Electrocatalytic Processes in Lithium Power Sources

Most important electrocatalytic processes that occur in primary and secondary (rechargeable) lithium power sources are briefly considered.     

气液双热源耦合换热器性能研究

设计了一种由管翅式换热器和套管式换热器耦合而成的气液双源耦合式换热器,该换热器可以实现一种介质同时与气态热源和液态热源进行同步耦合换热.对该换热器进行了详细的介绍,并对其耦合换热特性及该换热器在耦合热源热泵空调中应用时的制热工况进行了的性能测试.研究结果证明,使用该气液双热源耦合式换热器的耦合热源热泵空调系统,气液双热...     

一种高功率掺铒光纤超荧光光源

通过优化掺铒光纤各种参量,用一个980 nm激光二极管作抽运源,采用单程结构,在一根光纤后向获得功率高达31.74 mW(15.02 dBm)的C-波段ASE输出的同时,其前向得到了功率为10.14 mW(10.06 dBm)的L-波段ASE输出.通过简单连接组合可得到输出覆盖C＋L波段(1525~1620 nm)功率＞36 mW的掺铒光纤宽带光源.     

On the calculation of group characters

It is known that characters of irreducible representations of finite Lie algebras can be obtained using the Weyl character formula including Weyl group summations which make actual calculations almost impossible except for a few Lie algebras of lower rank. By starting from the Weyl character formula, we show that these characters can be re-expressed without referring to Weyl group summations. Some useful technical points are given in detail for the instructive example of G₂ Lie algebra.     

基于激光驱动等离子体X光源的X射线相衬成像

为了诊断惯性约束聚变（ICF）内爆靶丸球壳的多层信息,在神光Ⅱ激光器上对激光驱动等离子体X光源的相衬成像进行了研究。利用神光Ⅱ第9路激光驱动平面Ti靶获得X光源,在10 μm的针孔约束下作为次级点光源对样品成像,用X光胶片记录。成功地将相衬成像技术应用于ICF实验,综合考虑成像放大倍数、分辨力、成像衬度和抑制烧蚀碎片等因素,选择合适的实验条件,成功获得了清晰的双层内爆靶丸球壳结构,空间分辨力优于10 μm。     

外粒子源注入下气体放电过程的模拟研究

利用Geant4程序建立外源注入式、低气压气体开关物理模型,通过模拟计算电子增益与极板间电场强度、电子增益与极板间隙距离的函数关系验证了模型的正确性。计算了气体种类、气体压强对电子增益的影响,分析得到形成自持放电所需最小入射电子数,计算结果表明：在相同的气压及电场条件下,氮气的电子增益远大于氦气,这与氦气的高电离能性质相吻合; 随气压增大,电子增益呈非线性增长; 为实现自持放电,外源注入电子数面密度为1×10⁵~2×10⁵ /cm²。     

On the perturbations of spectra of upper triangular operator matrices

In this paper we investigate perturbations of the regular spectrum of an upper triangular operator matrix such as acting on a Hilbert space H⊕K.     

Action des hydrazines fluoroalkylées sur les phosphoallènes: synthèse d’hydrazones N-fluoroalkylées β-phosphonatées

Ten phosphorylated β-hydrazones of structure R₂P(O)C(NNHR_F)CHR₂′ were prepared in 54-91% yield by heating the allenes R₂P(O)CHCCR₂′ with fluorinated hydrazines H₂NNHR_F in chloroform or methanol [R=Ph, OCH₂C(Me)₂CH₂O or OCH₂C(Me)(Pr)CH₂O, R′=H or Me and R_F=CH₂CF₃ or C₆F₅]. Two cyclohexyl derivatives were prepared similarly from R₂P(O)CHCCy. The triphenyl derivatives Ph₂P(O)CH₂C(NNHCH₂CF₃)Ph and Ph₂P(O)CH₂C(NNHC₆F₅)Ph were made in 91 and 68% yield by heating the ketones Ph₂P(O)CH₂C(O)Ph with an ethanol solution of the corresponding hydrazines. The stereochemistry of the hydrazones was determined by multinuclear NMR experiments. Compounds with C(NNHR_F)Me groups exist as a mixture of Z and E isomers, with the Z form predominating (fluorinated group syn to phosphorus). Those with C(NNHR_F)CHMe₂, C(NNHR_F)Cy or C(NNHR_F)Ph groups were formed selectively, the Z isomers being the only products. The results are explained by steric hindrance, the bulkier isopropyl, cyclohexyl or phenyl group disfavouring the E configuration. , , , NMR data, coupling constants and IR data are reported.     

First separation and characterization of cis and trans 1,2-bisaryloxy perfluorocyclobutanes

4-Bromotrifluorovinyloxybenzene (4-Br-TFVE) undergoes cyclodimerization upon heating at 150 °C affording cis and trans isomers of 1,2-bis(4-bromophenoxy)hexafluorocylcobutane. Stereoisomers were separated by selective crystallization, confirmed by single crystal X-ray, and further characterized by NMR. Remarkable difference in the solid state structures include aryl to aryl dihedral angles of 12° for the trans isomer and 88° for the cis isomer. Polymers containing roughly equal amounts of cis and trans fused perfluorocyclobutyl (PFCB) rings should be expected to have low crystallinity due to the marked difference in the two unit cells as is observed.     

A short, simple and general approach for the synthesis of (3S,4S)-3-methoxy-4-methylamino pyrrolidine and (3S,4R)-3-methoxy-4-methylamino pyrrolidine

A general and efficient stereoselective approach for the synthesis of (3S,4S) and (3S,4R)-3-methoxy-4-methylamino pyrrolidines, a part of the structure of AG-7352, a naphthyridine antitumor agent and quinoline antibacterial compounds has been described.