全文获取类型
收费全文 | 9968篇 |
免费 | 1670篇 |
国内免费 | 1919篇 |
专业分类
化学 | 4795篇 |
晶体学 | 133篇 |
力学 | 350篇 |
综合类 | 99篇 |
数学 | 1302篇 |
物理学 | 6878篇 |
出版年
2024年 | 25篇 |
2023年 | 97篇 |
2022年 | 303篇 |
2021年 | 346篇 |
2020年 | 279篇 |
2019年 | 316篇 |
2018年 | 277篇 |
2017年 | 400篇 |
2016年 | 390篇 |
2015年 | 421篇 |
2014年 | 571篇 |
2013年 | 747篇 |
2012年 | 599篇 |
2011年 | 611篇 |
2010年 | 583篇 |
2009年 | 666篇 |
2008年 | 757篇 |
2007年 | 751篇 |
2006年 | 732篇 |
2005年 | 652篇 |
2004年 | 531篇 |
2003年 | 487篇 |
2002年 | 382篇 |
2001年 | 344篇 |
2000年 | 380篇 |
1999年 | 305篇 |
1998年 | 247篇 |
1997年 | 263篇 |
1996年 | 208篇 |
1995年 | 151篇 |
1994年 | 128篇 |
1993年 | 112篇 |
1992年 | 109篇 |
1991年 | 72篇 |
1990年 | 55篇 |
1989年 | 63篇 |
1988年 | 60篇 |
1987年 | 26篇 |
1986年 | 17篇 |
1985年 | 15篇 |
1984年 | 13篇 |
1983年 | 6篇 |
1982年 | 13篇 |
1981年 | 8篇 |
1980年 | 4篇 |
1979年 | 11篇 |
1977年 | 5篇 |
1974年 | 5篇 |
1973年 | 4篇 |
1971年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
21.
3d-metal antimonides: Fe1+x Sb, N+x Sb, Co+x Sb and the (Ni1?y Fe y )Sb solid solution have been studied by the Mössbauer effect method at 57Fe and 119Sn. It was found that the quadrupole interactions at the Fe and Sn nucleus in 3d-metal antimonides are very sensitive to the filling of different crystallographic sites with metal atoms. The metal atoms in trigonal-bipyramidal sites have a strong effect on the quadrupole splitting of 119Sn. They are nearest to anions (Sb or Sn) with the typical axial ratio of c/a = 1.25. The QS(x) dependence of 119 Sn in 3d-metal antimonides in the 0 ≤ x ≤ 0.1 concentration range can be used to determine x – the concentration of transition metal excess relative to the stoichiometric composition. 相似文献
22.
Cao H. P. Chen G. Grechkoseeva M. A. Mazurov V. D. Shi W. J. Vasil'ev A. V. 《Siberian Mathematical Journal》2004,45(6):1031-1035
The spectrum of a finite group is the set of its element orders. A finite group G is said to be recognizable by spectrum, if every finite group with the same spectrum as G is isomorphic to G. The purpose of the paper is to prove that for every natural m the finite simple Chevalley group F
4(2
m
) is recognizable by spectrum. 相似文献
23.
We employ an agent‐based model to show that memory and the absence of an a priori best strategy are sufficient for self‐segregation and clustering to emerge in a complex adaptive system with discrete agents that do not compete over a limited resource nor contend in a winner‐take‐all scenario. An agent starts from a corner of a two‐dimensional lattice and aims to reach a randomly selected site in the opposite side within the shortest possible time. The agent is isolated during the course of its journey and does not interact with other agents. Time‐bound obstacles appear at random lattice locations and the agent must decide whether to challenge or evade any obstacle blocking its path. The agent is capable of adapting a strategy in dealing with an obstacle. We analyze the dependence of strategy‐retention time with strategy for both memory‐based and memory‐less agents. We derive the equality spectrum to establish the environmental conditions that favor the existence of an a priori best strategy. We found that memory‐less agents do not polarize into two opposite strategy‐retention time distributions nor cluster toward a center distribution. © 2004 Wiley Periodicals, Inc. Complexity 9: 41–46, 2004 相似文献
24.
M. I. Gil' 《Proceedings of the American Mathematical Society》2003,131(12):3737-3746
A linear operator in a separable Hilbert space is called a quasinormal one if it is a sum of a normal operator and a compact one. In the paper, bounds for the spectrum of quasinormal operators are established. In addition, the lower estimate for the spectral radius is derived. Under some restrictions, that estimate improves the well-known results. Applications to integral operators and matrices are discussed. Our results are new even in the finite-dimensional case.
25.
26.
F-H实验仪与光栅光谱仪连用观测253.7nm谱线 总被引:1,自引:0,他引:1
通过F-H实验仪和光栅光谱仪的连用,可实时观测汞原子从6s6s1So态激发到6s6sSP1态,退激时,辐射出能量为4.9eV的光量子,其波长为253.7nm. 相似文献
27.
用密度泛函B3LYP/ 6 3 1G(d)方法 ,对质子化丙酮分子团簇 (CH3COCH3) nH+ (n =1~ 7)弱相互作用体系进行了全自由度能量梯度优化 ,得到了该系列团簇的稳定结构及其对应的体系能量 .通过对构型的分析得出了质子化丙酮分子团簇 (CH3COCH3) nH+ (n =1~ 7)的生长规律 .计算了中性丙酮分子团簇体系的质子亲合能并总结出其变化趋势 .分析讨论了质子化团簇的红外振动光谱 ,发现质子化团簇的振动光谱普遍较中性环型团簇的振动光谱复杂 ,最强的振动峰来源于质子在溶剂壳中两个氧原子之间的振动 ,而且随着团簇尺寸的增加羰基的伸缩振动峰的数目也随之增多 相似文献
28.
In this paper, we present some counterexamples which show that there is no theory on the spectrum of homogeneous compact operators which parallels the Riesz-Schauder theory on the spectrum of linear compact operators. These counterexamples also illustrate that it is impossible to study in a unified setting the Fucik spectrum of the Laplacian: -△w = au+ - bu- inΩand u = 0 on (?)Ω, as well as the spectrum of the p-Laplacian: -div(|(?)u| p-2(?)u) = λ|u|p-2u and u = 0 on (?)Ω. 相似文献
29.
时间分辨红外发射光谱法对自由基反应的研究 总被引:2,自引:0,他引:2
在过去的 15年中 ,傅立叶变换红外发射光谱法广泛应用于研究气相自由基反应 .Sloan首先研究了O(1D)的反应 ,随后Leone和Hancock研究了O(3 P)的反应 .此后 ,孔繁敖和朱起鹤等研究了小自由基 ,包括CH、CH2 、CH3 、C2 H3 、C2 H5、C2 H、C3 H3 和C3 H5与O2 、NO、N2 O、NO2 等分子的反应。在红外光谱中观察到各个反应的初生产物和初步反应通道 ,和从头算的理论研究结合起来 ,这些反应的机理已基本弄清 . 相似文献
30.
F.O. Borges G.H. Cavalcanti A.G. Trigueiros 《Journal of Quantitative Spectroscopy & Radiative Transfer》2003,78(1):119-129
The weighted oscillator strengths (gf) and the lifetimes presented in this work were carried out in a multi configuration Hartree-Fock relativistic (HFR) approach. In this calculation, the electrostatic parameters were optimized by a least-squares procedure, in order to improve the adjustment to experimental energy levels. This method produces gf-values that are in better agreement with intensity observations and lifetime values that are closer to the experimental ones. In this work, we presented all the experimentally known electric dipole S IX and S X spectral lines. 相似文献