test results suggest that this Li-rich SiC twin crystal possesses the band gap energy of 3.5 eV and charging capacity of 1979 mAh/g at the current density of 200 mA/g, making it a promising candidate for the cathode material in high-capacity Li-ion batteries. X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy results reveal that Si-induced Li insertion contributes to the changes in the surface species and structure of pristine SiC. These findings suggest that the Li-rich SiC twin crystal raises new possibilities for the development of high-capacity cathode materials and merits further investigation to expand its application scope. 相似文献
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124.
Ning Yu Jing-Fang Lv Shi-Mei He Yanyan Cui Ye Wei Kun Jiang 《Molecules (Basel, Switzerland)》2022,27(23)
In the presence of CuOAc, a series of unsymmetric ureas can be generated in moderate to good yields under mild reaction conditions (10 mol% of CuOAc, 2 equiv t-BuONa or PhONa, 30 °C), using aryl isocyanides and O-benzoyl hydroxylamines as the readily accessible starting materials. The reactions might undergo a cascade process involving isocyanide insertion into the N-O bond and Mumm-type rearrangement. This work represents a rare example of isocyanide insertion into N-O bonds, which would extend isocyanide insertion chemistry. 相似文献
125.
现有的不同厂家的SDH设备网管信息不能实现互通,为了解决这一问题,提出了一种SDH网管信息提取和插入系统的软硬件设计方案,主要包括网管信息的提取和插入、HDLC数据的封装和拆封、利用主控制器和USB模块进行数据传输,从而实现网管信息的高速上传并在上位机实时显示和保存功能。最后对该系统进行了测试验证,结果表明该系统能分析不同的SDH设备网管信息,为网管信息互通提供了基础信息。 相似文献
126.
The reaction of phenyliodonium bis(phenylsulfonyl)methylide with flavones affords insertion products into the alkenyl carbon-hydrogen bond of the flavone, presumably by an electrophilic attack of the iodonium ylide on the double bond of the flavone. 相似文献
127.
Let G be a graph. An independent set Y in G is called an essential independent set (or essential set for simplicity) if there is {y1,y2} (?) Y such that dist (y1,y2) = 2. In this paper, we use the technique of the vertex insertion on l-connected (l = k or k + 1, k≥ 2) graphs to provide a unified proof for G to be hamiltonian, or hamiltonian-connected. The sufficient conditions are expressed 相似文献
128.
T.S. Arthanari 《Discrete Mathematics》2006,306(14):1474-1492
In this paper we define a combinatorial object called a pedigree, and study the corresponding polytope, called the pedigree polytope. Pedigrees are in one-to-one correspondence with the Hamiltonian cycles on Kn. Interestingly, the pedigree polytope seems to differ from the standard tour polytope, Qn with respect to the complexity of testing whether two given vertices of the polytope are nonadjacent. A polynomial time algorithm is given for nonadjacency testing in the pedigree polytope, whereas the corresponding problem is known to be NP-complete for Qn. We also discuss some properties of the pedigree polytope and illustrate with examples. 相似文献
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In this paper a theoretical analysis of the performance of a parallel form of the Quicksort algorithm is presented and shown to be in qualitative agreement with experiments carried out on the Loughborough University NEPTUNE parallel system. 相似文献