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P. Sagan G. Wisz B. Tsizh I. Virt I. Rudy 《Molecular Crystals and Liquid Crystals》2018,671(1):148-155
AbstractThe structure, morphology and optical transmittance spectra of pentacene films on the (glass/ITO) surface were studied. The films were grown by two methods - the thermal vacuum deposition (TVD) and pulsed laser deposition (PLD). The electron diffraction pattern from thermally deposited pentacene films confirms their polycrystalline structure while the diffraction pattern of PLD-coated layers has a diffusion character. The results obtained showed that layers deposited by the TVD method has an optical spectrum that is characteristic for the pentacene film in contrary to the layers deposited by the PLD method. It is found a sensitivity of the optical transmittance of pentacene films to the ammonia action, which may be used for development the optical gas sensor. 相似文献
13.
We investigate the relation between the optical properties and the average molecular tilt angle for blends of pentacene and perfluoropentacene, which can be considered as a prototypical donor–acceptor complex. Combining near‐edge X‐ray absorption fine‐structure spectroscopy and optical spectroscopy we study thin films of these compounds prepared at three different substrate temperatures Tsub. For Tsub =180 K we observe a larger average tilt angle than for blends prepared at higher substrate temperatures. This orientational change has significant impact on the uniaxial anisotropic optical properties of the mixed films which we measure post growth as well as in real‐time during growth. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
14.
Dr. Wenlong Yang Dr. Jorge H. S. K. Monteiro Prof. Ana de Bettencourt-Dias Prof. Vincent J. Catalano Prof. Wesley A. Chalifoux 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(6):1441-1445
This work explores the syntheses, structures, photophysical properties, and photostability of benzodipyrenes (BDPs). BDPs were synthesized through an InCl3-AgNTf2-catalyzed, four-fold alkyne benzannulation reaction. The structures of BDP 4 a and its corresponding endoperoxide product were unambiguously confirmed by X-ray crystallography. The BDPs reported here can also be recognized as peri- and cata-benzannulated pentacenes with a non-functionalized central ring. Unlike the previous reported pentacene-based polycyclic aromatic hydrocarbons, the absorbances of the BDPs were blueshifted by ca. 40 nm relative to pentacene, even after extension of π-conjugation. The newly synthesized BDP products exhibit relatively good stability with half-lives as high as 4612 min in THF. 相似文献
15.
Alberto Piloni Roberto Simonutti Martina H. Stenzel 《Journal of polymer science. Part A, Polymer chemistry》2019,57(18):1994-2001
Fluorine‐19 (19F)‐based contrast agents are increasingly used for magnetic resonance imaging. Conjugated to polymers, they provide an excellent quantitative imaging tool to detect the movement of the polymeric nanoparticles in vivo as there is no background signal in tissue. One of the challenges is the decline in signal intensity when the conjugated hydrophobic fluorinated functionalities aggregate. Therefore, a new fluorinated monomer was prepared from l ‐arginine that carries a 2,2,2‐trifluoroethyl functional group for imaging. The resulting monomer, 2,2,2‐trifluoroethylamide l ‐arginine methacrylamide (3FArgMA), was copolymerized with poly(ethylene glycol) methyl ether methacrylate (PEGMEMA), [2‐(2,3,4,6‐tetra‐O‐acetyl‐α‐d ‐mannopyranosyloxy)ethyl methacrylate or 1‐O‐methacryloyl‐2,3:4,5‐di‐O‐isopropylidene‐β‐d ‐fructopyranose, respectively, using poly(methyl methacrylate) macro‐reversible addition–fragmentation chain transfer polymerization agent. The resulting block copolymers, which varied in 3FArgMA content, were self‐assembled into micelles of hydrodynamic diameters from 25 to 60 nm. The permanently positively charged arginine functionality on the 3FArgMA displayed repulsive forces against aggregation enabling high spin–spin relaxation times (T2) in acidic as well as alkaline solutions. However, the longer poly(ethylene glycol) side functionality in PEGMEMA enabled better steric stabilization (T2~30 ms) while the short fructose side chain was not enough to maintain high T2 values, in particular when a higher 3FArgMA content was used. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 1994–2001 相似文献
16.
Lowering the driving voltage and improving the luminance of blue fluorescent organic light-emitting devices by thermal annealing a hole injection layer of pentacene 下载免费PDF全文
We chose pentacene as a hole injection layer (HIL) to fabricate the high performance blue fluorescent organic light-emitting devices (OLEDs). We found that the carrier mobility of the pentacene thin films could be efficiently improved after a critical annealing at temperature 120 °C. Then we performed the tests of scanning electron microscopy, atomic force microscopy, and Kelvin probe to explore the effect of annealing on the pentacene films. The pentacene film exhibited a more crystalline form with better continuities and smoothness after annealing. The optimal device with 120 ℃ annealed pentacene film and n-doped electron transport layer (ETL) presents a low turn-on voltage of 2.6 V and a highest luminance of 134800 cd/m2 at 12 V, which are reduced by 26% and improved by 50% compared with those of the control device. 相似文献
17.
Characteristics of pentacene organic thin film transistor with top gate and bottom contact 下载免费PDF全文
High performance pentacene organic thin film transistors (OTFT) were
designed and fabricated using SiO2 deposited by electron beam
evaporation as gate dielectric material. Pentacene thin films were
prepared on glass substrate with S--D electrode pattern made from ITO
by means of thermal evaporation through self-organized process. The
threshold voltage VTH was --2.75± 0.1V in 0---50V
range, and that subthreshold slopes were 0.42± 0.05V/dec. The
field-effect mobility (μEF) of OTFT device increased with
the increase of VDS, but the μEF of OTFT device
increased and then decreased with increased VGS when VDS was kept constant. When VDS was --50V, on/off current
ratio was 0.48× 105 and subthreshold slope was 0.44V/dec.
The μEF was 1.10cm2/(V.s), threshold voltage
was --2.71V for the OTFT device. 相似文献
18.
本文从介质化学结构与受激布里渊散射(SBS)特性的关系入手,寻找出了SBS特性良好的全氟胺系列新介质——FC-131,FC-3283,FC-40,FC-43,FC-70等,并测定或计算出了新介质的SBS参数. 结果表明,新介质的吸收系数均小于10-3 cm-1,光学击穿阈值均高于100 GW/cm2. 全氟胺系列新介质不仅具有良好的SBS特性,而且还具有无毒、低挥发性和高稳定性等一系列独特的物理化学性质. 新介质的发现不仅增加SBS介质的种类,而且能够有效提高SBS系统的性能,对于SBS相位共轭镜在高功率激光系统中的应用打下了良好的基础.
关键词:
受激布里渊散射(SBS)
全氟胺
吸收系数
光学击穿阈值 相似文献
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