全文获取类型
收费全文 | 7430篇 |
免费 | 1445篇 |
国内免费 | 701篇 |
专业分类
化学 | 2293篇 |
晶体学 | 43篇 |
力学 | 253篇 |
综合类 | 41篇 |
数学 | 974篇 |
物理学 | 5972篇 |
出版年
2024年 | 19篇 |
2023年 | 79篇 |
2022年 | 137篇 |
2021年 | 167篇 |
2020年 | 228篇 |
2019年 | 210篇 |
2018年 | 195篇 |
2017年 | 201篇 |
2016年 | 268篇 |
2015年 | 253篇 |
2014年 | 332篇 |
2013年 | 564篇 |
2012年 | 413篇 |
2011年 | 487篇 |
2010年 | 396篇 |
2009年 | 473篇 |
2008年 | 540篇 |
2007年 | 559篇 |
2006年 | 477篇 |
2005年 | 388篇 |
2004年 | 341篇 |
2003年 | 377篇 |
2002年 | 356篇 |
2001年 | 298篇 |
2000年 | 306篇 |
1999年 | 242篇 |
1998年 | 210篇 |
1997年 | 143篇 |
1996年 | 100篇 |
1995年 | 101篇 |
1994年 | 69篇 |
1993年 | 87篇 |
1992年 | 59篇 |
1991年 | 46篇 |
1990年 | 55篇 |
1989年 | 45篇 |
1988年 | 39篇 |
1987年 | 34篇 |
1986年 | 35篇 |
1985年 | 31篇 |
1984年 | 29篇 |
1983年 | 13篇 |
1982年 | 19篇 |
1981年 | 26篇 |
1980年 | 26篇 |
1979年 | 16篇 |
1978年 | 18篇 |
1977年 | 18篇 |
1976年 | 13篇 |
1974年 | 11篇 |
排序方式: 共有9576条查询结果,搜索用时 0 毫秒
61.
We consider quantum unbounded spin systems (lattice boson systems) in -dimensional lattice space Z. Under appropriate conditions on the interactions we prove that in a region of high temperatures the Gibbs state is unique, is translationally invariant, and has clustering properties. The main methods we use are the Wiener integral representation, the cluster expansions for zero boundary conditions and for general Gibbs state, and explicitly -dependent probability estimates. For one-dimensional systems we show the uniqueness of Gibbs states for any value of temperature by using the method of perturbed states. We also consider classical unbounded spin systems. We derive necessary estimates so that all of the results for the quantum systems hold for the classical systems by straightforward applications of the methods used in the quantum case. 相似文献
62.
We consider the Hopfield model withM(N)=N patterns, whereN is the number of neurons. We show that if is sufficiently small and the temperature sufficiently low, then there exist disjoint Gibbs states for each of the stored patterns, almost surely with respect to the distribution of the random patterns. This solves a provlem left open in previous work. The key new ingredient is a self-averaging result on the free energy functional. This result has considerable additional interest and some consequences are discussed. A similar result for the free energy of the Sherrington-Kirkpatrick model is also given. 相似文献
63.
No modern theory of polymer excluded volume adequately describes the crossover from poor solvent to good solvent conditions; a fundamental difficulty is a singularity in the binary cluster integral. Mayer expansion techniques are applied to a model with a pair interaction between monomers to clarify the distinction between geometric and solvent contributions to excluded volume. Detailed calculations are undertaken for a hard-core potential and a mimic Lennard-Jones potential. The significance of the singularity in the binary cluster integral for calculations in the crossover regime is discussed. 相似文献
64.
A. G. Schlijper 《Journal of statistical physics》1985,40(1-2):1-27
A new derivation is presented of some variational approximations for classical lattice systems that belong to the class of cluster-variation methods, among them the well-known Bethe-Peierls and Kramers-Wannier approximations. The limiting behavior of a hierarchical sequence of cluster-variation approximations, the so-calledC hierarchy, is discussed. It is shown that this hierarchy provides a monotonically decreasing sequence of upper boundsf
n on the free energy per lattice sitef and thatf
n f asn . Our results are based on extension theorems for states given on subsets of the lattice, which might be of some independent interest, and on an application of transfer matrix concepts to the variational characterization of translation-invariant equilibrium states. 相似文献
65.
Zeev Elkoshi Howard Reiss Audrey Dell Hammerich 《Journal of statistical physics》1985,41(3-4):685-708
A hole in a fluid is specified in a well-defined manner. The concentration of holes is a thermodynamic property of the fluid and we derive this concentration in three different ensembles for a one-dimensional fluid of hard rods. The thermodynamics of these rigorously defined holes is developed, and the properties of holes are explored. The ensemble in which the concentration of holes is maintained fixed exhibits dramatic properties. Finally, pair correlation functions for hard rods in the various ensembles are computed. Contrary to a frequently made assumption, the equilibrium number of holes is found to never be proportional to the probability of finding a single hole in the fluid. Constraining the concentration of holes as well as the density leads to dramatic structural effects prominently displayed by the pair correlation function. The ensemble in which the concentration of holes is fixed is an example of an internally constrained metastable system. 相似文献
66.
Peter D. Dacre 《Theoretical chemistry accounts》1976,43(2):197-205
The direct CI method, which avoids explicit calculation of the Hamiltonian matrix, is presented in a new form. The method is linked with Davidson's algorithm for iterative evaluation of the ground state eigenvector. The viability of the method is indicated by the test calculations on water which are described. 相似文献
67.
Cabaleiro-Lago EM Rodríguez-Otero J García-López RM Peña-Gallego A Hermida-Ramón JM 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(20):5966-5974
A comprehensive B3LYP/6-31+G* study on the electrocyclization of 1,2,4,6-heptatetraene analogues was conducted. Starting from the cyclization of (2Z)-2,4,5-hexatrienal, a pericyclic disrotatory process favored by the assistance of a electron lone pair, we incorporated small modifications in its molecular structure to obtain a truly pseudopericyclic process. To this purpose electronegative atoms (fluorine and nitrogen) were added to give a more electrophilic character on the carbon atom which is attacked by the electron lone pair of the oxygen atom. The complete pathway for each reaction was determined, and changes in magnetic properties were monitored with a view to estimating the aromatization associated with each process. This information, together with the energetic and structural results, allowed us to classify the reactions as pseudopericyclic or pericyclic. Among all studied reactions only one was a truly pseudopericyclic process and another was a borderline case. The features of this unequivocally pseudopericyclic case were analyzed in depth. 相似文献
68.
Hiltrud Breitenfelder-Manske Friedrich Kohler 《Monatshefte für Chemie / Chemical Monthly》1985,116(11):1247-1261
The second virial coefficients of homonuclear three-centerLennard-Jones molecules are calculated with various parameters of the isosceles triangle connecting the three sites. A special effort is made to establish the reducedBoyle temperaturesT
B and the values of the second virial coefficients atT/T
B=0.3 for the sake of comparison with one- and two-centerLennard-Jones molecules. It is shown that it is possible to find parameter values of the interaction potential of one- and two-centerLennard-Jones molecules which give very similar values of second virial coefficients forT/T
B0.3, and the equivalence conditions are established. These conditions might not only give a basis for a microscopic scaling of state variables, but also some restrictions for the validity of the group contribution concept.Presented in part at the DFG-Colloquium at Paderborn, 19th April 1982, and at the 5th Conference on Mixtures of Nonelectrolytes and Intermolecular Interactions, April 18–22, 1983, at Halle (GDR). 相似文献
69.
Emission and absorption polarization spectra as well as emission lifetimes between room temperature and 5 °K have been measured of [Cr urea6]X3 single crystals, where X stands for ClO
4
–
, J–, NO
3
–
, Br–, Cl–, F–, and X3 for JSO
4
3–
. The strong temperature dependence of the fluorescence/phosphorescence-ratios, and of the emission lifetimes is discussed. The differences between the spectra as well as the emission lifetimes of the various salts can be attributed to an anion dependent trigonal perturbation.
Die Autoren danken dem Verband der Chemischen Industrie für finanzielle Unterstützung dieser Arbeit. 相似文献
70.
Recognition of sheared and normal DNA by a novel metal complex [Co(phen)2hpip]3+ (phen=1,10-phenanthroline, HPIP=2-(2-hydroxyphenyl)imidazole[4,5-f][1,10]phenanethroline) is studied by molecular modeling. Calculating results indicate that, this complex can specifically recognize DNA segment of sequence –MMNNMM– (M means mismatch base pairs and N means normal base pairs). Intercalating from minor groove between the middle normal duplex into the sheared DNA with the depth of 1.2 nm is of preference and enantioselectivity is observed. Comparison on the two DNA structures of optimal conformation and analysis on the interaction between DNA and the two tail ligands of the complex show that, the effect of the two neighboring mismatch duplexes on the structure of the middle normal base pairs and the steric interaction between the mismatch duplexes and the two tail ligands of the complex are the essential reason to the segment specificity. Investigation on the detailed energy terms indicate that, in effecting enantioselectivity, the electrostatic distribution of the complex is in the majority and steric interaction is at the next place. But, steric interaction is surely the only factor determining the intercalating from minor groove. 相似文献