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61.
Ildikó Mohammed-Ziegler Ferenc Billes 《Journal of inclusion phenomena and macrocyclic chemistry》2007,58(1-2):19-42
This review summarizes different applications of optical spectroscopic methods in calixarene chemistry including UV/Vis spectrometry,
vibrational spectroscopic techniques (FTIR and Raman spectroscopy), luminescence spectroscopy (including fluorescence and
phosphorescence), ellipsometry and various optical microscopic methods. Moreover, the results of theoretical studies (AM1,
PM3, DFT, ab initio, etc.) are summarized based on selected papers in the field of conformational studies, thermodynamics and complexation features.
About 300 references are processed systematically from the results reported mainly in the recent years with emphasis on the
potential of practical application of these molecules. 相似文献
62.
简要地介绍了中子俘获瞬发γ射线数据及其衰变纲图的评价方法技术、主要程序及其功能、数据评价流程、强度平衡检验,以及对A=1-44的稳定核素和A>190的部分稳定核素的热中子俘获瞬发γ射线数据及其衰变纲图评价的具体应用.The method of prompt γ-ray data evaluation for neutron capture and how to calculate the prompt γ-ray intensities of neutron capture have been briefly presented. The prompt γ-ray data of thermal-neutron capture of some stable nuclei for A=1-44 and A>190 have been evaluated. The ENSDF format has been adopted. The checks of intensity balance and format have been made. The examples are given to illustrate its application. 相似文献
63.
基于Karhunen-Loève变换和小波谱特征矢量量化的三维谱像数据压缩 总被引:1,自引:1,他引:0
提出了基于Karhunen Lo埁ve变换的小波谱特征矢量量化三维谱像数据压缩方法耍幔颍瑁酰睿澹?Lo埁ve变换 /小波变换 /小波谱特征矢量量化方法应用了Karhunen Lo埁ve变换的消除谱相关性优良性能 ,应用二维小波变换消除空间相关性 ,在小波变换域内应用二维集分割嵌入块编码和一维谱特征矢量量化对三维谱像数据压缩 ,获得较高的压缩性能。实验结果表明 :Karhunen Lo埁ve变换 /小波变换 /小波谱特征矢量量化编码比Karhunen Lo埁ve变换 /小波变换 /改进对块零树编码和Karhunen Lo埁ve变换 /小波变换 /快速矢量量化编码方法在同样压缩比条件下 ,峰值信噪比提高 2dB和 1dB以上 ,而速度提高了 1.5和 8倍 ,整体压缩性能有较大的提高 相似文献
64.
For the purpose of testing the spherical uniformity based on i.i.d. directional data (unit vectors) zi, i=1,…,n, Anderson and Stephens (Biometrika 59 (1972) 613–621) proposed testing procedures based on the statistics Smax=maxu S(u) and Smin=minu S(u), where u is a unit vector and nS(u) is the sum of squares of u′zi's. In this paper, we also consider another test statistic Srange=Smax−Smin. We provide formulas for the P-values of Smax, Smin, Srange by approximating tail probabilities of the limiting null distributions by means of the tube method, an integral-geometric approach for evaluating tail probability of the maximum of a Gaussian random field. Monte Carlo simulations for examining the accuracy of the approximation and for the power comparison of the statistics are given. 相似文献
65.
Francis J. Narcowich Joseph D. Ward Holger Wendland. 《Mathematics of Computation》2005,74(250):743-763
In this paper we discuss Sobolev bounds on functions that vanish at scattered points in a bounded, Lipschitz domain that satisfies a uniform interior cone condition. The Sobolev spaces involved may have fractional as well as integer order. We then apply these results to obtain estimates for continuous and discrete least squares surface fits via radial basis functions (RBFs). These estimates include situations in which the target function does not belong to the native space of the RBF.
66.
Hiroshi Sakamoto 《Journal of Discrete Algorithms》2005,3(2-4):416-430
A linear-time approximation algorithm for the grammar-based compression is presented. This is an optimization problem to minimize the size of a context-free grammar deriving a given string. For each string of length n, the algorithm guarantees approximation ratio without suffix tree construction. 相似文献
67.
Chung-Cherng Lin 《Journal of Physics and Chemistry of Solids》2004,65(5):913-921
The phase transition of a synthetic clinoenstatite in a diamond-anvil cell has been studied by using Raman spectroscopy at various pressures and room temperature. The phenomena observed in clinoenstatite have been compared with that observed in orthoenstatite. It is found that the pressure-induced phase transitions in the two enstatites are reversible, but with different transition pressures and transition behavior. An analysis of Raman spectra has revealed that the two enstatites have different high-pressure polymorphs. This result suggests that the space group of the high-pressure polymorph of orthoenstatite is not of C2/c, and that orthoenstatite and orthoferrosilite have different transition routes at room temperature and high pressure. The compressional behavior of the high-PC2/c enstatite is also discussed according to the pressure dependences of Raman frequencies. 相似文献
68.
The dynamics of a single electron submitted to a linearly polarized laser field is examined in the non-relativistic case by calculating an upper bound of the position of the electron in the time domain. 相似文献
69.
We study a system of quasilinear equations describing one-dimensional flow of a viscous compressible heat-conducting medium with a nonmonotone state function and mass force. The large-time behavior of solutions is considered for arbitrarily large initial data. In spite of possible nonuniqueness and discontinuity of the stationary solution, we prove L2-stabilization for the stress and heat flux as t → ∞ along with corresponding global energy estimates for them. The new method of proof utilizes a combination of energy type equalities for the stress and heat flux. Consequently, H1-stabilization of the velocity and temperature along with global estimates for their derivatives are valid as well. 相似文献
70.
研究了阳离子表面活性剂十六烷基三甲基溴化铵 (CTAB)对四 ( 4 N 甲基吡啶 )卟啉 (H2 TMPyP)及其银配合物 (AgTMPyP)在Ag胶中的表面增强拉曼散射 (SERS)谱的影响 .SERS光谱表明 ,吸附于Ag胶粒的H2 TMPyP与衬底银原子结合形成AgTMPyP ,加入CTAB后 ,部分AgTMPyP表面络合物还原为H2 TMPyP .相似的去金属化反应也出现在AgTMPyP/Ag胶 /CTAB体系中 .CTAB的加入使SERS谱带强度明显增加 .AgTMPyP的去金属化被认为是由于CTAB的存在使Ag胶颗粒表面附近微环境发生改变 相似文献