全文获取类型
收费全文 | 21948篇 |
免费 | 3489篇 |
国内免费 | 1915篇 |
专业分类
化学 | 14413篇 |
晶体学 | 523篇 |
力学 | 1373篇 |
综合类 | 190篇 |
数学 | 1012篇 |
物理学 | 9841篇 |
出版年
2024年 | 34篇 |
2023年 | 150篇 |
2022年 | 416篇 |
2021年 | 446篇 |
2020年 | 617篇 |
2019年 | 605篇 |
2018年 | 619篇 |
2017年 | 760篇 |
2016年 | 985篇 |
2015年 | 907篇 |
2014年 | 961篇 |
2013年 | 2312篇 |
2012年 | 1319篇 |
2011年 | 1340篇 |
2010年 | 1123篇 |
2009年 | 1202篇 |
2008年 | 1253篇 |
2007年 | 1261篇 |
2006年 | 1222篇 |
2005年 | 1077篇 |
2004年 | 1081篇 |
2003年 | 957篇 |
2002年 | 1032篇 |
2001年 | 703篇 |
2000年 | 721篇 |
1999年 | 600篇 |
1998年 | 509篇 |
1997年 | 415篇 |
1996年 | 366篇 |
1995年 | 382篇 |
1994年 | 290篇 |
1993年 | 250篇 |
1992年 | 241篇 |
1991年 | 171篇 |
1990年 | 149篇 |
1989年 | 115篇 |
1988年 | 120篇 |
1987年 | 105篇 |
1986年 | 101篇 |
1985年 | 85篇 |
1984年 | 79篇 |
1983年 | 42篇 |
1982年 | 56篇 |
1981年 | 31篇 |
1980年 | 34篇 |
1979年 | 40篇 |
1978年 | 13篇 |
1977年 | 9篇 |
1976年 | 7篇 |
1973年 | 17篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
41.
Ana Luísa Daniel‐da‐Silva João Carlos Moura Bordado José Miguel Martín‐Martínez 《Journal of Polymer Science.Polymer Physics》2007,45(22):3034-3045
The degree of phase separation in several moisture‐cured poly(urethane urea)s (PUUs) was studied by FTIR spectroscopy, wide angle X‐ray diffraction (WAXD), and temperature‐modulated differential scanning calorimetry (TMDSC). This latter technique was shown to be particularly useful in analysing the degree of phase separation in PUU polymers. Both phase mixing and phase segregation coexisted in the PUUs and the degree of phase separation increased as the urea hard segment (HS) content in the PUU increased. The maximum solubility of urea HSs into the polyol soft segments (SSs) was achieved for 50 wt % urea HS content in diol‐based PUUs, whereas for triol‐based PUUs the highest solubility between HS and SS was reached for lower urea HS amount. Finally, the higher the urea HS content the higher the extent of phase separation in the PUU. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3034–3045, 2007 相似文献
42.
Rhythmic growth of ring‐banded spherulites in blends of liquid crystalline methoxy‐poly(aryl ether ketone) (M‐PAEK) and poly(aryl ether ether ketone) (PEEK) has been investigated by means of differential scanning calorimetry (DSC), polarized light microscopy (PLM), and scanning electron microscopy (SEM) techniques. The measurements reveal that the formation of the rhythmically grown ring‐banded spherulites in the M‐PAEK/PEEK blends is strongly dependent on the blend composition. In the M‐PAEK‐rich blends, upon cooling, an unusual ring‐banded spherulite is formed, which is ascribed to structural discontinuity caused by a rhythmic radial growth. For the 50:50 M‐PAEK/PEEK blend, ring‐banded spherulites and individual PEEK spherulites coexist in the system. In the blends with PEEK as the predominant component, M‐PAEK is rejected into the boundary of PEEK spherulites. The cooling rate and crystallization temperature have great effect on the phase behavior, especially the ring‐banded spherulite formation in the blends. In addition, the effects of M‐PAEK phase transition rate and phase separation rate on banded spherulite formation is discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3011–3024, 2007 相似文献
43.
本文提出从高分辨电子显微像中,利用光学、全息和部分相干等方法,提取传递函数,制作相位和振幅滤波器,实现解卷,提高高分辨电子显微像的分辨率. 相似文献
44.
M. Faucher D. Garcia E. Antic-Fidancev M. Lemaitre-Blaise 《Journal of Physics and Chemistry of Solids》1989,50(12)
Some structural and spectroscopic features of rare earth orthoaluminates are examined.The trigonal→ orthorhombic transition is studied in a series of NdxSm1−xAlO3 compounds. The evolution of the crystal structure is followed by X-ray analysis and optical absorption. The free ion and crystal field parameters of Nd3+ (4f3 configuration) are determined in LuAlO3:Nd3+.The anomaly of the calculated splitting of the
levels is slight, but well characterized in NdAlO3. The spin correlated crystal field and orbitally correlated crystal field models are tested as well as an empirical correction which was proposed earlier. 相似文献
45.
46.
Settling of a large solid particle in bioconvection flow caused by gyrotactic microorganisms is investigated. The particle is released from the top of the bioconvection chamber; its settling pattern depends on whether it is released in the centre of the bioconvection plume or at its periphery. The Chimera method is utilized; a subgrid is generated around a moving particle. The method suggested by Liu and Wang (Comput. Fluid 2004; 33 :223–255) is further developed to account for the presence of a moving boundary in the streamfunction‐vorticity formulation using the finite‐difference method. A number of cases for different release positions of the particle are computed. It is demonstrated that bioconvection can either accelerate or decelerate settling of the particle depending on the initial position of the particle relative to the plume centre. It is also shown that the particle impacts bioconvection plume by changing its shape and location in the chamber. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
47.
Johan Revstedt 《国际流体数值方法杂志》2004,45(7):775-795
The flow around spherical, solid objects is considered. The boundary conditions on the solid boundaries have been applied by replacing the boundary with a surface force distribution on the surface, such that the required boundary conditions are satisfied. The velocity on the boundary is determined by extrapolation from the flow field. The source terms are determined iteratively, as part of the solution. They are then averaged and are smoothed out to nearby computational grid points. A multi‐grid scheme has been used to enhance the computational efficiency of the solution of the force equations. The method has been evaluated for flow around both moving and stationary spherical objects at very low and intermediate Reynolds numbers. The results shows a second order accuracy of the method both at creeping flow and at Re=100. The multi‐grid scheme is shown to enhance the convergence rate up to a factor 10 as compared to single grid approach. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
48.
We carried out detailed calculations for photorefractive wave-mixing switches based on one of three crystals with high electro-optic coefficients, namely, BaTiO3, Strontium Barium Niobate (SBN (0.75)), and Potasium Sodium Strontium Barium Niobate (KNSBN). A comparison of results for the three crystals shows that a 0_-cut BaTiO3 crystal is suitable for a longitudinal switch and requires a voltage of about 80 for a 2-mm-thick crystal to induce sufficient phase mismatch. The electrodes must be transparent for the incident and diffracted beams. A 45_-cut SBN (0.75) crystal, however, is suitable for a lateral switch and requires a voltage of about 150 for a 1-mm-wide crystal. The electrodes do not need to be transparent. 相似文献
49.
Takeshi Murashige Hideo Fujikake Hiroto Sato Hiroshi Kikuchi Taiichiro Kurita Fumio Sato 《Optical Review》2004,11(6):349-352
We have confirmed light diffraction of aligned polymer fibers obtained by a phase separation of an anisotropic-phase solution of liquid crystal and polymer. He—Ne laser light passing through the polymer fibers was scattered in the axis vertical to the fibers, and had two peaks of light intensity symmetrical to the center of the transmitting laser spot. The two peaks were found to be caused by light diffraction due to the periodic polymer-fiber dispersion because the peaks corresponded to values calculated by intervals between the fibers. The periodical fiber networks are considered to be formed by anisotropic spinodal decomposition. This effect can be used to measure the dispersion order of the polymer fibers. © 2004 The Optical Society of Japan 相似文献
50.
The problem of investigation of the amplitude and phase structure of a time-varying probing optical signal and the structure of time-varying inhomogeneities of a substance tested by this signal is considered. The analysis is concerned, in particular, with determination of the structure of signals and processes with resolution in the pico- and femtosecond range. The scheme used for the analysis is based on registration of four spatially separated spectra of the studied radiation. The spectra are formed in a four-channel scheme with a twin-wave Michelson interferometer and a spectral device. Modulators based on electrooptical crystals (perovskites) are placed in the channels. The sum spectra are formed: without modulators, with the effect of either of the modulators, and with both of them affecting the radiation. The effect of the studied substance implies either modulating the radiation (in this case it is described by multiplication) or redistributing the radiation (then it is described by convolution). 相似文献