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51.
    
Theoretical models of the variations of the peak positions of X‐ray rocking curves as a function of the azimuthal angle of a single‐crystal wafer have been proposed. These models completely describe the variations of the peak positions both when the surface normal of a wafer is parallel and when it is not parallel to the rotation axis of the goniometer used. Based on the models, an accurate measurement method for the surface orientation of a single‐crystal wafer with a small surface miscut of <∼3° has been proposed through rocking curve measurements using a high‐resolution X‐ray diffractometer. The method measures the misalignment of the sample surface normal with respect to the rotation axis of the goniometer as well as the surface orientation of the wafer. The surface orientation has been measured for a 6 inch (152.4 mm) single‐crystal sapphire wafer, and the misalignment of the surface normal from the rotation axis was determined. The results were compared with those from a different method. In addition, a simple and accurate method to obtain the surface orientation of a wafer is proposed by measuring only four rocking curves, two each at two sample azimuths 180° apart.  相似文献   
52.
For integral geometric and local topological properties of two sets of positive reach, one fixed and the other moving or translating, certain exceptional relative positions have to be excluded. We give a measure geometric justification in form of a Sard-type theorem which extends to more general singular sets. A slightly stronger result has been proved by Schneider for the special case of convex bodies.  相似文献   
53.
    
We give a new proof for the Wedin theorem on the simultaneous unitary similarity transformation of two orthogonal projections and show that it is equivalent to Halmos' theorem on the unitary equivalence of projection pairs. As a consequence of these theorems, we derive several results on pairs of orthogonal projections, relative subspace positions and oblique projections as well.  相似文献   
54.
The pressure dependence of the peak positions and widths of the fluorescence lines corresponding to the 5DJ7FJ electronic transitions in Sm2+-doped SrFCl crystals was measured at room temperature (RT) with a diamond anvil cell (DAC) and a high-pressure gas system, using silicone oil and gaseous helium as the pressure-transmitting medium, respectively. At RT and ambient pressure the electronic transitions 5D07FJ (J= 0, 1, 2, 3) and 5D17FJ (J=0, 1, 2) in Sm2+ ions yielded rather sharp spectral lines peaked at 14490, 14206, 13685, 13012 cm−1 and 15823, 15533, 15012 cm−1, respectively. At pressures up to 45 kbar in the DAC all these peaks shifted linearly to lower energies at the rates −2.36, −2.10, −2.43, −2.22 cm−1/kbar and −2.35, −2.33, −2.47 cm−1/kbar. Under purely hydrostatic gas pressure up to 7 kbar at RT the initial (normal pressure) widths of the 5D07F0, 5D07F1 and 5D17F0 lines having a Lorentzian profile (with corrected FWHM values of 1.55, 5.71 and 1.97 cm−1) decreased linearly with increasing pressure at the rates −0.009(2), −0.077(3) and −0.034(2) cm−1/kbar, respectively. Possible mechanisms of the observed pressure effects are discussed. For further studies of linewidth variations with the pressure, gaseous helium as a best possible high-pressure medium is strongly recommended.  相似文献   
55.
The concept of the residence time of an atom in a kink position was introduced to predict the structure of electrochemically deposited surface coatings. The residence time is obtained from the reciprocal value of the rate constant for separation from the kink position. Residence times and deposition rates determine the density of kink positions [ksp] on the growing metal film. For equilibrium conditions (Nernst potential), the density of kink positions [ksp]0 depends on the exchange current density i0 and on the residence time by the equation:
, where NL is Loschmidts or Avogadros number, F is Faradays constant and z is the charge of the metal ions in the electrolyte. Calculated values of residence times are presented for pure metals as well as for silver–lead and nickel–aluminium alloys.Contribution to the 3rd Baltic Conference on Electrochemistry, Gdansk-Sobieszewo, Poland, 23–26 April 2003Dedicated to the memory of Harry B. Mark, Jr. (28 February 1934–3 March 2003)  相似文献   
56.
57.
    
Many loudspeakers in newer flat television systems are mounted on the bottom of the television, with their diaphragms facing downward, so as to be hidden inside the TV frame. This kind of loudspeaker installation, called downfiring, induces relatively large reflections from the walls of a room. The increased reflections inevitably change the impulse response of the loudspeakers, which leads to a perceptible distortion in sound quality. In this study, an equalization procedure to resolve the distortion due to downfiring loudspeakers is presented. The change in the early-arriving sound from the room reflections was analyzed, and the specific experimental environment was set up to measure the early reflections for designing a single-channel equalization filter. The inverse technique for the single-input multiple-output (SIMO) system was applied such that both the magnitude and phase responses from downfiring loudspeakers can be equalized at multiple listener positions. We also investigated the possible equalization range in space and time, for which the single-channel filter can work effectively. The performance of the filter designed for the equalization range was then demonstrated by experiments. The experiments were performed using a flat television mock-up installed in a reflective environment. For the performance evaluation of the proposed method, we employed two different measures that can represent the magnitude and phase distortions: the mean squared error of the magnitude and an energy decay curve. The experimental results demonstrate that the single-channel filter can reduce the early reflections from a downfiring loudspeaker by a considerable amount.  相似文献   
58.
罗香怡  刘海凤  贲帅  刘学深 《物理学报》2016,65(12):123201-123201
通过数值求解非波恩-奥本海默近似下的一维含时薛定谔方程,研究了蝴蝶结型纳米结构基元中氢分子离子高次谐波的产生.研究表明,在蝴蝶结型纳米结构基元内部产生的非均匀场的空间位置对高次谐波的发射有较大影响.当非均匀场的空间位置从30 a.u.平移到-30 a.u.时,高次谐波的截止位置被延展且形成光滑的超连续的谐波谱,并应用时频分析方法、经典三步模型以及电离概率等解释了高次谐波发射的物理机理.研究了高次谐波谱对非均匀场空间位置的依赖性与载波包络值的关系,发现随着载波包络值的变化,非均匀场在不同空间位置处的高次谐波谱变化趋势相同.  相似文献   
59.
    
We chose a series of isoindigo-based conjugated polymer(ⅡDDT,ⅡDDT-C3 and ⅡDDT-C4) with different length of side chains and bifurcation positions to investigate the relationship between the degree of alignment and the length of side chains and bifurcation positions.We found that the dichroic ratio was increased from 2.37 to 5.23 when the side chain was longer and the bifurcation position was away from the backbone.The π-π stacking distance was decreased from 3.67 A to 3.61 A when the bifurcation position was away from the backbone because of its smaller hindrance and the d-spacing of the(100)was increased from 20.06 A to 25.21 A when the side chain was longer.All the polymers were adopted an edge-on orientation with the backbone paralleled with the long axis of fibers.The weak interaction of side-chain in ⅡDDT-C4 was beneficial for the molecules being rearranged in parallel during the contact line receding and the strong n-n interaction could accelerate the interchain assembly of the parallel molecules through π-π interaction to form aligned fibers.  相似文献   
60.
The aim of this note is to introduce for point processes in ? d the notions general position and reinforced general position, and to characterize these processes. As a consequence we show that Poisson processes P ρ with an infinite intensity measures ρ are in general position iff ρ is diffuse in the sense that any affine subspace of dimension d ? 1 is a ρ-nullset. Moreover, P ρ is in reinforced general position iff in addition any (d ? 1)-sphere is a ρ-nullset.  相似文献   
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