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91.
In the work the focus is on the preparation of self-assembled monolayer-like films consisting of thiolated cyclodextrin on gold substrate and a characterization by using secondary ion mass spectrometry. The short (1 min) and long (1 h) time preparations of self-assembled monolayer-like films, resulting in submonolayer and monolayer regimes, are investigated, respectively. The observed species of thiolated cyclodextrin (M as molecular ion) self-assembled monolayer-like films are assigned to three groups: AuxHySz clusters, fragments with origin in cyclodextrin molecule associated with Au, and molecular ions. The group of AuxHySz (x = 2-17, y = 0-2, z = 1-5) clusters have higher intensities than other species in the positive and even more in negative mass spectra. Interestingly, the dependence between the number of Au and S atoms shows that with the increasing size of AuxHySz clusters up to 11 Au atoms, the number of associated S atoms is also increasing and then decreasing. Molecular species as (M−S+H)Na+, (M+H)Na+, AuMNa+, (M2−S)Na+, and M2Na+ are determined, and also in cationized forms with K+. The intensities of thiolated cyclodextrin fragments at the long time preparation are approximately 10 times higher than the intensities of the same fragments observed at the short time. The largest observed ions in thiolated cyclodextrin self-assembled monolayer-like films are AuM2 and Au2M. The thiolated cyclodextrin molecular ions are compared with hexadecanethiol molecular ions in the form of AuxMw where the values of x and w are smaller for thiolated cyclodextrin than for hexadecanethiol. This result is supported with larger, more compact, and more stabile thiolated cyclodextrin molecule. 相似文献
92.
Fuxue WangHai Lu Xiangqian XiuDunjun Chen Ping HanRong Zhang Youdou Zheng 《Applied Surface Science》2011,257(9):3948-3951
The effect of oxygen plasma treatment on the performance of GaN Schottky barrier diodes is studied. The GaN surface is intentionally exposed to oxygen plasma generated in an inductively coupled plasma etching system before Schottky metal deposition. The reverse leakage current of the treated diodes is suppressed in low bias range with enhanced diode ideality factor and series resistance. However, in high bias range the treated diodes exhibit higher reverse leakage current and corresponding lower breakdown voltage. The X-ray photoelectron spectroscopy analysis reveals the growth of a thin GaOx layer on GaN surface during oxygen plasma treatment. Under sub-bandgap light illumination, the plasma-treated diodes show larger photovoltaic response compared with that of untreated diodes, suggesting that additional defect states at GaN surface are induced by the oxygen plasma treatment. 相似文献
93.
ZnO:Fe array thin films were prepared by the hydrothermal method using the sol-gel grown film as a seed layer. The samples were characterized by X-ray diffraction (XRD), ultraviolet/visible absorption spectra (UV-vis) and scanning electron microscopy (SEM). The photocatalytic activities of the prepared samples were investigated for the photodegradation of methylene blue (MB) under sunlight irradiation. The results show that the lattice constant a and the cell volume of ZnO:Fe film increase due to the substitution of Fe for Zn. The absorption edge of Fe-doped ZnO displays a red shift with a significant absorption between 600 and 700 nm. The ZnO:Fe array film is composed of disk particles with uniformity and compactness. Doping Fe ions enhances the photodegradation rate of ZnO array film for MB. 1.5% Fe doped ZnO sample exhibits the highest activity under irradiation time of 4 h. Its degradation rate increases about 1.6 times compared to the undoped ZnO. 相似文献
94.
95.
采用APPLEⅡ微机控制9W测微光密度计,实现对谱板自动化测量。论述了该系统的工作原理、主要功能和特性。给出了使用该系统所测得的实际光谱谱图。 相似文献
96.
Anisotropic (elliptically polarized) photoinduced second harmonic generation (PISHG) in SiNxOy/Si1 1 1 films was proposed for contact-less monitoring of specimens with different nitrogen to oxygen (N/O) ratios. As a source for the photoinducing light, we used a nitrogen Q-switched pulse laser at wavelengths of 315, 337 and 354 nm as well as doubled frequency YAG–Nd laser wavelength (λ=530 nm). The YAG : Nd pulse laser (λ=1.06 μm; W=30 MW; τ=10–50 ps) was used to measure the PISHG. All measurements were done in a reflected light regime. We found that the output PISHG signal was sensitive to the N/O ratio and the film thickness. Measurements of the PISHG versus pumping wavelengths, powers, incident angles as well as independent measurements of the DC-electric field induced second harmonic generation indicate the major role played in this process by axially symmetric photoexcited electron–phonon states. The SiNxOy films were synthesized using a technique of chemical evaporation at low pressures. Films with thickness varying between 10 and 30 nm and with an N/O ratio between 0 and 1 were obtained. Electrostatic potential distribution at the Si1 1 1–SiNxOy interfaces was calculated. Comparison of the experimentally obtained and quantum chemically calculated PISHG data are presented. High sensitivity of anisotropic PISHG to the N/O ratio and film thickness is revealed. The role of the electron–phonon interactions in the dependencies observed is discussed. We have shown that the PISHG method has higher sensitivity than the traditional extended X-ray absorption fine structure spectroscopic and linear optical method for films with the N/O ratio higher than 0.50. 相似文献
97.
98.
Direct Monitoring of Thickness and Refractive Index of Optical Thin Film Deposited on Fiber End-face
We propose a system for depositing thin films on waveguides which enables low-temperature deposition and precise control of the refractive index and film thickness. It is composed of a conventional ion-beam sputtering (IBS) system and a new system for directly monitoring film characteristics during deposition. We controlled refractive indices over a wide range from 1.52 to 1.97 by moving the sputtering targets (SiO2 and Si3N4) in the IBS system. The refractive index or film thickness was in-situ monitored by observing the optical power reflected from the end-face of a monitoring fiber set in the deposition chamber. Antireflection coating films were successfully deposited on a fiber end-face and a laser diode chip facet with low reflectivity from 0.05 to 0.07%. This deposition system is attractive for constructing highly functional optical devices for future photonic networks. 相似文献
99.
Katsuhiro Munakata Kenji Harada Nobukazu Yoshikawa Masahide Itoh Shinsuke Umegaki Toyohiko Yatagai 《Optical Review》1999,6(6):518-521
Two fabrication methods of surface relief electro-optic (EO) gratings in azo-polymer films are described: surface deformation by a continuous wave laser and laser ablation by a pulse laser. In the fabrication process, the periodic intensity modulation of laser beams is formed by an interference fringe or a phase mask. The surface relief EO grating is fabricated by poling the surface relief grating (SRG) after the SRG fabrication process. The linear dependence of an applied voltage in the modulation efficiency of the first-order diffraction beam is observed. The proposed methods are effective for highly-efficient surface relief EO grating fabrication. 相似文献
100.
The distinctive features of the atomic and electronic structure of thin surface layers of substances in the process of formation
of epitaxial silicon films on silicon are studied using the procedures of reflection and scattering of ultrasoft x-ray radiation.
The angular distribution of the scattered x-ray radiation (the scattering indicatrices) and the near fine structure of SiL2,3 spectra of reflection are investigated. The assumption of the sensitivity of the observed peak of anomalous scattering (the
Yoneda peak) of x-ray radiation to the presence, in the surface regions of the materials, of extended double-boundary defects,
the defects of packing, grain boundaries, dislocations, etc. is made. It is shown that the experimental procedure used makes
it possible to obtain information on the surface layers of substances.
Translated from Zhurnal Priklaldnoi Spektroskopii, Vol. 67, No. 4, pp. 496–498, July–August, 2000. 相似文献