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181.
Katsuhiro Inomata Chieko Fukuda Kuniyoshi Hori Hideki Sugimoto Eiji Nakanishi 《Journal of Polymer Science.Polymer Physics》2007,45(2):129-137
The phase behavior and crystallization of graft copolymers consisting of poly(n‐hexyl methacrylate) (PHMA) as an amorphous main chain and poly(ethylene glycol) (PEG) as crystallizable side chains (HMAx with 15 ≤ x ≤ 73, where x represents the weight percentage of PEG) were investigated. Small‐angle X‐ray scattering profiles measured above the melting temperature of PEG suggested that a microdomain structure with segregated PHMA and PEG domains was formed in HMA40 and HMA46. This phase behavior was qualitatively described by a calculated phase diagram based on the mean‐field theory. Because of the segregation of PEG into microdomains, the crystallization temperature of the PEG side chains in HMAx was higher than that in poly(methyl acrylate)‐graft‐poly(ethylene glycol) having a similar value of x, which was considered to be in a disordered state above the melting temperature. In HMAx with x ≤ 40, PEG crystallization was strongly restricted, probably because the PEG microdomains were isolated in the PHMA matrix. As a result, the growth of PEG spherulite was not observed because the PEG crystallization occurred after vitrification of the PHMA segregated domains. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 129–137, 2007 相似文献
182.
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184.
Yoshihide Yoshimoto 《Surface science》2004,556(1):52-62
A conception of a structure formation suitable for nano-technology is proposed, which is programmable and suitable for mass production-like lithography. This conception utilizes the controlled folding of chains like the scan-lines of television. Its possibility and property were studied theoretically using the modeled chains consist of beads. By adopting the interaction among the beads which can distinguish the kind of the partner by its polarity and is chiral to break the chiral symmetry of the folded state, the special chains which have the unique ground states could be designed. In these ground states, the chains are folded like the scan-lines of television. The thermodynamic properties of the suggested chains were studied by the Monte Carlo simulations and the suggested chains showed the phase-transition-like behavior which is distinct compared to both the random chains and the chain that has only the non-specific attraction. The size dependence and the effects of adding the non-specific attraction and modifying the border of the folded conformation were also studied. 相似文献
185.
L. Stoch 《Journal of Thermal Analysis and Calorimetry》1997,49(3):1433-1440
Chemical component exchange and transport phenomena accompanying the multistage phase transformations of several silicate and aluminosilicate-phosphate glasses and borates as model systems are considered. It is demonstrated that the component transport limitations modify the role of chemical affinity influence and determine the sequence of new compound formation.The work was supported by grant P040703406 from the National Committee of Scientific Research of Poland. 相似文献
186.
关于李萨如图形讨论的小结 总被引:4,自引:0,他引:4
对《大学物理》和其它一些刊物上多年来关于李萨如图形的讨论作了归纳和分析。 相似文献
187.
G. F. Brand 《International Journal of Infrared and Millimeter Waves》1997,18(9):1655-1662
A millimeter-wave interferometer operating purely on the geometric phase is presented. Like its optical counterpart described
by Hariharan and Roy, this system uses two circular polarizers with a half-wave section in between. The geometric phase of
each signal is determined by the orientation of the half-wave section. 相似文献
188.
P. Galatola M. Zelazna I. Lelidis 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,2(1):51-56
We study the surface behavior of a semi-infinite smectogenic sample bounded by a solid wall, in the presence of an external
electric field. Our analysis is performed in the framework of a Landau-de Gennes theory. For the sake of simplicity, we consider
only the case in which, in the absence of field and surfaces, a direct isotropic to smectic-A transition occurs, while in
the presence of the electric field a nonspontaneous nematic phase appears. Two new surface phases are identified, namely a
parasmectic and a surface-induced smectic phase. The shifts in the transition temperatures and the critical behavior of the surface states are analyzed.
Received: 25 August 1997 / Accepted: 23 January 1998 相似文献
189.
K. Held D. Vollhardt 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,5(3):473-478
The importance of Hund's rule coupling for the stabilization of itinerant ferromagnetism is investigated within a two-band
Hubbard model. The magnetic phase diagram is calculated by finite-temperature quantum Monte-Carlo simulations within the dynamical
mean-field theory. Ferromagnetism is found in a broad range of electron fillings whereas antiferromagnetism exists only near
half filling. The possibility of orbital ordering at quarter filling is also analyzed.
Received: 26 February 1998 / Accepted: 17 April 1998 相似文献
190.
Linear propagation of two pulses through methanol solution of aluminum phthalocyanine chloride is investigated using a modified white-light Michelson interferometer. The observed coherence time of the white light is 6 fs, and the separation between the two-excitation pulses is set to about 10 fs. The excitation is dependent on the phase-relation between the two pulses. We have observed an enhancement of the excitation when the two pulses are in-phase and strong suppression of the excitation when the two pulses are out of phase by π. 相似文献