In this paper, we report on the tunable metal‐enhanced fluorescence (MEF) of Ag nanostructures. Because of the good MEF properties of the highly dendritic Ag nanostructures, we obtained an increase of up to 25 times for the weak fluorescence of porphyrin molecules (Por4–). More importantly, by the introduction of a stimulus‐responsive PAA/PDDA multilayer film as an interlayer, the distance between the fluorophores and the Ag nanostructures could be tuned by immersing the substrates into solutions of different ionic strength or pH. The MEF behavior of the composite films could thus be tuned in a controlled manner, because of the distance dependent nature of the MEF effects.
Co2FeAl0.5Si0.5 (CFAS)-based multilayers sandwiched by MgO layers have been deposited and annealed at different temperatures. Perpendicular magnetic anisotropy (PMA) with the magnetic anisotropy energy density Ku ≈2.5×106 erg/cm3 (1 erg = 10-7 J) and the coercivity Hc = 363 Oe (1 Oe = 79.9775 A · m-1) has been achieved in the Si/SiO2/MgO (1.5 nm)/CFAS (2.5 nm)/MgO (0.8 nm)/Pt (5 nm) film annealed at 300 ℃. The strong PMA is mainly due to the top MgO layer. The structure can be used as top magnetic electrodes in half-metallic perpendicular magnetic tunnel junctions. 相似文献
Interfacial magnetic anisotropy in a Pt/Co1-xFex /Pt multilayer is tuned by doping iron atoms into the cobalt layer.The perpendicular magnetic anisotropy and out-of-plane coercivity are found to decrease with increasing x.For a specific x,the out-of-plane coercivity acquires a maximal value as a function of the thickness of the CoFe layer.At low temperature,the coercivity is enhanced.Small coercivity but reasonably large perpendicular magnetic anisotropy can be obtained by controlling the x and CoFe layer thickness. 相似文献
Cr, Nb, Cr/Nb, CrNx, NbNx, CrNbN, and (CrN/NbN)n structures were produced on Si and glass substrates, using the d.c. magnetron sputtering technique. Compositional analysis, based on binding energies of Cr, Nb, and N, was carried out by means of X-ray photoelectron spectroscopy (XPS). Through Auger electron spectroscopy (AES), depth profiles were obtained, allowing to demonstrate the multilayers production. Surface morphological characteristics, as roughness and grain size, were evaluated by atomic force microscopy (AFM), revealing very smooth surfaces, that is a consequence of the deposition parameters used in the synthetization experiments. Finally, for different configurations, conductivity measurements were carried out, revealing the influence of nitrogen content and temperature on electron transport. It was found that substoichiometric nitrides (CrN0.35 and NbN0.12) exhibited the highest conductivity, because the nitrogen atoms act as donor of electrons. 相似文献
The layer-by-layer (LbL) assembly process of creating highly structured thin films derived from layers of polyelectrolytes
and nanoparticles was adopted in this study to modify the surface of lignocellulosic fibers. Aqueous dispersions of clay nanoplatelets
were created with ultrasonication and characterized with dynamic light scattering and atomic force microscopy in which confirmed
the presence of individual clay nanoplatelets. Film thickness of never-dried clay and poly(diallyldimethylammonium chloride)
(PDDA) multilayers was studied with a quartz crystal microbalance with dissipation monitoring (QCM-D). Using identical LbL
deposition parameters, a slurry of steam-exploded wood fibers was modified by alternate adsorption of PDDA and clay with multiple
rinsing steps after each adsorption cycle. Zeta potential measurements were used to characterize the fiber surface charges
after each adsorption step while SEM images revealed that the LbL film masked the cellulose microfibril structure. Using a
thermogravimetric analyzer, LbL modified steam-exploded wood fibers were observed to attain increased thermal stability relative
to the unmodified material tested in both air and nitrogen atmospheres. Significant char for the LbL clay coated steam-exploded
wood suggests the multilayer film serves as a barrier creating an insulating layer to prevent further decomposition of the
material. This nanotechnology may have a positive impact on the processing of lignocellulosic fibers in thermoplastic matrices,
designing of paper-based overlays for building products, and modification of cellulosic fibers for textiles. 相似文献
Electrostatic multilayers of chitosan (CHI)/sodium alginate (SA) and CHI/poly(styrene sulfonate) sodium salt (PSS) were alternatively coated on electrospun cellulose acetate (CA) fiber mat. Morphologies of the composite membranes were characterized by scanning electron microscopy. The morphology of the CHI/SA-coated membrane was denser than the CHI/PSS-coated one. The top layers consisted of carboxyl and sulfonic functional groups for SA and PSS layers, respectively. Amino groups of CHI were only presented in slight quantity. X-ray photoelectron spectroscopy (XPS) confirmed the deposition of the amino groups of CHI on the multilayer membrane surface. These composite membranes were characterized for its water permeability where the water flux decreased with an increase in the number of the bilayers. The water flux was in the range of 60 and 40 L m−2 h−1 for 15 and 25 bilayered membranes, respectively. The sodium chloride (NaCl) solution flux was lower than the pure water flux due to the effect of osmotic pressure, and it decreased with an increase in the NaCl concentration. The rejection of NaCl increased substantially with the number of the bilayers of the polyelectrolytes multilayers. The level of NaCl rejection from this work was in the range of 6% and 15% for 15 and 25 bilayered membranes, respectively. 相似文献
This paper describes the formation of patterned cell co-cultures using the layer-by-layer deposition of synthetic ionic polymers and without the aid of adhesive proteins/ligands such as collagen or fibronectin. In this study, we used synthetic polymers, namely poly(diallyldimethylammonium chloride) (PDAC) and sulfonated polystyrene (SPS) as the polycation and polyanion, respectively, to build the multilayer films. We formed SPS patterns on polyelectrolyte multilayer (PEM) surfaces either by microcontact printing PDAC onto SPS surfaces or vice-versa. To create patterned co-cultures on PEMs, we capitalize on the preferential attachment and spreading of primary hepatocytes on SPS as opposed to PDAC surfaces. In contrast, fibroblasts readily attached to both PDAC and SPS surfaces, and as a result, we were able to obtain patterned co-cultures of fibroblast and primary hepatocytes on synthetic PEM surfaces. We characterized the morphology and hepatic-specific functions of the patterned cell co-cultures with microscopy and biochemical assays. Our results suggest an alternative approach to fabricating controlled co-cultures with specified cell-cell and cell-surface interactions; this approach provides flexibility in designing cell-specific surfaces for tissue engineering applications. 相似文献