国产光纤实现直接抽运全光纤化3000 W级激光输出

基于国产光纤构建了直接抽运全光纤化主控振荡器功率放大器结构光纤激光器, 放大级分别采用武汉烽火锐光科技有限公司和中国电子科技集团公司第四十六研究所提供的国产20/400 μm掺镱双包层光纤作为增益光纤, 通过全国产化放大级实现了3050和3092 W的1080 nm激光输出. 放大级提取效率分别为67.3%和68.2%, 光-光效率分别为63.0%和63.9%. 据可查询资料, 这是公开报道的直接抽运全光纤激光输出的最高水平, 同时由于采用了国产光纤作为放大级增益光纤, 表明国产光纤具备了3 kW级光纤激光器输出能力. 通过国产光纤横截端面以及光纤熔接显微镜图像实验分析知, 光纤制造工艺的不足是导致国产光纤激光器效率低的主要原因. 继续改进光纤工艺, 提升抽运功率, 优化光纤长度, 有望实现更高功率的全国产化光纤激光器输出.     

垂直磁场对光抽运信号的影响

保持扫场和垂直磁场合成的叠加磁场大小一定,定量研究了地磁场的垂直分量抵消不同时叠加磁场方向变化角度Δθ对光抽运信号幅度的影响.结果表明:光抽运信号幅度随叠加磁场方向变化角度Δθ的增大而增大,当Δθ=180°时,即地磁场的垂直分量完全抵消时,光抽运信号幅度最大,并用量子理论的观点解释了这一规律.     

A periodic array of nano‐scale parallel slats for high‐efficiency electroosmotic pumping

It is known that the eletroosmotic (EO) flow rate through a nano‐scale channel is extremely small. A channel made of a periodic array of slats is proposed to effectively promote the EO pumping, and thus greatly improve the EO flow rate. The geometrically simple array is complicated enough that four length scales are involved: the vertical period 2L, lateral period 2aL, width of the slat 2cL as well as the Debye length . The EO pumping rate is determined by the normalized lengths: a, c, or the perforation fraction of slats and the dimensionless electrokinetic width . In a nano‐scale channel, K is of order unity or less. EO pumping in both longitudinal and transverse directions (denoted as longitudinal EO pumping (LEOP) and transverse EO pumping (TEOP), respectively) is investigated by solving the Debye–Hückel approximation and viscous electro‐kinetic equation. The main findings include that (i) the EO pumping rates of LEOP for small K are remarkably improved (by one order of magnitude) when we have longer slats () and a large perforation fraction of slats (η > 0.7); (ii) the EO pumping rates of TEOP for small K can also be much improved but less significantly with longer slats and a large perforation fraction of slats. Nevertheless, it must be noted that in practice K cannot be made arbitrarily small as the criterion of for the reference potential at the channel center put lower bounds on K; in other words, there are geometrical limits for the use of the Poisson–Boltzmann equation.     

A miniaturized flow-injection analysis ( μ FIA) system with on-line chemiluminescence detection for the determination of iron in estuarine water

A miniaturized flow-injection analysis system constructed from a glass base plate and polydimethylsiloxane (PDMS) top plate was employed for the determination of iron in river water. Two designs were investigated, one utilizing a syringe pump and the other utilizing EOF pumping with a mini-filtration system incorporated. The syringe pump system was used to optimize the analytical method on chip, where the pump was used to deliver both the analyte and the reagents to the reactor chip. The highly sensitive chemiluminescence reaction between alkaline luminol (3-aminophthalhydrazide) and 0.1?M of hydrogen peroxide (H₂O₂) in the presence of iron(II) was utilized. The bright blue light (λ _max?～?440?nm) emitted was detected using a miniaturized photomultiplier tube interfaced directly under the chip. The light intensity signals were recorded, and the corresponding concentration of iron(II) concentration was determined. The calibration for iron(II) standards was linear up to 0.75?µg?mL^?1 (y?=?5.7839x?+?0.0378, r² ?=?0.9939) with a precision value of up to 3.72% RSD, for n?=?3. The limits of detection (blank?+?3s _y/x) were found to be 28?ng?mL^?1. The system which utilized EOF pumping and incorporated a minifiltration unit provided a linear calibration for 0–5?µg?mL^?1 (y?=?3.316x?+?0.1831; correlation coefficient, r ²?=?0.9996) over a working range of 0.0–0.5?µg?mL^?1. This system provided lower limits of detection 5.1?ng?mL^?1 and better repeatability (%RSD less than 0.5% for n?=?4), but problems occurred with the mini-filtration system at higher iron(II) concentrations. The EOF pumping system provided slightly higher results for the concentration of iron(II) in the Humber estuary (0.058?µg?mL^?1), but these results were in line with the results expected by the Environment Agency.     

不同加铝方式对SAPO-34分子筛合成及MTO催化性能的影响

在水热合成体系中,以三乙胺(TEA)和四乙基氢氧化铵(TEAOH)为混合模板剂,考察了在初始凝胶形成过程中铝源的加入方式对合成SAPO-34分子筛及甲醇制烯烃(MTO)催化性能的影响;通过X射线衍射(XRD)、扫描电子显微镜(SEM)、氮气等温吸附脱附(BET)、²⁹Si固体核磁(²⁹Si MAS NMR)、氨气程序升温脱附(NH₃-TPD)等方法对合成产物进行物性表征,并研究了其在甲醇转化制烯烃(MTO)反应中的催化性能。结果表明,随着首先加铝量的增加,粒径有逐渐变小的趋势,且逐渐出现板层状形貌的SAPO-34分子筛;同时,产物分子筛骨架中Si(4Al)配位结构的数量增加,强酸比例在逐渐增大,且酸密度增加;随着强酸比例和酸密度的提高,SAPO-34分子筛在MTO催化反应中的寿命逐渐延长,丙烯选择性逐渐增大而乙烯选择性逐渐减小。     

Some theoretical and practical aspects in the separation of humic substances by combined liquid chromatography methods

Permanent need to understand nature, structure and properties of humic substances influences also separation methods that are in a wide scope used for fractionation, characterization and analysis of humic substances (HS). At the first glance techniques based on size-exclusion phenomena are the most useful and utilized for relating elution data to the molecular mass distribution of HS, however, with some limitations and exceptions, respectively, in the structural investigation of HS. The second most abundant separation mechanism is reversed-phase based on weak hydrophobic interactions beneficially combined with the step gradients inducing distinct features in rather featureless analytical signal of HS. Relatively great effort is invested to the developments of immobilized-metal affinity chromatography mimicking chelate-forming properties of HS as ligands in the environment. Surprisingly, relatively less attention is given to the ion-ion interactions based ion-exchange chromatography of HS. Chromatographic separation methods play also an important role in the examination of interactions of HS with pesticides. They allow us to determine binding constants and the other data necessary to predict the mobility of chemical pollutants in the environment. HS is frequently adversely acting in analytical procedures as interfering substance, so more detailed information is desired on manifestation of its numerous properties in analytical procedures. The article topic is covered by the review emphasizing advances in the field done in the period of last 10 years from 2000 till 2010.     

清洁、大流量真空差分系统的研制

本研究是为了设计一套大流量、清洁的真空差分系统. 计算了超重反冲核实验装置终端真空差分系统各级的真空度; 介绍了差分系统的设计和真空泵、测量设备选择; 选择能在高压强下连续运行的新型分子/增压泵作为过渡流范围内的主排气泵, 对分子增压泵进行了性能测试并对差分系统进行了模拟靶室实验, 最后对实验结果进行了分析.     

烟火泵浦钕玻璃激光器出光实验研究

 烟火泵浦是激光器小型化、便携化的一种解决方法。研制了一种用于钕玻璃激光器泵浦源的化学试剂,其主要成分为金属粉和碱金属含氧酸盐。设计了烟火泵浦钕玻璃激光器实验装置,激光器采用平-凹腔结构、紧包型侧面泵浦,输出镜反射率98％,钕玻璃棒尺寸f8 mm×100 mm。采用A,B两种配方的泵浦源进行出光实验,A配方得到了波长为1 053 nm能量为29 mJ的激光,B配方没有出光。分别计算了两种泵浦源的阈值辐射强度,并与测量得到的药剂辐射强度平均值比较。A配方所提供的辐射强度2.68×104 W·sr^-1,大于阈值2.37×104 W·sr^-1;B配方小于阈值,未能出光。这与实验结果吻合,证明烟火泵浦方法可行。     

微腔中单量子点的激光输出特性研究

研究一个四能级量子点耦合到单模光学腔中的量子系统,利用系统的主方程作数值模拟计算微腔中单量子点的激光输出强度随非相干泵浦的变化关系.结果显示量子点在泵浦作用下激光的输出有一个阈值;且量子点和腔模耦合强度增强时,产生激光的阈值明显减小,输出激光的峰值却增大.当泵浦作用继续增强到一定程度,因激光能级间的相干性被过强的非相干泵浦所破坏,单量子点激光输出变为零----出现了淬灭现象.     

高功率光子晶体光纤放大器实验研究

利用掺Yb³⁺的光子晶体光纤作为光纤放大器的增益介质,采用反向抽运方式,分别从理论和实验方面研究了不同信号的增益特性,在信号光功率为6W,抽运光功率为160W时,获得了104W的输出功率.实验发现,当抽运功率大于一定值时,放大器输出会有一定的不稳定性,并影响输出功率的进一步提高. 关键词： 光子晶体光纤 光纤放大器 反向抽运 高功率