全文获取类型
收费全文 | 786篇 |
免费 | 79篇 |
国内免费 | 52篇 |
专业分类
化学 | 359篇 |
晶体学 | 18篇 |
力学 | 67篇 |
综合类 | 14篇 |
数学 | 239篇 |
物理学 | 220篇 |
出版年
2023年 | 9篇 |
2022年 | 32篇 |
2021年 | 24篇 |
2020年 | 17篇 |
2019年 | 17篇 |
2018年 | 26篇 |
2017年 | 26篇 |
2016年 | 29篇 |
2015年 | 18篇 |
2014年 | 48篇 |
2013年 | 70篇 |
2012年 | 34篇 |
2011年 | 27篇 |
2010年 | 20篇 |
2009年 | 34篇 |
2008年 | 37篇 |
2007年 | 52篇 |
2006年 | 34篇 |
2005年 | 27篇 |
2004年 | 24篇 |
2003年 | 43篇 |
2002年 | 39篇 |
2001年 | 26篇 |
2000年 | 26篇 |
1999年 | 24篇 |
1998年 | 17篇 |
1997年 | 17篇 |
1996年 | 9篇 |
1995年 | 8篇 |
1994年 | 11篇 |
1993年 | 12篇 |
1992年 | 14篇 |
1991年 | 6篇 |
1990年 | 5篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 7篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1983年 | 5篇 |
1982年 | 10篇 |
1981年 | 1篇 |
1980年 | 4篇 |
1979年 | 6篇 |
1978年 | 1篇 |
1976年 | 2篇 |
1972年 | 2篇 |
1971年 | 1篇 |
排序方式: 共有917条查询结果,搜索用时 0 毫秒
1.
This paper investigates the large scale travelling ionospheric disturbances (LSTIDs) using the observation data of an HF Doppler array located in Central China. The data observed in a high solar activity year (year 1989) are analyzed to obtain the main propagation parameters of LSTIDs such as period, horizontal phase velocity and propagating direction. Results are outlined as follows: Most of the LSTIDs propagate southward; others tend to propagate northward, mostly in summer; dispersion of most LSTIDs is matched with that of Lamb pseudomode, while others have the dispersion of long period gravity wave mode. The horizontal phase velocities of these two modes are about 220 and 450 m/s respectively. The analysis shows that LSTIDs are strongly pertinent to solar activity and space magnetic storms; thus the results presented here are significant for the research of ionospheric weather in mid-low latitude region. 相似文献
2.
A. Truffert 《Annals of Operations Research》1991,30(1):115-156
The conditional expectation of integrands and random sets is the main tool of stochastic optimization. This work wishes to make up for the lack of real synthesis about this subject. We improve the existing hypothesis and simplify the corresponding proofs. In the convex case we especially study the problem of the exchange of conditional expectation and subdifferential operators. 相似文献
3.
Summary Campaign results of high-repetition ionospheric soundings, performed at the ionospheric station of Rome using a Digisonde
128P, are presented. We introduce an index derived from run rapid ionograms that can be used to detect oscillations of isodensity
surfaces ofF ionospheric region started by morning solar terminator. 相似文献
4.
Chang-jian Zhao 《中国科学A辑(英文版)》2007,50(9):1347-1360
In this paper, we first introduce a concept of L
p
-dual Quermassintegral sum function of convex bodies and establish the polar projection Minkowski inequality and the polar
projection Aleksandrov-Fenchel inequality for L
p
-dual Quermassintegral sums. Moreover, by using Lutwak’s width-integral of index i, we establish the L
p
-Brunn-Minkowski inequality for the polar mixed projection bodies. As applications, we prove some interrelated results.
This work was partially supported by the National Natural Science Foundation of China (Grant No. 10271071), Zhejiang Provincial
Natural Science Foundation of China (Grant No. Y605065) and Foundation of the Education Department of Zhejiang Province of
China (Grant No. 20050392) 相似文献
5.
Two matrix approximation problems are considered: approximation of a rectangular complex matrix by subunitary matrices with
respect to unitarily invariant norms and a minimal rank approximation with respect to the spectral norm. A characterization
of a subunitary approximant of a square matrix with respect to the Schatten norms, given by Maher, is extended to the case
of rectangular matrices and arbitrary unitarily invariant norms. Iterative methods, based on the family of Gander methods
and on Higham’s scaled method for polar decomposition of a matrix, are proposed for computing subunitary and minimal rank
approximants. Properties of Gander methods are investigated in details.
AMS subject classification (2000) 65F30, 15A18 相似文献
6.
Dielectric relaxation study of the binary mixtures of poly(vinyl pyrrolidone) (PVP) (Mw=24000, 40000 and 360000 g mol−1) with ethyl alcohol (EA) and poly(ethylene glycol)s (PEGs) (Mw=200 and 400 g mol−1) in dilute solutions of dioxane were carried out at 10.1 GHz and 35°C. The relaxation time of PVP-EA mixtures was interpreted
by the consideration of a wait-and-switch model in the local structure of self-associated ethyl alcohol molecules and also
the PVP chain length as a geometric constraint for the reorientational motion of ethyl alcohol molecules. The formation of
complexes and effect of PVP chain length on the molecular dynamics, chain flexibility and stretching of PEG molecules in PVP-PEG
mixtures were explored from the comparative values of dielectric relaxation time. Further, relaxation time values in dioxane
and benzene solvent confirm the viscosity independent molecular dynamics in PVP-EA mixtures but the values vary significantly
with the non-polar solvent environment. 相似文献
7.
Mao-fengZhang Qiao-hongYao Chun-huiHuang Wei-xiaoCao 《高分子科学》2005,(1):27-27
A kind of azo-containing resin (Azo-R) was synthesized by a simple way through the coupling reaction of 2-nitro-N-methyldiphenylamine-4-diazoresin (NDR) with phenol, and a new covalentely attached multilayer film from Azo-R as H-donor and photosensitive diazoresin, diphenylamine-4-diazoresin (DR) as H-acceptor via H-bonding attraction by selfassembly technique has been fabricated. Following the decomposition of diazonium group of DR under exposure to UV light, the H-bonds between the layers of the film convert to covalent bonds and the film becomes very stable toward polar solvents or electrolyte aqueous solutions. Thus the UV-irradiated azo-containing films can be used to measure photocurrent in a conventional three-electrode photoelectrochemical cell using KCl as supporting electrolyte. It was confirmed that the azo-containing multilayer film is responsible for the photocurrent generation. 相似文献
8.
This review covers our extensive research activities in the area of fluorine containing phospha- and arsaalkenes as well as selenocarbonyls, which differ considerably in their properties and reactivities from their alkyl and aryl counterparts and thus contribute in a gratifying manner to the still growing field of unsaturated element-carbon compounds of 3rd and 4th row main group elements E. Of particular interest is the influence of the fluorine substituents and other small groups (OR, NR2) with either inductive and/or mesomeric effects on the polarity and reactivity of the EC bond. Addition reactions of proton acidic and hydridic polar HX reactants as well as [2+2], [3+2] and [4+2] cycloadditions have been thoroughly studied. The results obtained allow a classification of the EC systems within five different types, A to E, and prove a change from “normal” to “inverse” heteroalkenes in this sequence. The ligand properties of some derivatives have also been investigated in some detail. 相似文献
9.
A. N. Ageev A. A. Aratskova L. D. Belyakova T. N. Gvozdovich A. V. Kiselev Ya. I. Yashin J. Kàlal F. Švec 《Chromatographia》1983,17(10):545-548
Summary The retention of benzene derivatives with nonpolar and polar substituents on a porous methacrylate copolymer containing epoxy groups using both nonpolar and polar eluents was investigated. When n-hexane is used as the eluent, the retention of n-alkylbenzenes and polymethylbenzenes is weaker than that of benzene. In the case of benzene derivatives containing polar functional groups their capacity ratios (k) on this porous polymer increases approximately linearly with the increase of the adsorbate molecules dipole moment. The retention characteristics of the methacrylate copolymer were compared with that of a styrene-divinylbenzene copolymer and silica gels with a hydroxylated surface and with a surface modified by chemically bonded alkylsilyl groups. 相似文献
10.
Two published procedures for glass capillary column production are applied to produce capillaries for chromatography of polar natural compounds. Soda lime glass capillaries, after leaching with aqueous HCL, are either treated with colloidal silicic acid or with barium carbonate and coated with either Silar 7CP or SE 52. A test mixture as well as polar carbohydrate and peptide mixtures are chromatographed on the different columns and their chromatographic properties are evaluated. Combined capillary gas chromatography-electron impact and chemical ionization mass spectrometry are used for identification of the peptide sequence. 相似文献