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101.
102.
Christian Maes 《Journal of statistical physics》1990,61(3-4):667-681
An anisotropic lattice gas dynamics is investigated for which particles on
d
jump to empty nearest neighbor sites with (fast) rate –2 in a specified direction and some particular configuration-dependent rates in the other directions. The model is translation and reflection invariant and is particle conserving. The space coordinate in the fast-rate direction is rescaled by –1. It follows that the density field converges in probability, as 0, to the corresponding solution of a nonlinear diffusion-type equation. The microscopic fluctuations about the deterministic macroscopic evolution are determined explicitly and it is found that the stationary fluctuations decay via a power law (1/r
d
) with the direction dependence of a quadrupole field. 相似文献
103.
We study a one-dimensional model for fracture, identifying fractured areas with intervals on which a stress field exceeds a threshold value. When is a diffusion process, the cumulative numberN(l) of fractured areas whose length is greater thanl obeys a power lawCl
–p
asl0 with probability one. The exponentp and the constantC are determined. The exponentp agrees with the Hausdorff dimension of the end points of fractured areas, i.e.,
–1(). Even if is self-similar with parameterH>0, i.e.,(cx)– is equivalent toc
H
{(x)–} for anyc>0, the exponentp does not depend solely onH;p=H, where(0, 1/H) is another parameter characterizing. Non-diffusion processes are given whereN(l) does not follow a power law. 相似文献
104.
R. Cabrera‐Trujillo J. R. Sabin Y.
hrn E. Deumens 《International journal of quantum chemistry》2003,94(4):215-221
Under certain collision conditions, a swift ion projectile colliding with a target will gain rather than lose kinetic energy, contrary to the standard conception of stopping power. In this work, we consider the conditions for such a collision such that the energy loss is negative, that is, that there will be projectile kinetic energy gain. In particular, for a target initially in the ground state we find that the projectile gains kinetic energy only when charge exchange and de‐excitation processes are involved. This occurs when the electron affinity of the projectile is larger than the ionization potential of the target. Consequences of this effect are analyzed. © 2003 Wiley Periodicals, Inc. Int J Quantum Chem 94: 215–221, 2003 相似文献
105.
丹麦生物质发电的现状和研究发展趋势 总被引:9,自引:7,他引:9
丹麦是世界上利用秸秆生物质燃烧发电技术开发、运行最好的国家,其经验值得中国借鉴。根据作者在丹麦对生物质燃烧发电的研究经历,系统地介绍了丹麦在秸秆生物质发电的经验、遇到的问题及相应的研究和今后的发展方向。 相似文献
106.
An efficient hybrid field solution to the general multilayer substrates transmission line problems with full shielded and half open cross-sectional geometry is presented by using the waveguide modes coupling and decoupling procedure in the spectral domain. Modal transverse transmission lines corresponding to the LSE and LSM modes are taken into account so that the Green's elements for the edge conditions can be derived by a simple iterative method. In this paper, we analyze not only the propagation constants and characteristic impedances but also the available transmission power capacity and power distribution of most commonly used structures. Normalized eigenmode power levels characterizing the propagation features are computed. 相似文献
107.
T'-214相化合物R2-xCexCuO4(R为稀土离子)成为超导体决定于R3+的离子半径大小、Ce4+的取代量和化合物的热处理时的稳定性.从Raman光谱实验结果提出热处理过程中发生电荷转移.Ce4+的取代引起TN(Cu)下降,当TN(Cu)降到0时,超导性出现。不同的稀土离子TN(Cu)不同,稀土离子的反铁磁性(AFM)与超导性(SC)共存。热电势的测量结果可以用双通道模型解释,n型超导体中电子与空穴共存. 相似文献
108.
Changeable size moving window partial least squares (CSMWPLS) and searching combination moving window partial least squares (SCMWPLS) are proposed to search for an optimized spectral interval and an optimized combination of spectral regions from informative regions obtained by a previously proposed spectral interval selection method, moving window partial least squares (MWPLSR) [Anal. Chem. 74 (2002) 3555]. The utilization of informative regions aims to construct better PLS models than those based on the whole spectral points. The purpose of CSMWPLS and SCMWPLS is to optimize the informative regions and their combination to further improve the prediction ability of the PLS models. The results of their application to an open-path (OP)/FT-IR spectra data set show that the proposed methods, especially SCMWPLS can find out an optimized combination, with which one can improve, often significantly, the performance of the corresponding PLS model, in terms of low prediction error, root mean square error of prediction (RMSEP) with the reasonable latent variable (LVs) number, comparing with the results obtained using whole spectra or direct combination of informative regions for a compound. Regions consisting of the combinations obtained can easily be explained by the existence of IR absorption bands in those spectral regions. 相似文献
109.
Spectral quantities of cyclopropane, cyclobutane, cyclohexane, and of several derivatives, have been calculated by a semiempirical all-valence electron SCF-CI MO method. In cyclopropane, HOMO is practically localized in the carbon-frame, and LVMO is purely so. In cyclobutane, these two MO's are based on C-H bonds, while cyclohexane holds an intermediate position. Despite the overall similarity-experimental and computed-of the spectra of these molecules, assignments are non-parallel. Like cyclopropane, cyclobutane can extend conjugation, but to a diminished degree; cyclohexane behaves in this respect like an acyclic alkane. An interpretation of this gradation, in terms of the nature of high-lying MO's, is proposed. 相似文献
110.
我们用Fe_2(SO_4)_3·xH_2O为催化剂,对2-甲基-2-已醇脱水生成烯烃反应的溶剂化能力及其动力学做了研究,测定了20种不同溶剂中的反应速率常数和以丙至辛6种直链醇为溶剂于不同温度下反应的速率常数,确定了溶剂化能力与溶剂介电常数之间的线性关系。这方面工作尚未见报道。 相似文献