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31.
The microscopic mechanism of nine experimentally observed bands in ^178W is investigated using the particle-number conserving method of the cranked shell model with monopole and quadrupole paring interactions. The experimental results, including the moments of inertia and angular momentum alignments of nine bands in ^178W, are reproduced well by the particle-number conserving calculations, in which no free parameter is involved. Calculations demonstrate that occurrence of sharp backbending comes mainly from the contribution of high-j intruder orbitals vi13/2 or πh11/2 and their interference effect with orbitals near the Fermi surface. Theω variation of the occupation probability of each cranked orbital and the contribution to moment of inertia from each cranked orbital are analyzed.  相似文献   
32.
在基于身份的密钥提取过程中,使密钥生成器在私钥中嵌入随机数,从而使得密钥提取具有较好的灵活性,使得用户对一个身份可具备多个私钥,这无疑会增加密钥使用的安全性;基于这种新的密钥提取思路,给出一个基于身份的签名体制,新的密钥提取方式使得它具有更好的安全性和灵活性;新的基于身份的签名体制中具有最少对运算,因此,与类似的方案相比,其具备较好的计算效率;新签名体制的安全性依赖于k-合谋攻击问题(k-CAAP)的困难性,其在适应性选择消息和ID攻击下具备强不可伪造性,并且其安全性证明具有紧规约性.  相似文献   
33.
For pairing based cryptography we need elliptic curves defined over finite fields whose group order is divisible by some prime with where k is relatively small. In Barreto et al. and Dupont et al. [Proceedings of the Third Workshop on Security in Communication Networks (SCN 2002), LNCS, 2576, 2003; Building curves with arbitrary small Mov degree over finite fields, Preprint, 2002], algorithms for the construction of ordinary elliptic curves over prime fields with arbitrary embedding degree k are given. Unfortunately, p is of size .We give a method to generate ordinary elliptic curves over prime fields with p significantly less than which also works for arbitrary k. For a fixed embedding degree k, the new algorithm yields curves with where or depending on k. For special values of k even better results are obtained.We present several examples. In particular, we found some curves where is a prime of small Hamming weight resp. with a small addition chain.AMS classification: 14H52, 14G50  相似文献   
34.
We concisely and directly prove that the interpolation Macdonald polynomials are orthogonal with respect to the Fourier pairing and briefly discuss immediate applications of this fact, in particular, to the symmetry of the Fourier pairing and to the binomial formula.  相似文献   
35.
We use surrogate analysis and constraint pairing in multidimensional knapsack problems to fix some variables to zero and to separate the rest into two groups – those that tend to be zero and those that tend to be one, in an optimal integer solution. Using an initial feasible integer solution, we generate logic cuts based on our analysis before solving the problem with branch and bound. Computational testing, including the set of problems in the OR-library and our own set of difficult problems, shows our approach helps to solve difficult problems in a reasonable amount of time and, in most cases, with a fewer number of nodes in the search tree than leading commercial software.  相似文献   
36.
为减少城市交通拥挤,从交通量均分的角度出发,提出了综合反映道路网络局部和整体性质的k最优定向,并且利用奇度点配对的思想为定向问题设计了启发式算法。  相似文献   
37.
    
Abstract

A liquid chromatographic chiral stationary phase (CSP) was prepared starting from (1S, 2S)-1,2-diaminocyclohexane. The CSP containing two simple functional groups, such as a primary amino group and an ureide tethering linkage on a cyclohexane ring, was quite successful with the use of 60% 2-propanol in hexane containing 0.5% acetic acid as a mobile phase for the resolution of various N-(3,5-dinitrobenzoyl)-α-amino acids, the separation (α) and the resolution factors (R S ) being in the range of 1.12–1.23 and 1.33–2.99, respectively. In contrast, N-(3,5-dinitrobenzoyl)-α-amino acid ethyl esters and N-(3,5-dinitrobenzoyl)-α-amino acid amides were not resolved at all, or resolved very poorly on the CSP. From these results, it was concluded that the ionic or ion-paring interaction between the CSP and analytes plays a very important role for the chiral recognition. The chromatographic behaviors for the resolution of N-(3,5-dinitrobenzoyl)-α-amino acids on the CSP were found to be controlled with the variation of the type and the content of alcohol and/or acid in hexane.  相似文献   
38.
    
(Thio)-urea-containing bifunctional quaternary ammonium salts emerged as powerful non-covalently interacting organocatalysts over the course of the last decade. The most commonly employed catalysts in this field are either based on Cinchona alkaloids, α-amino acids, or trans-cyclohexane-1,2-diamine. Our group has been heavily engaged in the design and use of such catalysts, i. e. trans-cyclohexane-1,2-diamine-based ones for around 10 years now, and it is therefore the intention of this short personal account to provide an overview of the, at least in our opinion, most significant and pioneering achievements in this field by looking on catalyst design and asymmetric method development, with a special focus on our own contributions.  相似文献   
39.
    
A better understanding of the solution chemistry of the lanthanide (Ln) salts in water would have wide ranging implications in materials processing, waste management, element tracing, medicine and many more fields. This is particularly true for minerals processing, given governmental concerns about lanthanide security of supply and the drive to identify environmentally sustainable processing routes. Despite much effort, even in simple systems, the mechanisms and thermodynamics of LnIII association with small anions remain unclear. In the present study, molecular dynamics (MD), using a newly developed force field, provide new insights into LnCl3(aq) solutions. The force field accurately reproduces the structure and dynamics of Nd3+, Gd3+ and Er3+ in water when compared to calculations using density functional theory (DFT). Adaptive-bias MD simulations show that the mechanisms for ion pairing change from dissociative to associative exchange depending upon cation size. Thermodynamics of association reveal that whereas ion pairing is favourable, the equilibrium distribution of species at low concentration is dominated by weakly bound solvent-shared and solvent-separated ion pairs, rather than contact ion pairs, reconciling a number of contrasting observations of LnIII–Cl association in the literature. In addition, we show that the thermodynamic stabilities of a range of inner sphere and outer sphere coordination complexes are comparable and that the kinetics of anion binding to cations may control solution speciation distributions beyond ion pairs. The techniques adopted in this work provide a framework with which to investigate more complex solution chemistries of cations in water.  相似文献   
40.
    
Various estimates of the even-odd effect of the mass shell of atomic nuclei are considered.Based on the experimental mass values of the Ca,Sn,and Pb isotopes,the dependence of the energy gap on the neutron number is traced and the relationship of this characteristic to the properties of external neutron subshells is shown.In nuclei with closed proton shells,effects directly related to neutron pairing and effects of nucleon shells are discussed.  相似文献   
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