n-Butyllithium-promoted regioselective elimination of vicinal bis-triflate having an adjacent ether oxygen

Regioselective elimination of a vicinal bis-triflate having an adjacent ether oxygen functional group has been developed. Considered in the context of our studies of the regioselective elimination of vicinal dibromide, the key to the mechanism involves the electron-withdrawing inductive effect of the neighboring oxygen functional group. Aliphatic vinyl triflate was shown to be effective in Suzuki–Miyaura cross coupling compared with corresponding aliphatic vinyl bromide.     

Volatile Organic Compound Fragmentation in the Afterglow of Pulsed Glow Discharge in Ambient Air

Glow discharge (GD) source gained an increased level of attention in relation to the analysis of volatile organic compounds (VOCs) since past work showed that this soft ionization method allowed direct analysis of VOCs with minimal fragmentation, however, the issue of fragmentation was not previously studied in detail. The aim of the present work was to investigate the effect of discharge conditions on VOC fragmentation in the system consisting of the cell with pulsed glow discharge and a time-of-flight mass spectrometer. Ionization of VOCs of different classes (hydrocarbons, alcohols, esters, and carboxylic acids) was investigated. A copper cathode with flat geometry was used. VOCs were ionized in the afterglow of short pulse glow discharge in the air. The use of discharge afterglow significantly reduces or eliminates the effects of ionization mechanisms other than Penning process, in particular, electron ionization. This significantly reduced VOC fragmentation and provided rather low limits of detection. Specific cluster formation was observed for alcohols and esters, which may facilitate their identification.     

10MW串级脉冲发电机的理论、设计、实验及应用研究

脉冲发电机具有小型、机动、灵活、可靠、寿命长等特点, 作为高功率固体激光器和加速器电源是一新的技术路线。比较了各种类型脉冲电源的性能指标,解释了旋转磁通压缩和串级原理,提出串级脉冲发电机的自激、偏极与双机同壳概念,给出电机的设计公式,10MW串级脉冲发电机的设计、实验及在强激光与粒子束领域中的潜在应用。     

单粒子翻转脉冲激光模拟的能量阈值的计算

根据光的吸收机理,分析了单粒子效应脉冲激光模拟实验中所需用的脉冲激光的特点,探讨了脉冲激光单粒子效应的Monte Carlo计算模拟途径。在只考虑光电效应的简化下,得到存储器硅片单粒子翻转时入射脉冲激光能量阈值与临界电荷的计算关系式,进而给出该硅片的翻转截面的计算公式。在给定了存储器硅片的临界电荷的情况下,对入射脉冲激光能量阈值和单粒子翻转截面进行了计算。     

高功率脉冲离子束的产生

分析了高功率二极管中的双向流以及提高离子流产生效率的反射三极管、磁绝缘二极管和箍缩二极管工作原理,概述了高功率脉冲离子束研究进展及发展方向。     

300kV的虚火花放电实验

介绍了用脉冲线加速器作驱动电源产生高压虚火花放电的实验。脉冲线加速器由十级马克斯发生器和改装的脉冲形成线构成, 虚火花放电室中注入低气压氮气, 在300kV的放电电压下获得药10kA的高亮度电子束。     

脉冲高功率离子二极管的动力学模拟

基于等离子体的爆炸发射模型,利用自洽的2.5维的胞中粒子（PIC）模拟程序MAGIC模拟了平板型磁绝缘离子二极管中电子和质子的动力学特性。给出了电压为300kV,外加磁场为2倍临界磁场情况下的二极管特性,阴阳极间隙中带电粒子的空间和相空间分布,以及净电荷密度分布和电场分布,结果表明,引出束流密度比单离子Child-Langmuir公式计算的结果大5倍;外加磁场导致在阴极附近形成虚阴极。空间电荷使得阴阳极间隙中电场扰动和增强。     

微波放电解离氯分子解离效率的测量

以Cl/Cl2/HN3/He为基础的NCl(a1Δ)/I作为一种化学激光新的体系,氯原子产生的多少对该体系的研究是至关重要的。利用滴定法研究了微波解离氯分子的解离效率。用HN3/He滴定Cl,由光学多通道分析仪监测NCl(a1Δ)和NCl(b1Σ)辐射的荧光。发现微波解离氯分子的效率并不是想象的那样低,在较小的氯流量下,最高的解离效率可以达到100％。     

放电参数对毛细管放电泵浦的软X射线激光的影响

以哈尔滨工业大学可调谐激光技术国家重点实验室中的Marx发生器的放电脉冲波形为基础,理论上模拟计算了在不同放电参数下充氩气的毛细管放电产生的等离子体状态和类氖氩离子3p_3s跃迁线的增益系数的时空演变过程。中心模型中,选取内径为3.1 mm 的陶瓷毛细管并充入初始密度为1.07×10-6g·cm-3的氩气,电流脉冲峰值为27.81 kA,脉冲宽度为61.4 ns。改变放电参数进行模拟,结果表明：上升前沿越陡,则增益系数越大,电流脉冲上升时间在20~40 ns,电流峰值在25~40 kA,电流脉冲宽度在50~70 ns范围内,毛细管放电产生的等离子体状态比较理想,可获得较高的增益系数。     

重复脉冲强流电子束源长时间稳定运行实验研究

简要阐述了脉冲变压器型重复脉冲强流电子束加速器CHP01的组成、主要特点及工作原理,利用设计的重复脉冲强流电子束源进行了长时间运行实验研究,实验结果达到：在100 Hz重复频率下连续运行5 s,脉冲变压器能稳定输出电压1.15 MV,强流束二极管输出电压超过800 kV、束流7 kA、脉冲宽度45 ns,阴极电子发射密度超过10 kA/cm2,且运行稳定可靠。利用该电子束源进行了X波段类周期慢波结构微波器件实验研究,在50 Hz重复频率下连续运行5 s,输出微波功率超过1 GW,脉冲宽度大于25 ns。