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81.
82.
Remigijus Mikulevičius 《随机分析与应用》2015,33(3):549-571
This article studies the rate of convergence of the weak Euler approximation for Itô diffusion and jump processes with Hölder-continuous generators. It covers a number of stochastic processes including the nondegenerate diffusion processes and a class of stochastic differential equations driven by stable processes. To estimate the rate of convergence, the existence of a unique solution to the corresponding backward Kolmogorov equation in Hölder space is first proved. It then shows that the Euler scheme yields positive weak order of convergence. 相似文献
83.
Assessment of the various ionization methods in the analysis of metal salen complexes by mass spectrometry 下载免费PDF全文
Beata Słomińska Wojciech Chaładaj Witold Danikiewicz 《Journal of mass spectrometry : JMS》2014,49(5):392-399
Metal salen complexes are one of the most frequently used catalysts in enantioselective organic synthesis. In the present work, we compare a series of ionization methods that can be used for the mass spectral analysis of two types of metalosalens: ionic complexes (abbreviated as Com+X?) and neutral complexes (NCom). These methods include electron ionization and field desorption (FD) which can be applied to pure samples and atmospheric pressure ionization techniques: electrospray ionization (ESI), atmospheric pressure chemical ionization (APCI) and atmospheric pressure photoionization (APPI) which are suitable for solutions. We found that FD is a method of choice for recording molecular ions of the complexes containing even loosely bonded ligands. The results obtained using atmospheric pressure ionization methods show that the results depend mainly on the structure of metal salen complex and the ionization method. In ESI spectra, Com+ ions were observed, while in APCI and APPI spectra both Com+ and [Com + H]+ ions are observed in the ratio depending on the structure of the metal salen complex and the solvent used in the analysis. For complexes with tetrafluoroborate counterion, an elimination of BF3 took place, and ions corresponding to complexes with fluoride counterion were observed. Experiments comparing the relative sensitivity of ESI, APCI and APPI (with and without a dopant) methods showed that for the majority of the studied complexes ESI is the most sensitive one; however, the sensitivity of APCI is usually less than two times lower and for some compounds is even higher than the sensitivity of ESI. Both methods show very high linearity of the calibration curve in a range of about 3 orders of magnitude of the sample concentration. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
84.
We have compared the structure, microstructure, and electrochemical characteristics of xLi2MnO3–(1−x)Li(Mn0.375Ni0.375Co0.25)O2 (0.0 ≤ x ≤ 1.0) thin films with their bulk cathode laminate counterparts of identical compositions. Pure Li(Mn0.375Ni0.375Co0.25)O2 as well as the synthesized composite films partially transform into cubic spinel structure during charge–discharge cycling. In contrast, such layered to spinel phase transformation has only been identified in bulk cathode laminates with x ≥ 0.75. At a current density 0.05 mAcm−2, the discharge capacity of Li(Mn0.375Ni0.375Co0.25)O2 thin film was measured to be ∼60 μAhcm−2. The discharge capacity (∼217 μAhcm−2) was markedly improved in x∼0.5 composite thin film. The capacity retention after 20 charge discharge cycles are improved in composite films; however, their capacity fading could not be eliminated completely. 相似文献
85.
Dmitri O. Charkin Stanislav I. Bezzubov Oleg I. Siidra Artem S. Borisov Stepan N. Kalmykov 《无机化学与普通化学杂志》2020,646(11-12):540-543
Crystals of a new uranyl sulfate (C2N4H8S2)[UO2(SO4)2] · 0.3H2O ( 1 ) templated by a relatively rare bis-isothiouronium cation, were formed upon evaporation of aqueous solutions containing uranyl acetate, thiourea, and excess sulfuric acid. The new compound is orthorhombic, P212121, a = 6.928(2) Å, b = 13.398(3) Å, c = 15.225(3) Å, Z = 2. Its crystal structure is comprised of [UO2(SO4)2] moieties linked by hydrogen bonds formed between the template cations and terminal oxygen atoms of the sulfate tetrahedra. The C2N4H8S22+ template is most likely formed in situ during a redox reaction between uranyl cation and thiourea in a strongly acidic medium, with UO22+ partially reduced to U4+. 相似文献
86.
修理设备可更换且修理有延迟的两不同型部件并联可修系统 总被引:5,自引:0,他引:5
假定部件的寿命服从指数分布,其修理延迟时间和修理时间均服从一般分布,并且修理设备的寿命服从指数分布,其更换时间服从一般分布,利用马尔可夫更新过程理论和一种新的分解方法,研究了修理设备可更换且修理有延迟的两不同型部件并联可修系统,求得了系统和修理设备有关可靠性指标的一系列结果. 相似文献
87.
The purpose of this paper is to consider the expected value of a discounted penalty due at ruin in the Erlang(2) risk process under constant interest force. An integro-differential equation satisfied by the expected value and a second-order differential equation for the Laplace transform of the expected value are derived. In addition, the paper will present the recursive algorithm for the joint distribution of the surplus immediately before ruin and the deficit at ruin. Finally, by the differential equation, the defective renewal equation and the explicit expression for the expected value are given in the interest-free case. 相似文献
88.
We consider a continuous-time random walk which is the generalization, by means of the introduction of waiting periods on sites, of the one-dimensional non-homogeneous random walk with a position-dependent drift known in the mathematical literature as Gillis random walk. This modified stochastic process allows to significantly change local, non-local and transport properties in the presence of heavy-tailed waiting-time distributions lacking the first moment: we provide here exact results concerning hitting times, first-time events, survival probabilities, occupation times, the moments spectrum and the statistics of records. Specifically, normal diffusion gives way to subdiffusion and we are witnessing the breaking of ergodicity. Furthermore we also test our theoretical predictions with numerical simulations. 相似文献
89.
《Current Applied Physics》2020,20(1):82-88
A detailed investigation about the effect of Sc2O3: 1 mol%Ho3+/5 mol%Yb3+ co-doped with Ce4+ ions prepared by sol-gel methods was performed systematically. Under the excitation of 980 nm laser diode, both green emission (553 nm, 5F4/5S2→5I8) and red emission (672 nm, 5F5→5I8) were both observed in the emission spectra of the samples, which were found to be two-photon process and sensitized by Yb3+ ions. With the increasing of Ce4+ ions, the up-conversion green emission intensity are increased by 6.52, 8.69, 10.85, 13.92 and 16.66 fold, corresponding to the Ce4+ ions concentrations from 5 mol% to 13 mol%, respectively. The number of photons are necessary to populate the upper emitting state decreases to 2 and the infrared absorption coefficient is reduced, when the Ce4+ ions concentration increase to 13 mol%. Ce4+ ions play an important role in tailoring the local crystal field around Ho3+ ions, lowering the highest phonon cut-off energy of matrix and reducing the infrared absorption coefficient, thus hindering the non-radiative processes, which contribute to the increased emission intensity. The excellent enhancement makes it a promising multifunctional optical luminescence material. 相似文献
90.
ZENG ZhenHua MA XiuFang DING WuChen & LI WeiXue State Key Laboratory of Catalysis Center for Theoretical Computational Chemistry Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian China 《中国科学:化学》2010,(2)
Combined with third generation synchrotron radiation light sources, X-ray photoelectron spectroscopy (XPS) with higher energy resolution, brilliance, enhanced surface sensitivity and photoemission cross section in real time found extensive applications in solid-gas interface chemistry. This paper reports the calculation of the core-level binding energy shifts (CLS) using the first-principles density functional theory. The interplay between the CLS calculations and XPS measurements to uncover the structures,... 相似文献