苯甲酰基硫代苯甲酸-S-苯酯的双重磷光研究

在对不同取代的苯甲酰基硫代苯甲酸-S-苯酯的光物理性质进行研究时,发现其苯甲酰基在邻位时可观测到双磷光现象,本工作对这种现象的机理进行了研究,确定这种现象是由于溶剂的作用,使溶液中具有多种不同的构象体,不同异构体的磷光发射不同,其激发波长也不同,改变激发波长可观察到双重磷光现象。     

RADIATIVE FORCING AND GREENHOUSE EFFECT DUE TO THE ATMOSPHERIC TRACE GASES

The radiative forcing and greenhouse effect due to the atmospheric trace gases have been calculated by using an advanced radiative-convective model developed in this paper. The relationship between radiative forcing and concentration is given for each trace gas. The resuhs show that (ⅰ) the radiative forcing and then the greenhouse effect are significantly affected by the overlapping of atmospheric absorption bands; (ⅱ) the increasing concentration of trace gases other than CO_2, such as CH_4, N_2O, CFCs, etc., may potentially play an important role in the future global warming;(ⅲ) the proposed substitutes, such as HCFC124 and HFC125, for the chlorofluorocarbons which are considered to destroy the ozone layer have still considerable greenhouse effect even though their ozone depletion potentials are much smaller than CFCs; and (ⅳ) the feedback processes within the earth-atmosphere system have important effect on the surface temperature change due to the radiative forcing to the system.     

对固体圆二色光谱测试方法的再认识——兼谈“浓度效应”

对近期发展的固体圆二色(CD)光谱测试方法进行了概述、评价和比较, 着重探讨了“浓度效应”的存在使固体CD光谱失真的原因. 通过对本课题组和其他作者已报道的四种化合物的固体CD谱再测试的反思, 强调了依手性化合物的手性光谱学性质不同, 根据浓度梯度实验选择其合适测试浓度的必要性. 对固有手性的阻转异构化合物(S)-1,1'-联二萘酚(S-BINOL)进行了成膜法固体CD谱浓度梯度测试, 发现所得固体薄膜CD谱中也存在着“浓度效应”     

二茂铁硫醇自组装膜的电化学行为及其离子对效应

详细了研究１０－二基铁－１－癸硫醇（ＨＳＣ１０Ｆｃ）在金基底上形成的自组装单分子膜的电化学行为,发现ＨＳＣ１０Ｆｃ在金基底上形成稳定的自组装膜,并且在０．１ｍｏｌ／Ｌ的ＨＣｌＯ４溶液中表现出可逆的氧化还原行为,但其氧化还原峰的峰形和峰位极易溶液中阴离子种类和浓度的影响,考察了二茂铁自组装膜及通过后置换形成的二茂铁硫醇／十二烷基硫醇混合膜在混合电解液中的电化学行为,直接比较了两种不同阴离子与二茂铁阳     

An experimental method for testing the solvophobic theory by using graphitized carbon black in GC and LC

Summary The net solvent effect for several solute-solvent pairs has been calculated by using the solvophobic approach for describing the liquid chromatographic process. For the same solutes and solvents the net solvent effect has been experimentally measured by using graphitized carbon black columns in GC and HPLC. A comparison between the measured and calculated values made in terms of normalized free energy changes, indicates that the solvophobic theory is fairly adequate for predicting the sequence of solvent strength and provides a comprehensive explanation of the various interactions occurring in reversed-phase LC. A critical discussion of the deviations of the theory from the experimental data is also presented.Presented at the 14th International Symposium on Chromatography London, September, 1982     

大学数学“1+X”教学模式的探讨与思考

通过对课堂教学,课后作业,考试方式等环节的讨论,对大学数学"1+X"教学模式进行了探讨,对提高大学数学的教学效果作了一些思考.     

2014“高教社杯”全国大学生数学建模竞赛颁奖仪式在海军航空工程学院青岛校区举行

<正>2014年12月20日,2014"高教社杯"全国大学生数学建模竞赛颁奖仪式暨工作会议在海军航空工程学院青岛校区隆重举行。全国大学生数学建模竞赛组委会主任、复旦大学李大潜院士,海军航空工程学院政委龚理华少将,山东省教育厅宋承祥副厅长,高等教育出版社林金安副总编辑,中国科学院袁亚湘院士,全国大学生数学建模竞赛组委会副主任、专家组组长、浙江大学陈叔平教授等160余人出席了颁奖仪式。颁奖仪式由全国组委会秘书长、清华大学谢金星教授主持。颁奖仪式上,学院龚理华     

居民生活碳排放抽样调查方案设计:以青海省为例

调查方案设计是居民生活碳排放调查及数据分析的基础和保证.以大量文献和作者在居民生活碳排放调查中的实践经验为基础,立足调查方案的科学性和实践操作的可行性,以青海省为例,从居民生活碳排放调查的统计量选取、抽样框的构建、抽样方法的选择和样本量的确定、调查方案实施的详细步骤4方面综述性归纳了一套居民生活碳排放调查方案设计的方法,以期为居民生活碳排放研究提供参考.     

品牌体验对品牌忠诚的影响机制分析——基于餐饮品牌的实证研究

本文以餐饮品牌为研究对象,探讨了包括感官体验、情感体验和关联体验三个维度的品牌体验对品牌忠诚的影响机制,基于对388份问卷数据的分析,我们发现:除感官体验维度对态度忠诚存在直接的正向影响之外,品牌体验的其他各维度对态度忠诚和行为忠诚均无直接作用;品牌体验的三个维度均可通过感知价值和顾客满意对品牌忠诚产生间接影响,其中感官体验的效应最大,其次为情感体验,关联体验相对较低。     

Improved estimators for the GMANOVA problem with application to Monte Carlo simulation

The problem of finding classes of estimators which improve upon the usual (e.g., ML, LS) estimator of the parameter matrix in the GMANOVA model under (matrix) quadratic loss is considered. Classes of improved estimators are obtained via combining integration-by-parts methods for normal and Wishart distributions. Also considered is the application of control variates to achieve better efficiency in multipopulation multivariate simulation studies.