Naphthalimide‐Based Triptycenes: Synthesis and Optoelectronic Properties

In the past decades, the naphthalimide structure has found application in many areas of chemistry due to its unique photophysical properties. Naphthalimide has two isomers, 1,8‐naphthalimide containing a six‐membered imide ring and 2,3‐naphthalimide containing a five‐membered imide ring. The former has been widely investigated while studies on the latter are considerably more rare. On the other hand, naphthalimide can also be regarded as a building block to construct polycyclic aromatic hydrocarbons (PAHs), which have found wide applications in optical materials. Here we report the synthesis and optoelectronic properties of three 2,3‐naphthalimide‐based triptycenes. These three triptycene derivatives enrich the family of triptycenes.     

Polymerization of branched thiophene monomers and optoelectronic properties of materials

Bithiophene monomers ( 5HBTh and 5HBThO ) were prepared by the Suzuki coupling reaction of 3‐thienylboronic acid with 2‐bromo‐5‐hexylthiophene and 2‐bromo‐5‐hexylthiophene‐1,1‐dioxide. The oxidation polymerization mediated by vanadium catalyst gave poly(5HBTh) and oligo(5HBThO) . 5HBThO bearing thiophene‐1,1‐dioxide had an absorption maximum at longer wavelength region than 5HBTh due to the intramolecular charge transfer interaction, while peak maxima blue shifted and their difference became small after the polymerization. Terthiophene monomers ( 5″HTTh , 3,5″DHTTh , and 4,5″DHTTh ) were subsequently prepared by the mono‐bromination of 5HBTh followed by the Suzuki coupling reaction with boronic acid derivatives. The vanadium‐catalyzed oxidation polymerization of 5″HTTh and 4,5″DHTTh afforded soluble polymers and the absorption maximum wavelengths red shifted after the polymerization in contrast to bithiophene monomers and 3,5″DHTTh . The absorption and emission spectra of poly(5″DHTTh) red shifted when compared with those of poly(4,5″DHTTh) . Thus the presence and position of n‐hexyl chain influenced the monomer polymerizability and optoelectronic properties of branched polythiophenes. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 3034–3044, 2009     

光电子物理及应用前沿问题——介绍全国首届光电子物理及应用前沿问题研讨会

综述了全国首届光电子物理及应用前沿问题研讨会有关情况，讨论了若干光电子物理及其在高技术应用领域的前沿科学技术问题，从物质运动形态转化的角度探讨了当前主要的光电子材料、器件和相关的物理基础研究     

基于异质结构的PD24红外光电探测器件特性研究

针对大气污染物氮氧化物化学发光光谱特征情况对探测器的要求，使用红外分光光度法对PD24系列红外探测器件的光电特性，如光谱响应度、频响、响应度等参数进行了分析研究。比较了光电倍增管与PD24系列器件的性能情况。介绍了扩大器件接收面的透射、反射、聚光方案。实验表明，异质结光电二极管PD24-05是一种具有高速、高灵敏度、宽带宽等优良性能的红外光电探测器件；其光谱响应范围与氮氧化物化学发光光谱的匹配情况良好。     

Synthesis and Physical Properties of Benzopyridazine-Based Conjugated Molecules

A series of novel organic conjugated molecules （5a--5d） comprising 2,3-benzopyridiazine as electron-with- drawing core and thiophene derivatives as electron-donating arms have been synthesized successfully in good yields. The ultraviolet-visible （UV-Vis） absorption spectra and fluorescence spectra of 5a--5d revealed that the optical properties are strongly influenced by the interactions between nitrogen and sulfur atoms in the conjugated backbone, as well as the position of the alkyl chains in the thiophene rings. The experimental results and theoretical calculation data clearly indicated that the band gap and the energy levels of LUMO and HOMO could be fine-tuned by the po- sition of alkyl chains in the thiophene rings. Thus, the structure-property correlation of this class of conjugated molecules can be well established.     

Design,synthesis, and characterization of a novel c‐donor‐nc‐bridge‐c‐acceptor type block copolymer for optoelectronic applications

A novel conjugated block copolymer system containing a donor‐type conjugated block (c‐D) covalently connected to an acceptor type conjugated block (c‐A) via a nonconjugated and flexible bridge chain (nc‐B), also called a DBA type block copolymer, has been designed, synthesized, and characterized for potential cost‐effective and high‐efficiency optoelectronic applications such as solar cells. Specifically, D is a regio‐regular para‐2‐ethylhexyloxy‐substituted polyphenylenevinylene (or EH‐RO‐PPV), A is a regio‐regular polyphenylenevinylene with sulfone (SO₂) acceptor moiety and a linear oxydecane (‐OC₁₀H₂₁) group substituted on every phenylene unit, and B contains an aliphatic chain with two or four methylene units. The size of each block can be controlled via synthetic feed ratio of the monomer and the terminator. The measured average molecular weights of D, A, and DBA based on gel permission chromatography are in good agreements with the molecular weights calculated using the monomer:terminator synthetic feed ratios. Preliminary optoelectronic device studies revealed an order of magnitude better improvement in photoelectric power conversion efficiency of DBA over the corresponding D/A blend under identical fabrication and testing conditions. Such improvements could be attributed to more efficient photo induced charge separation and charge transport in DBA versus in D/A blends. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1149–1160     

亚纳秒光脉冲下GaAs光电开关行为的理论分析

本文对GaAs光电开关在亚纳秒光脉冲(650ps左右)触发下的性能作了理论分析。用计算机数值分析方法计算了光电开关的电导随光脉冲的变化过程,分析了光脉冲的能量、半宽度的涨落引起的光电开关的触发跳动、响应时间及幅度的变化规律。在合理选用参数时,用SPICE设计得到了上升沿为5kV/ns,触发跳动小于5ps的斜坡电压,从而证实了光电开关在亚纳秒光脉冲作用下的可行性。     

声速测量中反射端相位问题的讨论

本文在用共振干涉法测定空气中的声速实验里，就反射端的相位问题从理论上作了较深刻的讨论。     

超快光电测量技术

本文综述了近年来趔快光电测量技术的新进展,其中包括扭快光电材料的特性、高速光电器件的基本原理,着重介绍了若干主要的用快光电测量技术．     

最大平均相关高度滤波算法在畸变目标识别中的应用

为了解决在联合变换相关器上无法识别复杂背景下畸变目标(目标的平面内旋转或尺寸改变)的问题,对其应用最大平均相关高度滤波算法进行畸变目标识别.首先在频域内优化最大平均相关高度滤波器的三个性能控制参量;然后将优化好的最大平均相关高度频域滤波器映射到物空问,得到最大平均相关高度参考模板,作为实例,本文对复杂背景下的军舰和汽车...