偶氮氯膦Ⅲ双波长分光光度法测定奶粉中的Fe(Ⅲ)

在酸性介质中,Fe(Ⅲ)与偶氮氯膦Ⅲ反应生成具有明显正吸收峰和负吸收峰的螯合物,最大正吸收波长位于670nm,最大负吸收波长位于530nm,用双波长叠加测定,表观摩尔吸光系数(ε)为5.93×10~4 L/(mol·cm),线性范围为0.2~2.00mg/L,探讨了适宜的反应条件、考察了准确度、精密度及选择性。该方法用于奶粉中Fe(Ⅲ)的测定,结果令人满意。     

Numerical peak points and numerical Šilov boundary for holomorphic functions

In this paper, we characterize the numerical and numerical strong-peak points for when is the complex space or . We also prove that for all is the numerical Šilov boundary for

     

基于Raman和FTIR揭示避雨栽培甜樱桃叶片光合色素变化的光谱学分析

为提高甜樱桃果实的品质和产量,中国南方地区普遍采用了避雨栽培甜樱桃果树来避免其坐果率低、落果以及果实畸形等问题,但同时也导致了其光合作用受到影响.植物或藻类中的叶绿素和类胡萝卜素等光合色素在光收集和介导对各种内源性刺激的应激反应中起着不可替代的作用.为便捷快速检测果树光合作用中叶片的光合色素变化,采用拉曼光谱(Rama...     

NUMERICAL STUDY OF LOCAL BOUNDARY LAYER RECEPTIVITY TO FREESTREAM VORTICAL DISTURBANCES

IntroductionTheproblemofhowthedisturbancesinthefreestream ,suchassoundwaveandvorticesetc .,excitethedisturbancewavesintheboundarylayeriscalledreceptivityproblem[1,2 ].Throughthiscoursetheinitialconditionsofdisturbance,suchasitsamplitude,frequency ,andphasearedetermined .ThedispersionrelationsoffreestreamdisturbancesaredifferentfromthoseofT_Swaves.Asaresult,suchdisturbancesaloneinthefreestreamdonotexciteT_Swavesinboundarylayer.But,whentheperiodicdisturbancesinboundarylayerforcedbyfreestreamdi…     

轮廓爆破孔壁压力峰值计算方法

爆破孔壁压力峰值是进行非流固耦合爆破动力响应分析的重要参数。针对轮廓爆破孔壁压力峰值的计算方法问题,理论分析了爆炸冲击波与弹性壁面的相互作用,推导了空气冲击波与弹性壁碰撞后压力增大倍数的理论解,并采用流固耦合动力有限元数值分析方法,研究了3种岩体介质、2种轮廓爆破常用炸药、5种常用不耦合系数、2种轴向装药系数工况下轮廓爆破的冲击波碰撞压力增大倍数和炮孔壁压力峰值。结果表明:轮廓爆破时,爆炸冲击波与孔壁碰撞后压力增大倍数并不是常值,与炸药特性、孔壁介质条件、不耦合装药系数等因素相关,孔壁压力峰值也与上述因素密切相关。基于模拟的孔壁压力峰值数据的统计分析,并结合理论推导成果及常用爆破孔壁压力峰值计算形式,提出了一种新的轮廓爆破孔壁压力峰值计算方法。     

自由面对爆破振动信号能量分布特征的影响

基于爆破振动实测数据, 通过小波分析方法, 得到不同数量自由面爆破振动信号的总能量、各频带的峰值质点振动速度(PPV)及各频带能量, 进而对不同数量自由面爆破振动信号的能量分布特性进行研究。结果表明：开(掏)槽爆破, 由于受单一自由面限制, 大部分炸药爆炸的能量都将作为地震能量消耗掉;自由面越多, 爆破振动信号总能量越少;自由面的数量可影响各频带振动分量分布, 随自由面数量的增加, 爆破振动能量更趋向高频分布, 中低频能量有减少趋势, 振动速度降低;同一振动信号中的高频带PPV虽比低频带PPV高, 但振动持续时间短, 能量衰减较快。建议在工程爆破的减振设计中, 优化起爆方案, 尽量利用多个自由面, 这将比仅仅减少单段起爆药量更有效。

     

Numerical simulations to improve the performance of tunable diode laser absorption tomography in a harsh combustion environment

The impact of measurement noise and tomographic methods on reconstruction quality are investigated via simulation studies under a hypothesis harsh flow field environment. Computer tomographic methods based on direct absorption spectroscopy and wavelength modulation spectroscopy are conducted under different measurement noise levels to assess the noise effect quantitatively. It turns out that the wavelength modulation spectroscopy-based tomographic method shows efficient immunity to measurement noise. However, the direct absorption spectroscopy-based tomographic method is found to be susceptible to the measurement noise, which makes the reconstruction quality decline with the increasing noise level. In addition, two kinds of tomographic methods including linear and nonlinear method are investigated under a complex multimodal temperature distribution environment with limited projection data. The reconstructed distribution for the nonlinear tomographic method reveals great fidelity to the original value with a maximum deviation of 51.9?K, while the reconstructed distribution for the linear tomographic method under parallel beam arrangement shows an obvious distortion.     

Novel HPTLC densitometric methods for determination of tamsulosin HCl and tadalafil in their newly formulated dosage form: Comparative study and green profile assessment

A promising combination of tamsulosin HCl and tadalafil has recently been introduced for treating two prevalent and associated urological disorders: benign prostate hyperplasia and erectile dysfunction. Novel HPTLC methods were designed and validated for assaying the cited drugs in their challenging combined formulation. Separation was achieved using HPTLC silica gel 60 F₂₅₄ plates as a stationary phase with a densitometric measurement at 280 nm. The proposed methods with two different chromatographic systems were successfully applied: a conventional mixture (method I) of ethyl acetate–toluene–methanol–ammonia (5:3:2:0.5, by volume) and a greener one (method II) with ethyl acetate–ethanol–ammonia (8:2:0.1, by volume). The two methods were evaluated through a comparative study in terms of selectivity, tailing factor, developing time and concentration ranges. The greenness profile for each method was then appraised with several green guides, namely GlaxoSmithKline solvent sustainability guide, Environmental, Health and Safety (EHS) tool, National Environmental Method Index (NEMI) and Eco-scale. Moreover, method specificity and peak homogeneity were evaluated by peak purity assessment using the winCATS^® software spectral correlation tool. The methods have potential for being simple, fast, economic and selective, and the greener one could be a good option for sustainable analysis of the drugs.     

自动化色谱谱图解析——谱峰的自动识别与快速解析

结合基于高阶导数的谱峰识别方法和面积重现法,建立了一种完全自动化的对色谱曲线进行分割、识别与快速解析的方法。其中,DW(Durbin-Watson)测试的引入和区分信号与噪声判据的采用减少了在色谱解析过程中的人为干预,降低了对操作人员专业知识和经验的要求,为实现色谱解析的自动化奠定了基础。通过对模拟色谱和实验色谱的比较,验证了该方法是一个很有用的工具,可以为色谱分析工作提供有力的帮助。