MgO/Pt界面对增强Co/Ni多层膜垂直磁各向异性及热稳定性的研究

采用直流磁控溅射法在玻璃基片上制备了Pt底层和MgO/Pt双底层的Co/Ni多层膜样品, 通过反常霍尔效应研究了不同MgO厚度和退火温度对样品垂直磁各向异性(perpendicular magnetic anisotropy, PMA)的影响. 随着底层中MgO厚度的逐渐增加, 样品的矫顽力也随之增强, 霍尔电阻变化不大; 对样品进行退火处理后发现, 单纯Pt底层的Co/Ni多层膜随着退火温度的升高, 霍尔电阻逐渐降低, 矫顽力则迅速降低, 热稳定性较差; 而当MgO/Pt双底层的样品在200 ℃退火后矫顽力大幅增加, 霍尔电阻略微有所减小, 更高的退火温度使得Co和Ni合金化, 导致多层膜的PMA特征减弱.     

电结晶制Co/Pt多层膜的结构及磁性研究

以单晶Si(111)为基底, 在以P盐[主要成分Pt(NO₂)₂(NH₃)₂]和CoSO₄为主盐的硼酸体系中电结晶Co/Pt多层膜. SEM观察多层膜的断面形貌, 证实多层膜具有周期结构. 经XRD测试, 首次证实了Co-Pt界面上有CoPt₃化合物的存在. 用PPMS测试了多层膜的磁滞回线, 平行于外磁场时膜的矫顽力约为165 Oe, 垂直于外磁场时的矫顽力随Co含量的增加而增加, 最大达到396 Oe. 首次用电结晶方法制得了易磁化轴垂直于膜面的Co/Pt多层膜.     

Magnetic properties of soft layer/FePt--MgO exchange coupled composite perpendicular recording media

The magnetic properties of exchange coupled composite （ECC） media that are composed of perpendicular magnetic recording media FePt MgO and two kinds of soft layers have been studied by using an x-ray diffractometer, a polar Kerr magneto-optical system （PMOKE） and a vibrating sample magnetometer （VSM）. The results show that ECC media can reduce the coercivities of perpendicular magnetic recording media FePt-MgO. The ECC media with granular-type soft layers have weaker exchange couplings between magnetic grains and the magnetization process, for ECC media of this kind mainly follow the Stoner Wohlfarth model.     

Homogeneous and Solid-Gas Hydrogenation of Alkynes in the Presence of the Clusters Fe3(CO)9(ε-RC2 R 1) {R=R 1=Ph, Et; R=Me, R 1=Ph}: Characterization of New Metallacyclic Derivatives

The clusters Fe₃(CO)₉(RC₂ R ¹) (R=R ¹=Ph, Et; R=Me, R ¹=Ph), complexes 1a, 1b, 1c, containing an alkyne bound in perpendicular fashion with respect to a cluster edge, catalyze the hydrogenation of some acetylenes either under homogeneous and solid–gas conditions. We hypothesize that cluster catalysis occurs and that the catalytic activity is related to the coordinating ability of the alkynic substrates. Competition between hydrogenation and formation of metallacyclic byproducts occurs. The new metallacyclic derivatives Fe₃(CO)₆(-CO)₂{(RC₂ R ¹)(R ²C₂ R ³)}, Fe₂(CO)₆{(RC₂ R ¹)(R ²C₂ R ³)} {R=R ¹=Et, R ²=R ³=H, Ph; R ²=Me, R ³=Et, Ph; R ²=H, R ³=Bu ^t . R=R ¹=Ph, R ²=Me, R ³=Et, Ph} (complexes 2, 3) were found both in the homogeneous reaction mixtures and after the solid–gas reactions. The formation of these products lowers the catalytic activity.     

多种优化方法及其在高温超导磁体优化设计中的应用

本文阐述了几种优化方法及其对它们的改进,并选用测试函数对各种方法的寻优性能作了对比;然后阐述了高温超导磁体的径向磁场对临界电流的影响及最大径向磁场的位置定标方法;最后将各种优化方法应用于高温超导磁体的设计中.经过优化,高温超导磁体大大减小了其体积,提高了超导材料的利用率,节约了超导材料的用量及制冷时所损耗的电源功率.     

Representation theory of Dynkin quivers. Three contributions

The representations of the Dynkin quivers and the corresponding Euclidean quivers are treated in many books. These notes provide three building blocks for dealing with representations of Dynkin (and Euclidean) quivers. They should be helpful as part of a direct approach to study represen-tations of quivers, and they shed some new light on properties of Dynkin and Euclidean quivers.     

磁控溅射方法制备垂直取向FePt/BN颗粒膜

用磁控溅射在热单晶MgO(100)基片上制备了［FePt/BN］多层膜，经真空热处理后，得到具有垂直取向L1₀-FePt/BN颗粒膜.X射线衍射结果和磁性测量的结果表明，［FePt(2nm)/BN(0.5nm)］₁₀和［FePt(1nm)/BN(0.25nm)］₂₀多层膜经700℃热处理1h后，均具有较好的(001)取向.［FePt(1nm)/BN(0.25nm)］₂₀垂直矫顽力达到522kA/m，剩磁比达到0.99，开关场分布S达到0.94，FePt晶粒平均尺寸约15—20nm，适合用于将来超高密度的垂直磁记录介质. 关键词： 磁控溅射 垂直磁记录 0-FePt/BN纳米颗粒膜')" href="#">L1₀-FePt/BN纳米颗粒膜     

Influence of experimental parameters on dominant energy transfer mechanisms

Three pairs of dyes which operate as efficient energy transfer dye lasers in ethanol have been investigated to understand the dominant energy transfer mechanisms taking place in them. Special attention is given to the experimental configuration which is expected to influence the energy transfer rate constants over an order of magnitude or two. Fluorescence lifetimes have also been studied using time correlated single photon counting technique. It is found that apart from the excitation source and the concentration of dyes, the experimental configuration has a crucial role to play in determining the dominant energy transfer mechanism.     

Some t-Homogeneous Sets of Permutations

Perpendicular Arrays are orderedcombinatorial structures, which recently have found applicationsin cryptography. A fundamental construction uses as ingredientscombinatorial designs and uniformly t-homogeneoussets of permutations. We study the latter type of objects. Thesemay also be viewed as generalizations of t-homogeneousgroups of permutations. Several construction techniques are given.Here we concentrate on the optimal case, where the number ofpermutations attains the lower bound. We obtain several new optimalsuch sets of permutations. Each example allows the constructionof infinite families of perpendicular arrays.     

高尔夫球绕流流场数值研究

采用基于Smagorinsky-Lilly亚格子模型的大涡模拟方法模拟了 一个直径为42.6 mm, 布有均匀凹坑的高尔夫球的绕流流场, 证实了其尾涡分离点比光滑球的 分离点远, 其绕流阻力较小. 模拟了自转速度为100 rad/s的正旋和逆旋的高尔夫球, 发现它 们的尾流分布更不均匀, 并因此产生了垂直于来流方向的压力, 压力大小不受自转方向的影 响; 并发现带有旋转效应的凹坑高尔夫球受到的阻力系数增大; 自旋对于球的上下面压力有 明显影响.