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31.
Gordon G. Brown 《Journal of Molecular Spectroscopy》2006,238(2):200-212
The rotational spectrum of epifluorohydrin measured by chirped-pulse Fourier transform microwave (CP-FTMW) spectroscopy is presented. A new CP-FTMW spectrometer capable of measuring the entire 7.5-18.5 GHz spectrum with a single polarizing pulse is described briefly. The CP-FTMW spectrometer takes advantage of recent advances in digital electronics by utilizing a 4.2 GS/s arbitrary waveform generator as a frequency source and a 12 GHz digital oscilloscope to digitize the down converted molecular free induction decay (FID). Signal averaging in the time domain is used to increase the signal-to-noise ratio. The rotational constants of three unique conformers of epifluorohydrin were measured, as well as the rotational constants of the three unique 13C isotopomers and the 18O isotopomer (in natural abundance) of the most stable conformer. The rotational constants of the two less stable conformers differ significantly from those previously reported [F.G. Fujiwara, J.L. Painter, H. Kim, J. Mol. Struct. 41 (1977) 169-175]. Ab initio calculations were performed for all three conformations and are compared to experimental values. 相似文献
32.
We derive the waiting time distribution of the lowest class in an accumulating priority (AP) queue with positive Lévy input. The priority of an infinitesimal customer (particle) is a function of their class and waiting time in the system, and the particles with the highest AP are the next to be processed. To this end we introduce a new method that relies on the construction of a workload overtaking process and solving a first-passage problem using an appropriate stopping time. 相似文献
33.
Let t be a continuous Markov chain on N states. Consider adjoining a Brownian motion with this Markov chain so that the drift and the variance take different values when t is in different states. This new process Zt is a hidden Markov process. We study the probability distribution of the first passage time for Zt.Our result, when applied to the stock market, provides an explicit mathematical interpretation of the fact that in finite time, there is positive probability for the bull (bear) market to become bear (bull). 相似文献
34.
P. C. Allaart 《Acta Mathematica Hungarica》2008,121(3):243-275
This paper concerns the maximum value and the set of maximum points of a random version of Takagi’s continuous, nowhere differentiable
function. Let F(x):=∑
n=1∞
ε
n
ϕ(2
n−1
x), x ∈ R, where ɛ
1, ɛ
2, ... are independent, identically distributed random variables taking values in {−1, 1}, and ϕ is the “tent map” defined by ϕ(x) = 2 dist (x, Z). Let p:= P (ɛ
1 = 1), M:= max {F(x): x ∈ R}, and := {x ∈ [0, 1): F(x) = M}. An explicit expression for M is given in terms of the sequence {ɛ
n
}, and it is shown that the probability distribution μ of M is purely atomic if p < , and is singular continuous if p ≧ . In the latter case, the Hausdorff dimension and the multifractal spectrum of μ are determined. It is shown further that the set is finite almost surely if p < , and is topologically equivalent to a Cantor set almost surely if p ≧ . The distribution of the cardinality of is determined in the first case, and the almost-sure Hausdorff dimension of is shown to be (2p − 1)/2p in the second case. The distribution of the leftmost point of is also given. Finally, some of the results are extended to the more general functions Σa
n − 1
ɛ
n
ϕ(2
n − 1
x), where 0 < a < 1.
相似文献
35.
This paper introduces a blocking model and closed-form expression of two workers traveling with walk speed m (m = integer) in a no-passing circular-passage system of n stations and assuming n = m + 2, 2m + 2, …. We develop a Discrete-Timed Markov Chain (DTMC) model to capture the workers’ changes of walk, pick, and blocked states, and quantify the throughput loss from blocking congestion by deriving a steady state probability in a closed-form expression. We validate the model with a simulation study. Additional simulation comparisons show that the proposed throughput model gives a good approximation of a general-sized system of n stations (i.e., n > 2), a practical walk speed system of real number m (i.e., m ? 1), and a bucket brigade order picking application. 相似文献
36.
A Bose 《Journal of multivariate analysis》1983,13(3):442-463
We consider the problem of constructing entrance laws for Feller diffusions on the state space (0, ∞). Our method, based on Feller-McKean theory of one-dimensional diffusions, gives an analytic expression for the entrance density in terms of transition density. Moreover, the entrance density is the density of the first passage time to the left boundary {0}. Also, the entrance density is related to the transition density via Doob's h-path transformation. 相似文献
37.
工程施工中运输网络优化方案 总被引:5,自引:0,他引:5
施工工地运输方案的优化设计可以归结为 :按施工期要求设计运输线路或验证已有线路通行能力 ,计算总线路中影响提高流量的关键路段 ,取得最小费用最大流 .本文运用图论理论这一数学工具把实际问题抽象为有向网络 ,进而建立数学模型 .此方法理论上严密 ,解题步聚直观清晰 ,对水利、公路、水路、铁路等其它运输系统有普遍意义 . 相似文献
38.
For continuous time birth-death processes on {0,1,2,…}, the first passage time T+n from n to n + 1 is always a mixture of (n + 1) independent exponential random variables. Furthermore, the first passage time T0,n+1 from 0 to (n + 1) is always a sum of (n + 1) independent exponential random variables. The discrete time analogue, however, does not necessarily hold in spite of structural similarities. In this paper, some necessary and sufficient conditions are established under which T+n and T0,n+1 for discrete time birth-death chains become a mixture and a sum, respectively, of (n + 1) independent geometric random variables on {1,2,…};. The results are further extended to conditional first passage times. 相似文献
39.
We investigate the mean first passage time of an active Brownian particle in one dimension using numerical simulations. The activity in one dimension is modelled as a two state model; the particle moves with a constant propulsion strength but its orientation switches from one state to other as in a random telegraphic process. We study the influence of a finite resetting rate r on the mean first passage time to a fixed target of a single free active Brownian particle and map this result using an effective diffusion process. As in the case of a passive Brownian particle, we can find an optimal resetting rate r* for an active Brownian particle for which the target is found with the minimum average time. In the case of the presence of an external potential, we find good agreement between the theory and numerical simulations using an effective potential approach. 相似文献
40.
《Macromolecular bioscience》2017,17(12)
Chondrocytes are important for cartilage tissue engineering. However, dedifferentiation during chondrocyte subculture prevents the application of cartilage tissue engineering. Therefore, prevention of this dedifferentiation is required. Here, the possibility of poly(2‐methoxyethyl acrylate) (PMEA) and its analogous polymers, poly(tetrahydrofurfuryl acrylate) (PTHFA) and poly(2‐(2‐methoxyethoxy) ethyl acrylate‐co‐butyl acrylate) (PMe2A), for chondrocyte subculture without dedifferentiation is examined. Chondrocytes spread on PTHFA and polyethylene terephthalate (PET), whereas their spreading is delayed on PMEA and PMe2A. When primary chondrocytes are subcultured on these polymers, the expression levels of cartilaginous genes are higher on PMEA and PMe2A than on PET and PTHFA. Integrin contribution to the initial cell adhesion is lower on PMEA and PMe2A than on PTHFA and PET. This low level of integrin contribution to cell adhesion may cause a delay in cell spreading and the maintenance of cartilaginous gene expression. These results indicate that PMEA and PMe2A may be favorable substrates for chondrocyte subculture and cartilage tissue engineering. 相似文献