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991.
992.
993.
甲基对硫磷的快速测定及电化学性质 总被引:1,自引:2,他引:1
研究了杀虫剂甲基对硫磷的电化学性质。在pH10.38的Bdtton—Robinson缓冲溶液中,采用微分脉冲溶出伏安法在悬汞电极上得到一个还原峰,峰电位为-0.5V(vs.Ag/AgCl),本工作对实验条件进行了深入的研究,结合线性扫描伏安法等手段。研究了体系的电化学行为。实验表明,甲基对硫磷在汞电极上具有吸附性,电极反应具有不可逆性。该法用于水果及水样中甲基对硫磷残余量的测定,结果满意。 相似文献
994.
《Electroanalysis》2017,29(7):1721-1730
Poly(methyl red), PMR, was electropolymerized on glassy carbon electrodes by potential cycling in 50 mM phosphate buffer solution at pH 7.0 and 8.0 and Britton Robinson buffer solution in the pH range 7.0‐11.0. The electrochemical behavior of PMR modified electrodes was investigated by cyclic voltammetry in Britton Robinson buffer solution at different pHs from 5.0 to 10.0 and found that the best PMR film formation was obtained at pH 9.0. Uric acid was quantitatively determined at PMR modified electrodes by cyclic voltammetry and differential pulse voltammetry in Britton Robinson buffer at pH 5.0. Both methods presented a linear dependence between the anodic peak current and the concentration of uric acid in the range of 0.4 to 60 μM and 0.08 to 100 μM with the limits of detection of 0.038 and 0.009 μM for cyclic voltammetry and differential pulse voltammetry, respectively. Poly(methyl red) as redox mediator allowed the determination of uric acid without any interferences from the substances in serum samples. 相似文献
995.
This paper reports on the development of a novel electrochemical assay for Zn2+ in human sweat, which involves the use of disposable screen-printed carbon electrodes (SPCEs). Initially, SPCEs were used in conjunction with cyclic voltammetry to study the redox characteristics of Zn2+ in a selection of supporting electrolytes. The best defined cathodic and anodic peaks were obtained with 0.1 M NaCl/0.1 M acetate buffer pH 6.0. The anodic peak was sharp and symmetrical which is typical for the oxidation of a thin metal film on the electrode surface. This behaviour was exploited in the development of a differential pulse anodic stripping voltammetric (DPASV) assay for zinc. It was shown that a deposition potential of −1.6 V versus Ag/AgCl and deposition time of 60 s with stirring (10 s equilibration) produced a well-defined stripping peak with Epa = −1.2 V versus Ag/AgCl. Using these conditions, the calibration plot was linear over the range 1 × 10−8 to 5 × 10−6 M Zn2+. The precision was examined by carrying out six replicate measurements at a concentration of 2 × 10−6 M; the coefficient of variation was calculated to be 5.6%. The method was applied to the determination of the analyte in sweat from 10 human volunteers. The concentrations were between 0.39 and 1.56 μg/mL, which agrees well with previously reported values. This simple, low-cost sensitive assay should have application in biomedical studies and for stress and fatigue in sports studies. 相似文献
996.
冲击整形扩径工艺是修复油水井套管损坏的常用技术,根据冲击整形的施工工艺和波动理论,建立了套损局部位置处水泥环的损伤力学模型,以有限变形理论为基础,采用悬臂梁力学模型,分段研究了冲击整形时钻杆屈曲的平衡位形及对套管、水泥环产生的冲击力. 结合水泥环的应力状态, 根据脆性材料的Mazars损伤模型,建立了水泥环的损伤力学模型. 并分析了水泥环的损伤状态. 通过与现场测试结果对比,理论计算与实测结果误差在2.7%左右. 相似文献
997.
利用双温方程对激光烧蚀Si靶的过程进行了数值模拟,并结合合适的初始条件和边界条件,研究了在飞秒、皮秒激光作用下,脉冲波形(矩形、梯形、三角形和高斯形)对Si靶表面载流子和晶格温度分布的影响。结果表明:激光功率密度是影响载流子温升的主要因素,矩形脉冲激光烧蚀Si靶表面载流子的峰值温度最高,而高斯分布的脉冲引起靶面载流子峰值温度最低。可见,激光脉冲波形对Si靶表面载流子的温度分布具有重要影响。所得结果可为制备高质量的薄膜提供理论依据。 相似文献
998.
时分复用倍乘光脉冲重复率的新型光纤耦合器环状连接法分析 总被引:2,自引:0,他引:2
提出并详细分析了一种基于时分复用技术倍乘光脉冲重复率的方法:在2×2光纤耦合器的一个输入口与一个输出口间,接入时延为脉冲列半周期奇数倍的一段光纤使之形成环状连接循环耦合,而在另一输出口获得光脉冲。详细分析了该系统中光纤耦合器耦合比、插入损耗、时延光纤长度的要求,偏差的影响及其调节法,给出了理论公式、结果的计算机模拟与实验介绍;与经典的马赫陈德尔干涉仪接法及近年提出的Sagnac环接法进行了比较。该方法特别适用于对窄脉冲列进行串接复用实现重复率的多次倍乘,从而得到数千兆赫至上百千兆赫的高重复率光脉冲 相似文献
999.
Yu-Soo Lee Hyun-Ju Chung Jong-Han Joung Eung-Jo Kim Hee-Je Kim 《Optics & Laser Technology》2004,36(1):461-61
We describe the pulse forming of pulsed CO2 laser using multi-pulse superposition technique. Various pulse shapes, high duty cycle pulse forming network (PFN) are constructed by time sequence. This study shows a technology that makes it possible to make various long pulse shapes by activating SCRs of three PFN modules consecutively at a desirable delay time with the aid of a PIC one-chip microprocessor. The power supply for this experiment consists of three PFN modules. Each PFN module uses a capacitor, a pulse forming inductor, a SCR, a high voltage pulse transformer, and a bridge rectifier on each transformer secondary. The PFN modules operate at low voltage by driving the primary of HV pulse transformer. The secondary of the transformer has a full-wave rectifier, which passes the pulse energy to the load in a continuous sequence.We investigated various long pulse shapes as different trigger time intervals of SCRs among three PFN modules. As a result, we could obtain laser beam with various pulse shapes and durations from about 250 to 1000 μs. 相似文献
1000.
通过对托卡马克中模拟积分器积分误差的分析,设计了一种由数字信号处理部件动态抑制这些误差的斩波式积分器,并在实验中获得了长时间、低漂移的积分效果。 相似文献