Influence of Crystallization Conditions on Relaxation Properties of Polymer Near-Surface Layers

Relaxation properties of polymer near-surface layers were investigated with the help of thermoluminescent method using Nanoluminograph (PlasmaChem GMbH, Germany). The gel- and melt-crystallized films from PE of different molecular weight were studied. The light sum of thermoluminescence in the temperature range of various relaxation transitions was compared. It is found that it is primarily controlled by the type of morphology forming during crystallization and the arrangement of the structural units on a surface. The glass transition temperature in near-surface layers appeared to be lower that that in the bulk. Bulk glass transition temperature was determined by radiothermoluminescence, DMA and DSC techniques.     

Coherent Dynamic Structure Factor of a Polymer Chain Confined Into a Harmonic Radial Potential

The coherent dynamic structure factor of a single polymer chain is calculated based on the model of a Rouse polymer chain constrained (confined) by a harmonic radial potential and its behavior in different limiting cases is analyzed. The strength of confinement is characterized using an effective diameter of the harmonic radial potential as a model parameter. The method provides a reliable model to study the crossover between unconstrained (Rouse) and constrained dynamics.

     

Phonon relaxation and heat conduction in one-dimensional Fermi-Pasta-Ulam β lattices by molecular dynamics simulations

The phonon relaxation and heat conduction in one-dimensional Fermi-Pasta-Ulam (FPU) β lattices are studied by using molecular dynamics simulations.The phonon relaxation rate,which dominates the length dependence of the FPU β lattice,is first calculated from the energy autocorrelation function for different modes at various temperatures through equilibrium molecular dynamics simulations.We find that the relaxation rate as a function of wave number k is proportional to k 1.688,which leads to a N 0.41 divergence of the thermal conductivity in the framework of Green-Kubo relation.This is also in good agreement with the data obtained by non-equilibrium molecular dynamics simulations which estimate the length dependence exponent of the thermal conductivity as 0.415.Our results confirm the N 2/5 divergence in one-dimensional FPU β lattices.The effects of the heat flux on the thermal conductivity are also studied by imposing different temperature differences on the two ends of the lattices.We find that the thermal conductivity is insensitive to the heat flux under our simulation conditions.It implies that the linear response theory is applicable towards the heat conduction in one-dimensional FPU β lattices.     

Evolution of the 251 cm-1 temperature in infrared phonon mode with Ba0.6K0.4Fe2As2

The far-infrared optical reflectivity of an optimaUy doped Ba1-xKxFe2As2 （x = 0.4） single crystal is measured from room temperature down to 4 K. We study the temperature dependence of the in-plane infrared-active phonon at 251 em-1. This phonon exhibits a symmetric line shape in the optical conductivity, suggesting that the coupling between the phonon and the electronic background is weak. Upon cooling down, the frequency of this phonon continu- ously increases, following the conventional temperature dependence expected in the absence of a structural or magnetic transition. The intensity of this phonon is temperature independent within the measurement accuracy. These observa- tions indicate that the structural and magnetic phase transition might be completely suppressed by chemical doping in the optimally doped Bao.6Ko.4Fe2As2 compound.     

Response of thermal source in a transversely isotropic thermoelastic half-space with mass diffusion by using a finite element method

The two-dimensional problem of generalized thermoelastic diffusion material with thermal and diffusion relaxation times is investigated in the context of the Lord-Shulman theory.As an application of the problem,a particular type of thermal source is considered and the problem is solved numerically by using a finite element method.The components of displacement,stress,temperature distribution,chemical potential,and mass concentration are obtained.The resulting quantities are depicted graphically for a special model.An appreciable effect of relaxation times is observed on various resulting quantities.     

Continuum Model for Electronic Polarization Based on a Novel Dielectric Response Function

A generalized response function based on the use of dielectric spectra for dielectric relaxation process is derived. We apply the general response function to the special case in order to examine how special dielectric relaxation functions developed by other authors for solvent relaxation can be derived based on our formulations. Three typical solvents, water, methanol, and acetonitrile are used to investigate the electronic polarization processes of polar solvents. The solvent electronic polarization process is shown after a linear variation with the external electric field imposed on the solvent. The results show a conclusion that the electronic polarization of the solvents will accompany the electronic transition synchronously, without time lag.     

新疆长绒棉辐射效应的谱学研究

用¹³C CP/MAS NMR谱、ESR谱和质子弛豫时间等方法,研究了经γ射线在室温下辐照后新疆长绒棉纤维的辐射效应. 结果表明随着辐照剂量的增加,长绒棉纤维内的自由基浓度明显的增大,并产生了多种自由基的混合物. 由辐照前后的长绒棉纤维的¹³C CP/MAS NMR谱可以得出,随着辐射剂量的增加,C1峰的谱宽趋向增宽,表明了自由基存在的位置. 各类弛豫时间的改变则反映出长绒棉纤维内部聚集态结构和大分子链运动随辐射剂量的变化.     

Micron-scale origin of the shear-induced structure in Laponite–poly(ethylene oxide) dispersions

We study the transient response to simple shear of aqueous dispersions of Laponite clay particles and poly(ethylene oxide) at concentrations for which shear induces structure in the form of a network of polymer–clay bonds. We examine the effects of shear on the structure at the micrometer length scale. Bulk rheometric measurements give the material’s response to step changes in shear rate. We find that a critical value of the shear rate separates two regions with different rheological behaviors. Static small-angle light scattering shows a corresponding qualitative change in the anisotropy of the dispersion under shear at the micron scale. We interpret our results in terms of the effects of shear on the interactions between clay particles and polymer chains and on the aggregation mechanisms in the dispersion.     

基于动力松弛法的松弛索杆体系找形分析

索杆张力结构施工成形分析需要解决一个松弛态索杆系统的平衡形态求解问题,该问题可归结为一个给定构件原长的受荷索杆机构系统的找形问题。文中利用动力松弛法进行该类松弛索杆体系的找形分析。由于不建立刚度矩阵,避免了体系几何不稳定性所引起的刚度矩阵奇异问题。该方法采用悬链线索单元模型,可以考虑索大垂度效应。文中还推导了反映索原长和内力之间关系的悬链线索单元协调方程。通过一个正交松弛索网算例分析,考察了该找形方法的计算精度和收敛性。最后还模拟了一个索穹顶的施工成形过程,表明了该找形方法用于索杆张力结构施工成形分析的有效性。     

Effect of the liquid-like ionic structure on the electron–ion energy relaxation timescales in dense plasmas

In a recent publication [J. Daligault, D. Mozyrsky, Phys. Rev. E 75 (2007) 026402], we derived a general expression for the electron–ion energy relaxation rate in plasmas which, as a result of the small electron–ion mass ratio, expresses the relaxation rate in terms of the low-frequency electronic density fluctuations. Here we propose a practical model for the electronic density fluctuations in dense plasmas and apply this model to the calculation of the electron–ion energy relaxation rate. We find that the rate is only scarcely affected by the underlying liquid-like ionic disorder typical of dense matter. Relaxation rates obtained are systematically slightly larger than those predicted by the Fermi Golden Rule formula, in contradiction with the coupled-modes' theory that predicts values an order of magnitude lower. We also find that the discontinuity of the rate at melting is tiny, in contrast with the sharp increase of the electrical conductivity.