Highly Effective Proton-Conduction Matrix-Mixed Membrane Derived from an -SO3H Functionalized Polyamide

Developing a low-cost and effective proton-conductive electrolyte to meet the requirements of the large-scale manufacturing of proton exchange membrane (PEM) fuel cells is of great significance in progressing towards the upcoming “hydrogen economy” society. Herein, utilizing the one-pot acylation polymeric combination of acyl chloride and amine precursors, a polyamide with in-built -SO₃H moieties (PA-PhSO₃H) was facilely synthesized. Characterization shows that it possesses a porous feature and a high stability at the practical operating conditions of PEM fuel cells. Investigations of electrochemical impedance spectroscopy (EIS) measurements revealed that the fabricated PA-PhSO₃H displays a proton conductivity of up to 8.85 × 10⁻² S·cm⁻¹ at 353 K under 98% relative humidity (RH), which is more than two orders of magnitude higher than that of its -SO₃H-free analogue, PA-Ph (6.30 × 10⁻⁴ S·cm⁻¹), under the same conditions. Therefore, matrix-mixed membranes were fabricated by mixing with polyacrylonitrile (PAN) in different ratios, and the EIS analyses revealed that its proton conductivity can reach up to 4.90 × 10⁻² S·cm⁻¹ at 353 K and a 98% relative humidity (RH) when the weight ratio of PA-PhSO₃H:PAN is 3:1 (labeled as PA-PhSO₃H-PAN (3:1)), the value of which is even comparable with those of commercial-available electrolytes being used in PEM fuel cells. Additionally, continuous tests showed that PA-PhSO₃H-PAN (3:1) possesses a long-life reusability. This work demonstrates, using the simple acylation reaction with the sulfonated module as precursor, that low-cost and highly effective proton-conductive electrolytes for PEM fuel cells can be facilely achieved.     

Regge Models of Proton Diffractive Dissociation Based on Factorisation and Structure Functions

Recent results by the authors on proton diffractive dissociation (single, double and central) in the low-mass resonance region with emphasis on the LHC kinematics are reviewed and updated. Based on the previous ideas that the contribution of the inelastic proton–Pomeron vertex can be described by the proton structure function, the contribution of the inelastic Pomeron–Pomeron vertex appearing in central diffraction is now described by a Pomeron structure function.     

级联二阶非线性铌酸锂全光开关的研制

以基于准位相匹配和频与差频级联二阶非线性[X^(2)：X^(2)]基础上的全光开关的理论分析作指导,进行了周期极化铌酸锂晶体(PPLN)和退火质子交换光波导(APE)的实验制备,利用所研制的PPLN-APE器件,以自行研制的工作波长为1．54μm的被动调Q掺钴铝酸镁激光器作为控制光源,以工作波长为1．5μm的连续二极管激光器为信号光源进行了级联二阶非线性全光开关实验。当控制光峰值功率为3kw,信号光功率为1mW时,实现13％的开关效率,分析了进一步提高全光开关性能的途径。     

Proton Transfer of Phenanthridone in the Lowest Excited Singlet State in Moderately Concentrated Mineral Acid Solutions

A modified form of the steady state treatment for the determination of excited state proton transfer rate constants was successfully applied to a variety of oxygen and nitrogen center aromatic excited acids. These compounds shared the characteristic of being more acidic in the lowest excited singlet state (S₁) than in the ground electronic state (S₀) and of requiring a concentrated mineral acid medium for protonation. This treatment was extended to phenanthridone, the lactam of 6-hydroxyphenanthridine, which is a weak enough base in the ground and the excited states to require moderately concentrated mineral acids for protonation, and becomes a stronger base in the excited state than it is in the ground state. Phenanthridone exists as an -lactam and is a weaker base in the ground and excited states than the -lactams derived from 2-hydroxypyridine, 2-hydroxyquinoline, and 1-hydroxyisoquinoline. It is also a much weaker base than the vinylogous -lactams. The reasons for this are discussed here.     

Polymer electrolyte membranes based on polystyrenes with phosphonic acid via long alkyl side chains

A series of polystyrenes with phosphonic acid ( 5 ) via long alkyl side chains (4, 6, and 8 methylene units) were prepared by the radical polymerization of the corresponding diethyl ω‐(4‐vinylphenoxy)alkylphosphonates, followed by the hydrolysis with trimethylsilyl bromide. The resulting phosphonated polystyrene membranes had a high oxidative stability against Fenton's reagent at room temperature. The membranes prepared from 5 exhibited a very low water uptake, similar to that of Nafion 117 over the wide range of 30 to 80% relative humidity (RH). The proton conductivities of these membranes are lower than that of Nafion 117 in the range of 30 to 90% RH, but comparable or higher than those of the reported phosphonated polymers with higher IEC values, such as the phosphonated poly(N‐phenylacrylamide) (PDPAA, IEC: 6.72 mequiv/g) and fluorinated polymers with pendant phosphonic acids (M47, IEC: 8.5 mequiv/g), at low RH conditions despite the much lower IEC values (3.0–3.8 mequiv/g) of these membranes. These results suggest that the flexible pendant side chains of 5 would contribute to the formation of hydrogen‐bonding networks by considering the very low water uptake of these polymers. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012     

Synthesis and characterization of phenol‐based biaryl proton conducting polymers

Biaryl hydroxy polymers with orthogonal disposition of proton transporting ? OH moieties have been synthesized via conventional free radical polymerization. The polymers are characterized for their thermal stability and proton conductivity, and the results are compared with the corresponding styrenic hydroxy polymers. The orthogonal disposition of ? OH moieties in biaryl polymers does result in lower E_a for proton transport. However, the lower E_a values in biaryl polymers did not translate into a net increase in proton conductivity. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012     

Nucleon octet in a relativistic logarithmic potential

A simple independent-quark-model based on the Dirac equation with logarithmic potential is used to calculate several properties of octet baryons such as magnetic moment, the axial vector coupling constantg _A (n) for neutronβ-decay and the charge radius of the proton. In view of the simplicity of the model, the results obtained are quite good.     

Calorimetric study of laser-irradiated thin foil targets

Hydrodynmaic efficiency of laser-irradiated thin aluminum and gold-coated aluminum targets was experimentally determined using a specially designed cone calorimeter. Velocity of the accelerated target and ablation pressure were also estimated from the experimental data. The laser irradiance range used in the experiments was between 10¹² and 10¹³ watts/cm². Experiments indicate that the fall in the hydrodynamic efficiency due to gold coating on aluminum target is about 12% at an irradiance of 8 × 10¹² W/cm².     

气垫导轨上运动物体加速度测量方法的改进

利用计数计时测速仪测量气垫导轨上滑块运动的加速度,其测量精度直接依赖于2个光电门之间距离的测量,而在实验中该距离的测量往往不易达到很高的精度,致使加速度的测量精度不高.对计数计时测速仪的电路和单片机程序稍加修改,使之能测出滑块从一个光电门运动到另一个光电门所需时间,就无需测量2个光电门之间的距离,因而提高了加速度的测量精度,节约单片机的资源并缩短运行时间.