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91.
利用六面顶高压设备制备了高密度、低脆性、纳米级的ZnO块体材料,用MDI/JADE5 X射线衍射仪(Cu靶)和XL30S-FEG场发射扫描电子显微镜对高压样品的相组成、晶粒尺寸及微观形貌进行了表征.利用E55+FRA106/5傅里叶变换激光拉曼光谱仪通过ZnO块体样品位于50—500cm-1之内的拉曼光谱, 研究了极性半导体纳米材料的拉曼光谱学特征.发现在极性半导体ZnO纳米块体材料中,没有出现明显的尺寸限制效应.
关键词:
ZnO纳米块体
拉曼光谱
尺寸限制效应 相似文献
92.
Determination of a control parameter in a one-dimensional parabolic equation using the method of radial basis functions 总被引:3,自引:0,他引:3
In this work, the method of radial basis functions is used for finding the solution of an inverse problem with source control parameter. Because a much wider range of physical phenomena are modelled by nonclassical parabolic initial-boundary value problems, theoretical behavior and numerical approximation of these problems have been active areas of research. The radial basis functions (RBF) method is an efficient mesh free technique for the numerical solution of partial differential equations. The main advantage of numerical methods which use radial basis functions over traditional techniques is the meshless property of these methods. In a meshless method, a set of scattered nodes are used instead of meshing the domain of the problem. The results of numerical experiments are presented and some comparisons are made with several well-known finite difference schemes. 相似文献
93.
94.
95.
96.
Roland Opfer 《Advances in Computational Mathematics》2006,25(4):357-380
This paper reconstructs multivariate functions from scattered data by a new multiscale technique. The reconstruction uses
standard methods of interpolation by positive definite reproducing kernels in Hilbert spaces. But it adopts techniques from
wavelet theory and shift-invariant spaces to construct a new class of kernels as multiscale superpositions of shifts and scales
of a single compactly supported function φ. This means that the advantages of scaled regular grids are used to construct the
kernels, while the advantages of unrestricted scattered data interpolation are maintained after the kernels are constructed.
Using such a multiscale kernel, the reconstruction method interpolates at given scattered data. No manipulations of the data
(e.g., thinning or separation into subsets of certain scales) are needed. Then, the multiscale structure of the kernel allows
to represent the interpolant on regular grids on all scales involved, with cheap evaluation due to the compact support of
the function φ, and with a recursive evaluation technique if φ is chosen to be refinable. There also is a wavelet-like data
reduction effect, if a suitable thresholding strategy is applied to the coefficients of the interpolant when represented over
a scaled grid. Various numerical examples are presented, illustrating the multiresolution and data compression effects. 相似文献
97.
This paper summarizes a set of novel techniques for obtaining optical transformations, which are useful tools for signal processing. Then the paper focuses on deriving several interesting discrete transformations. The discussed transforms include continuous fractional transformations, hybrid transforms and discrete transform kernels. 相似文献
98.
S. Loridant G. LucazeauT. Le Bihan 《Journal of Physics and Chemistry of Solids》2002,63(11):1983-1992
A high-pressure structural study of SrCeO3 has been performed at room temperature by Raman spectroscopy and X-ray diffraction up to 32 and 45 GPa, respectively. A first-order reversible phase transition is observed at about 12 GPa in both techniques. A second weak structural change, taking place between 18 and 25 GPa, can be suspected from Raman data. The increase in the number of Raman bands and diffraction lines is an indication that the symmetry is lowered and the compound does not evolve towards the ideal cubic perovskite structure. A Rietveld analysis of X-ray data was performed for the low-pressure phase and the atomic positions and the cell lattice parameters variations are reported in this paper. The volume compressibility derived from Raman modes (5.6×10−12 Pa−1), involving mainly bond-stretching for each type of polyhedron, is found to be close to the one obtained from volume cell variations measured by X-ray diffraction (7.9×10−12 Pa−1). 相似文献
99.
由于原子簇化合物在催化,生物活性,功能材料等方面所呈现的重要性,使其成为无机和物理化学最重要的研究领域之一。文章中和谱学方法对一些具有混配体的过渡金属簇合物的结构及其两者之间的关系进行. 相似文献
100.
IR and Raman spectra of (NH4)3ZnCl5 have been recorded. The observed spectra have been analysed on the basis of the vibrations of ZnCl
4
2−
and NH
4
+
ions. The appearance of multiple Raman bands indicates the presence of two different types of ammonium ions. The effect of
anisotropic crystalline field over the ZnCl4 and NH4 tetrahedra is also discussed. The assignment of internal modes has been verified by the potential energy distribution calculations. 相似文献