乳状液法制备憎液溶胶Ⅰ.BaCO_3均匀粒子的制备

均匀胶体粒子的形成，除与反应条件（反应物浓度、陈化时间和温度、介质种类等）有关外，反应体系的环境也影响最终产物的形态，《至结晶结构．气溶胶法和微乳液法正是利用微环境中的‘水池效应”；分别制备出球形亚微米和纳米级的均匀粒子［‘－‘］、这些方法与水解法和相转化法等方法比较，反应物浓度要大几个数量级，而反应时间却短很多，因而受到研究人员的关注．乳状液也能提供亚微米、微米及以上级的微环境，因此，可以应用O／W乳状液乳液中的聚合反应制备亲液的分散体系．然而，极少有关利用w／O乳状液制备僧液溶胶的报导问；最近…     

一代树状碳硅烷液晶的光化学研究－－端基含12个4－丁氧基氮苯介晶基元

研究了新的含12个丁氧基偶氮苯介晶基元的五代树状碳硅烷液晶D1及偶氮苯介 晶基元化合物M5在氯仿、四氢呋喃、N，N－二甲基甲酰胺、乙醇和苯等溶剂中的量 子产率、反－顺光异构化、光回复异构、反／顺异构组分比、热回复异构及活化能 。D1和M5的光致变色速率常数为10~(-1)s~(-1)，而含同一偶氮基元的光致变色液 晶聚硅氧烷的光致变色速率常数为10~(-8)s~(-1)，因此，液晶树状物D1的光响应 速度比后者快10~7倍。     

几种杂多阴离子柱撑水滑石的合成与吸附行为

柱撑水滑石类层柱状阴离子粘土是一类新型层柱材料，由于其二维孔道结构的可调变性及潜在的择形催化性能，已引起人们的重视[1-3]．迄今，人们已合成了包括无机和有机阴离子，同多和杂多阴离子（Polyoxometalates，简称POMs）以及配合物阴离子在内的多种柱撑水滑石，其中同多和     

Erosion of efficiency in non-uniform linear chromatography

In linear chromatography (i.e. chromatography performed in the absence of sample overloading), when the plate height of a column is roughly uniform along its length, variations in the velocities of solutes are the only possible causes of erosion of efficiency. The sources of these variations (variations in capacity ratio and in the density of the mobile phase, etc.) play no direct role in the erosion of efficiency except through their effect on solute velocities. In other words, what eventually causes the erosion of efficiency is merely variation in the time required for solutes to traverse equally small segments of a column. Significant erosion can only arise from abrupt and deep deceleration of solutes in one or several relatively small segments of a column. If erosion of efficiency caused by pressure gradients in linear SFC is to be large, the depth and the sharpness of the deceleration of a solute must go beyond that hitherto confirmed experimentally. Many relevant examples are analyzed graphically.     

溶剂热法制备纳米氧化镍及其表征

以乙酰丙酮镍、油酸、油胺为原料，十八烯为溶剂，聚乙烯吡咯烷酮为表面活性剂，采用溶剂热法，在不同反应条件制备了纳米级氧化镍材料.通过X射线衍射（X-ray diffraction，XRD）、透射电子显微镜（Transmission electron microscope，TEM）、紫外-可见光吸收光谱（Ultraviolet-visible spectroscopy，UV-Vis）光谱分析以及塔菲尔（Tafel）测试考察了反应物比例、保温时间、表面活性剂（PVP）、油胺的量对产物微结构、粒径、形貌、光学以及电化学活性性能的影响.实验结果表明：在反应物n[Ni（acac）₂]∶n（OA）=1∶2、添加剂PVP质量分数为1.66%、油胺物质的量为30 mmol、200℃下保温8 h时，可获得粒径约为30～40 nm纯相氧化镍，具有最佳电化学活性，交换电流密度为J₀=1.23×10^-2 mA·cm^-2.     

Friedel-crafts acylation of 2-methoxynaphthalene over h-beta catalysts: effect of Si/Al ratio

The acylation of 2-methoxynaphthalene with acetic anhydride was carried out over zeolite beta catalysts having various Si/Al ratios. It was found that the reaction performance is strongly dependent on the Si/Al ratio of the catalyst. The catalytic reaction features were elucidated in terms of the acidic properties of the catalysts. This revised version was published online in June 2006 with corrections to the Cover Date.     

Critical exponents,hyperscaling, and universal amplitude ratios for two- and three-dimensional self-avoiding walks

We make a high-precision Monte Carlo study of two- and three-dimensional self-avoiding walks (SAWs) of length up to 80,000 steps, using the pivot algorithm and the Karp-Luby algorithm. We study the critical exponentsv and 2 ₄ – as well as several universal amplitude ratios; in particular, we make an extremely sensitive test of the hyperscaling relationdv = 2 ₄ –. In two dimensions, we confirm the predicted exponentv=3/4 and the hyperscaling relation; we estimate the universal ratios <R _g ² >/<R _e ² >=0.14026±0.00007, <R _m ² >/<R _e ² >=0.43961±0.00034, and ^*=0.66296±0.00043 (68% confidence limits). In three dimensions, we estimatev=0.5877±0.0006 with a correctionto-scaling exponent ₁=0.56±0.03 (subjective 68% confidence limits). This value forv agrees excellently with the field-theoretic renormalization-group prediction, but there is some discrepancy for ₁. Earlier Monte Carlo estimates ofv, which were 0.592, are now seen to be biased by corrections to scaling. We estimate the universal ratios <R _g ² >/<R _e ² >=0.1599±0.0002 and ^*=0.2471±0.0003; since ^*>0, hyperscaling holds. The approach to ^* is from above, contrary to the prediction of the two-parameter renormalization-group theory. We critically reexamine this theory, and explain where the error lies. In an appendix, we prove rigorously (modulo some standard scaling assumptions) the hyperscaling relationdv = 2 ₄ – for two-dimensional SAWs.     

The distribution of the likelihood ratio for mixtures of densities from the one-parameter exponential family

We here consider testing the hypothesis ofhomogeneity against the alternative of a two-component mixture of densities. The paper focuses on the asymptotic null distribution of 2 log _n , where _n is the likelihood ratio statistic. The main result, obtained by simulation, is that its limiting distribution appears pivotal (in the sense of constant percentiles over the unknown parameter), but model specific (differs if the model is changed from Poisson to normal, say), and is not at all well approximated by the conventional ₍₂₎ ² -distribution obtained by counting parameters. In Section 3, the binomial with sample size parameter 2 is considered. Via a simple geometric characterization the case for which the likelihood ratio is 1 can easily be identified and the corresponding probability is found. Closed form expressions for the likelihood ratio _n are possible and the asymptotic distribution of 2 log _n is shown to be the mixture giving equal weights to the one point distribution with all its mass equal to zero and the ²-distribution with 1 degree of freedom. A similar result is reached in Section 4 for the Poisson with a small parameter value (0.1), although the geometric characterization is different. In Section 5 we consider the Poisson case in full generality. There is still a positive asymptotic probability that the likelihood ratio is 1. The upper precentiles of the null distribution of 2 log _n are found by simulation for various populations and shown to be nearly independent of the population parameter, and approximately equal to the (1–2)100 percentiles of ₍₁₎ ² . In Sections 6 and 7, we close with a study of two continuous densities, theexponential and thenormal with known variance. In these models the asymptotic distribution of 2 log _n is pivotal. Selected (1–) 100 percentiles are presented and shown to differ between the two models.     

Chapter 15 DEA/AR analysis of the 1988–1989 performance of the Nanjing textiles corporation

This article employs new data envelopment analysis/assurance region (DEA/AR) methods to evaluate the efficiency of the 35 textile factories of the Nanjing Textiles Corporation (NTC), Nanjing, China. The returns to scale (RTS) of these factories were studied without assuming that the optimal DEA solutions were unique. All DMUs are identified with pointsE (Extreme Efficient),E (Efficient but not an extreme point) andF (Frontier but not efficient). We then further identify the nonfrontier DMUs with pointsNE, NE andNF according to whether they are projected onto a point inE, E, orF en route to evaluating their performances. All of the inefficient factories were in classNF and had unique optimal primal-dual solution pairs. Consequently, the solution pairs satisfy the strong complementary slackness condition (SCSC). Application of cone-ratio (CR) ARs reduced significantly the number of factories in classE, and showed that some AR-efficient factories were more flexible in adopting the mixture of central planning and market economies that China currently is trying to use. Also, linked-cone (LC) ARs were applied to measure maximum and minimum profit ratios. The SCSC multiplier space approach was utilized to analyze the sensitivity of the efficiency results to potential errors in the data with and without ARs. The results in this article suggest that collective units had a better performance than state-owned units in the two consecutive years analyzed.This paper was written while the author was at the School of Economics and Management, Southeast University, Nanjing 210018, P.R. China.     

Stoichiometric ratio and doping effects on the thermal properties of sodium potassium sulphate crystals

The influence of stoichiometric ratio on the phase transition of sodium potassium sulphate (Na_xK_1–x)₂SO₄ crystals is investigated in the temperature range 300–500 K. The stoichiometric ratiox is chosen to bex=0.2, 0.3, 0.4, 0.8 and 0.9. The study has been carried out by using differential scanning calorimetry, DSC technique. The value of the specific heat,C _p, at the transition temperature,T _c , increases asx is increased up tox=0.4 and then decreases for higher values ofx. The change in the specific heat, C _p, is following a relation of the form C _p C _p (T–T _c /T _c )^– with = 0.12 which is in a fair agreement with the 3d Ising model. Insertion of Cu²⁺ ions into the lattice of (Na_xK_1–x)₂SO₄ crystals leads to a multiple peak in the temperature dependence ofC _p. The results are discussed from thermodynamical point of view.We would like to thank Prof. E. F. El-Wahidy, Prof. of Solid State Physics and Head of Physics Department, Faculty of Science, Alexandria University, for his interest and support of this work.