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F. D. Saccone C. E. Rodríguez Torres F. H. Sánchez M. B. Fernández van Raap 《Hyperfine Interactions》2001,134(1):123-129
RE2Fe14B (RE=rare earth) materials are capable of absorbing hydrogen to form a stable solid solution at room temperature. Hydrogenation produces a number of significant changes in the hyperfine interactions. In this work, 57Fe Mössbauer effect spectroscopy and X-ray diffraction measurements were performed on Nd14.01Hf0.08Fe78.91B7.00 alloys submitted to thermal treatment in hydrogen atmosphere. A non-linear increase of the hyperfine fields and isomer shifts with hydrogen concentration was observed. The hyperfine parameters of the 8j1 site exhibit a rather different evolution than those experienced by the other major sites (8j2, 16k1, 16k2). The origin of the hyperfine field enhancement is analyzed in terms of volume expansion and H nearest neighbors to the Fe sites. A linear expression on these two effects to give account of isomer shift evolution for 8j1 site is given. 相似文献
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微波分光仪上双缝干涉实验中参数的选取 总被引:2,自引:0,他引:2
双缝干涉和双缝衍射其本质都是相干波的迭加,干涉和衍射没有严格的固定分界线。实验中为充分体现双缝干涉特征及规律,应恰当地选择和设定实验参数,并对双缝干涉的实验结果与杨氏双缝干涉及双缝衍射的结果进行对比讨论 相似文献
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The processes of electron transfer and dissociative scattering are explored for collisions of hyperthermal NO+ on GaAs(110). The experiments reveal a marked angular dependence to O− emergence. A strong correlation between the O− scattering angle and the final atom-surface interaction site provides a map of the lateral dependence to reactivity. The results are modeled by sequential neutralization, dissociation, and electron attachment steps. Classical trajectory calculations, in conjunction with an empirical opacity function, accurately reproduce the experimental results. The opacity function is interpreted as the probability that an electron will attach to a departing O fragment as a function of the last surface site the atom impacts. The experiments indicate that O− emergence occurs predominantly for oxygen atoms which come in close contact with the localized dangling bond states of GaAs(110). 相似文献
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The perylene iodine system was prepared by a vapour-phase reaction without the use of solvents. Compositions between peryleneI2 and peryleneI6 were synthesized and studied by gravimetric analysis, infrared spectroscopy, X-ray diffraction and temperature-dependent resistivity measurements. Infrared spectra in the region 400–4000 cm−1 taken after different amounts of iodine were removed from the sample are distinct from perylene with new absorption lines at 1551 and 1302 cm−1 and shifts of some perylene frequencies. Powder X-ray diffraction measurements indicate that the lattice is monoclinic with parameters a=11.65 Å, b=10.85 Å, c=10.1 Å, β=100.5°. The (1 0 0) reflection, which is forbidden in the space group of perylene, is observed from the compound. The material is electrically conductive and obeys Ohm's law at high temperatures. At low temperatures and high currents, nonlinear effects are observed. The conductivity of the material increases to 1.0 (Ω cm)−1 at room temperature as the iodine content increases to a composition of peryleneI6. The resistivity obeys an exponential temperature dependence. 相似文献