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41.
Matthew M. Malwitz Paul D. Butler Lionel Porcar Drew P. Angelette Gudrun Schmidt 《Journal of polymer science. Part A, Polymer chemistry》2004,42(17):3102-3112
The influence of shear on viscoelastic solutions of poly(ethylene oxide) (PEO) and clay [montmorillonite, i.e., Cloisite NA+ (CNA)] was investigated with rheology and small-angle neutron scattering (SANS). The steady-state viscosity and SANS were used to measure the shear-induced orientation and relaxation of the polymer and clay platelets. Anisotropic scattering patterns developed at much lower shear rates than in pure clay solutions. The scattering anisotropy saturated at low shear rates, and the CNA clay platelets aligned with the flow, with the surface normal parallel to the gradient direction. The cessation of shear led to partial and slow randomization of the CNA platelets, whereas extremely fast relaxation was observed for laponite (LRD) platelets. These PEO–CNA networklike solutions were compared with previously reported PEO–LRD networks, and the differences and similarities, with respect to the shear orientation, relaxation, and polymer–clay interactions, were examined. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3102–3112, 2004 相似文献
42.
43.
P. S. Goyal 《Pramana》2004,63(1):15-24
Inter University Consortium for Department of Atomic Energy Facilities (IUC-DAEF) is an autonomous institute of the University
Grants Commission and provides an interface between the university fraternity and the institutions of Department of Atomic
Energy. Mumbai Centre of IUC-DAEF promotes and supports the use of neutron facilities at Dhruva reactor by the university
scientists. To augment the existing neutron scattering facilities, IUC-DAEF has developed a neutron beam line at Dhruva reactor.
The present paper gives a brief survey of the activities and achievements of Mumbai Centre of IUC-DAEF. 相似文献
44.
《Pramana》2003,61(5):865-876
Particle production in Au+Au collisions has been measured in the PHOBOS experiment at RHIC for a range of collision energies
for a large span of pseudorapidities, |η| < 5.4. Three empirical observations have emerged from this data set which require
theoretical examination. First, there is clear evidence of limiting fragmentation. Namely, particle production in central
Au + Au collisions, when expressed as dN/dη′ ( η′ ≡ – ybeam), becomes energy independent at high energy for a broad region of η′ around η′ = 0. This energy-independent region grows
with energy, allowing only a limited region (if any) of longitudinal boost-invariance. Second, there is a striking similarity
between particle production in e+e−and Au + Au collisions (scaled by the number of participating nucleon pairs). Both the total number of produced particles
and the longitudinal distribution of produced particles are approximately the same in e+e−and in scaled Au + Au. This observation This presentation is based in large part on the PHOBOS summary talk by M Baker at
the16th Int. Conf. on Ultrarelativistic Nucleus- Nucleus Collisions, Quark Matter 2002, Nantes, France was not predicted and has not been explained. Finally, particle production has been found
to scale approximately with the number of participating nucleon pairs for (N
part
) > 65. This scaling occurs both for the total multiplicity and for highp
T
particles (3 <p
T
< 4.5 GeV/c).
This presentation is based in large part on the PHOBOS summary talk by M Baker at the16th Int. Conf. on Ultrarelativistic Nucleus-Nucleus Collisions, Quark Matter 2002, Nantes, France 相似文献
45.
46.
半正二阶三点边值问题的解和正解 总被引:8,自引:0,他引:8
考察了非线性二阶三点边值问题的n个解和正解的存在性,其中允许非线性项有一个负的下界并且n是一个任意的自然数.主要结论表明该问题可以具有n个解或者正解,只要非线性项在某些有界集上的“高度”是适当的. 相似文献
47.
BNCT优化网格设计及相关算法研究 总被引:2,自引:0,他引:2
用MCNP蒙特卡罗程序模拟了硼中子俘获治疗(BNCT)3种国际基准网格模型, 并与
修正的Snyder椭球模型进行了比较. 在此基础上, 给出了一种保质量守恒、内存量少、易于产生输入文件的4种基本材料成分的BNCT网格模型. 计算结果表明, 在4mm网格下, 新模型可以达到基准模型的精度; 根据解析模型剂量随深度的变化规律, 研究构造了多网格组合模型, 在重要区域计算精度不损失的条件下, 计算时间大大缩短. 最后研究给出了一个既保证精度、又在可接受的时间内完成剂量计算的模型、样本数和相应的算法, 它基本上满足临床BNCT的要求. 相似文献
48.
49.
Jon Samseth Richard J. Spontak Kell Mortensen 《Journal of Polymer Science.Polymer Physics》1993,31(4):467-474
Poly(siloxaneimide) (PSI) segmented copolymers exhibit organized microdomains if the blocks are sufficiently incompatible. As with neat diblock and triblock copolymers, the processing route employed to prepare films of PSI materials is expected to influence the dimensions and/or morphology of the resultant microstructure. In this work, small-angle neutron scattering (SANS) is utilized to characterize the disordered microstructure found in films of a series of PSI copolymers which are subjected to solvent casting and various thermal treatments. Microstructural dimensions such as the periodicity and correlation length are deduced from the Teubner-Strey (TS) model for disordered microemulsions. The scattering intensity of each copolymer up to q = 5.0 nm?1, where q is the scattering vector, is found to scale as q?2.8+?0.1. Results indicate that processing the materials as cast films or as melt-pressed films allowed to cool slowly has a small, but discernible, effect on microstructural characteristics. SANS profiles of films quenched from elevated temperatures reveal a clear transition in microdomain periodicity, which correlates well with the glass transition temperature of the imide microphase in these and other materials of similar chemical structure. © 1993 John Wiley & Sons, Inc. 相似文献
50.
E. A. Zheligovskaya 《Journal of Structural Chemistry》2003,44(5):827-835
A computer simulation of proton-ordered ice IX and its proton-disordered analog III (768 molecules, 90 K) was carried out by the molecular dynamics method using Poltev–Malenkov's potential. For ice IX, the differences in the dynamic characteristics of molecules with O(1) and O(2) are much wider than those in the case of ice III. The libration spectrum of ice IX has a number of distinct acute peaks, and the spectrum of ice III is strongly smoothed. These peculiarities are explained by the proton ordering of ice IX and disordering of ice III. The latter is responsible for the great differences in the short- and especially long-range environment of water molecules in ice crystals and hence for the presence of many molecules with different dynamic characteristics. Thus averaging over a large number of different vibrational spectra of molecules leads to a smoothed total spectrum in the case of the proton-disordered crystal modification of ice. 相似文献