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101.
CuPc molecules adsorbed on Au(1 1 0)-(1 × 2): growth morphology and evolution of valence band states
Fabrizio Evangelista A. RuoccoValdis Corradini M.P. DonzelloCarlo Mariani Maria Grazia Betti 《Surface science》2003,531(2):123-130
We present the growth morphology, the long-range ordering, and the evolution of the valence band electronic states of ultrathin films of copper phthalocyanine (CuPc) deposited on the Au(1 1 0)-(1 × 2) reconstructed surface, as a function of the organic molecule coverage. The low energy electron diffraction patterns present a (5 × 3) reconstruction from the early adsorption stages. High-resolution UV photoelectron spectroscopy data show the disappearance of the Au surface states related to the (1 × 2) reconstruction, and the presence of new electronic features related to the molecule-substrate interaction and to the CuPc molecular states. The CuPc highest occupied molecular orbital gradually emerges in the valence band, while the interface electronic states are quenched, upon increasing the coverage. 相似文献
102.
I. Antoniou M. Gadella J. Mateo G.P. Pronko 《International Journal of Theoretical Physics》2003,42(10):2389-2402
Through two examples: the Friedrichs model and a particular case of central potential scattering, we illustrate the way of constructing Gamow vectors. 相似文献
103.
Influence of annealing and chain defects on the melting behaviour of poly(vinylidene fluoride) 总被引:2,自引:0,他引:2
C. Marega 《European Polymer Journal》2003,39(8):1713-1720
The melting behaviour of poly(vinylidene fluoride) (PVDF) was investigated by differential scanning calorimetry (DSC) and small- and wide-angle X-ray scattering in order to study the influence of the chain defects content and of the temperature of annealing on the crystallization and melting behaviour.All the DSC scans show a double endotherm and the analysis of the data suggests that the low temperature endotherm is due to the melting of a population of thin lamellae, whose thickness increases during the annealing, but a high content of chain defects prevents the lamellar thickening and the main effect in this case is the crystallization of thin lamellae from a portion of polymer which did not crystallize during the quenching from the melt. Furthermore, the two melting endotherms, which are observed, can be partially ascribed to a melting-recrystallization process.Furthermore, stepwise isothermal cooling was performed in a differential scanning calorimeter followed by melting scans of fractionated PVDF samples to point out the possible presence of a series of endothermic peaks. 相似文献
104.
We consider some types of packet discretization for continuous spectra in quantum scattering problems. As we previously showed, this discretization leads to a convenient finite-dimensional (i.e., matrix) approximation for integral operators in the scattering theory and allows reducing the solution of singular integral equations connected with the scattering theory to some suitable purely algebraic equations on an analytic basis. All singularities are explicitly singled out. Our primary emphasis is on realizing the method practically. 相似文献
105.
Werner Kaller 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,87(2):107-117
The angular dependence of light scattered by aerosol particles in the atmosphere—the aerosol phase function—is one of the key properties of every radiative transfer and climate model. Side-scattering in the atmosphere is currently believed to be underestimated by most of the radiative transfer models in certain cases. The aerosol phase function can be measured with polar nephelometers.An innovative polar nephelometer able to measure the phase function of ambient aerosol directly is presented in this publication. The performance of the device was simulated completely using ray-tracing techniques. The results of these simulations are used to interpret the measurement data precisely. The measurements with the new polar nephelometer are fully automated. The quality of the measurement results was verified using different approaches. The values of the statistical and systematic error in measuring atmospheric aerosol are about 4% each. Scattering angles from 10° to 160° were measured and it is shown that with the same design this range can be extended to 3-177° in steps of 0.16° with an aperture of less than 1.8°.Measurements of the aerosol phase function are presented and compared with data taken with an integrating nephelometer and measurements of the particulate matter concentration. All data correlate very well. The described polar nephelometer can measure the phase function and the scattering coefficient of atmospheric aerosol with high accuracy and can be used for continuous monitoring measurements as well as in field campaigns. 相似文献
106.
M. Ismail A. Farraga H. A. Abdusalam Th. El-Sherbini 《International Journal of Theoretical Physics》2004,43(1):111-125
The scattering of electrons by atomic copper has been studied using Born approximation and the concept of the generalized oscillator strength (GOS). Differential and total cross-sections for the excitation of the 3d10 4p2 P state are calculated at incident energies of 100 eV and are compared with other available experimental and theoretical data. The agreement between our calculation for the differential cross-section and the available experimental results is fairly good at the forward angles, while the agreement at large angles is poor. The calculated total cross-sections are compared with the experimental data and those predicted by several theories. It is found that our calculation for the total cross-sections are in a good agreement with the close coupling calculation of Msezane and Henry (1986a, Physical Review A
33, 1631) for incident energies greater than 20 eV. The integrated cross-section measurements of Ismail and Teubner (1995, Journal of Physics B: Atomic, Molecular and Optical Physics
28, 4164) are in good agreement with the present calculation. 相似文献
107.
Based. On the effective Hamiltonian with the generalized factorization approach, we calculate the branchingratios and CP asymmetries of B → VV decays in the Topcolor-assisted Technicolor (TC2) model. Within the consideredparameter space we find that: (a) for the penguin-dominated B → K* φ and K*0 φ decays, the new physics enhancementsto the branching ratios are around 40%; (b) the measured branching ratios of B →K* φ and K*0φ decays prefer therange of 3 Neffc 5; (c) the SM and TC2 model predictions for the branching ratio B(B →ρ ρ0) are only about halfof the Belle‘s measurement; and (d) for most B → VV decays, the new physics corrections on their CP asymmetries are generally small or moderate in magnitude and insensitive to the variation of mπ and Neffc. 相似文献
108.
109.
Yang Ruike Wu Zhensen You Jinguang 《International Journal of Infrared and Millimeter Waves》2003,24(8):1383-1392
The influence of sand and dust storms on modern MMW and satellite communication systems reliability have been paid more attention to. The attenuations induced by sand and dust storms are estimated by means of Mie-theory and Rayleigh approximation, in the case of the tenuous distribution of particles. With the particle density increasing, however, these method become inadequate, the multiple scattering effects then become dominant for attenuation estimation. The attenuations considering multiple scattering effects are estimated by Monte-Carlo and four fluxes method at horizontal paths. At slant paths, based on multi-layer media model, the attenuations considering multiple scattering effects are calculated by layered Monte-Carlo method at 100, 37, 24, and 14GHz. It is shown that the multiple scattering effects should be considered at the attenuation prediction in the sand and dust storm, which the visibility is about 0.5km and smaller than 0.5km and frequency is about 20GHz. Above 30GHz, the multiple scattering effects due to sand and dust particles should be considered, as visibility is about 1km and smaller than 1km at slant paths. 相似文献
110.
单壁碳纳米管的SERS研究 总被引:2,自引:2,他引:0
本文通过改进实验方法,将单壁碳纳米管的乙醇溶液与金胶混合并制作成固体薄膜,使单壁碳纳米管夹裹在金纳米粒子之间,保证了吸附的紧密性,获得了高质量的单壁碳纳米管SERS光谱。不但观测到文献中报道的径向呼吸振动模(RBM)和C-C正切拉伸模(GM)的增强,还在1100-1500cm-1区域观测到一组新峰,其峰形完整并有相当的强度。这些峰在现有的文献中几乎没有报导。文章对这组新峰的出现进行了初步的分析。 相似文献