Chain‐growth condensation polymerization of 4‐aminobenzoic acid esters bearing tri(ethylene glycol) side chain with lithium amide base

Chain‐growth condensation polymerization of p‐aminobenzoic acid esters 1 bearing a tri(ethylene glycol) monomethyl ether side chain on the nitrogen atom was investigated by using lithium 1,1,1,3,3,3‐hexamethyldisilazide (LiHMDS) as a base. The methyl ester monomer 1a afforded polymer with low molecular weight and a broad molecular weight distribution, whereas the polymerization of the phenyl ester monomer 1b at ?20 °C yielded polymer with controlled molecular weight (M_n = 2800–13,400) and low polydispersity (M_w/M_n = 1.10–1.15). Block copolymerization of 1b and 4‐(octylamino)benzoic acid methyl ester ( 2 ) was further investigated. We found that block copolymer of poly 1b and poly 2 with defined molecular weight and low polydispersity was obtained when the polymerization of 1b was initiated with equimolar LiHMDS at ?20 °C and continued at ?50 °C, followed by addition of 2 and equimolar LiHMDS at ?10 °C. Spherical aggregates were formed when a solution of poly 1b in THF was dropped on a glass plate and dried at room temperature, although the block copolymer of poly 1b and poly 2 did not afford similar aggregates under the same conditions. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1357–1363, 2010     

基于食饵保护的食饵-捕食捕鱼模型分析(英文)

In this paper,we consider a prey-predator fishery model with prey dispersal in a two-patch environment,one is assumed to be a free fishing zone and the other is a reserved zone where fishing and other extractive activities are prohibited.The existence of possible steady states of the system is discussed.The local and global stability analysis has been carried out.An optimal harvesting policy is given using Pontryagin s maximum principle.     

Cracking in D6ac steel

This paper examines the results of an extensive test program undertaken to study crack growth in D6ac steel and shows that in each case the increment in the crack length per cycle (da/dN) conforms to the Generalised Frost-Dugdale crack growth law. This is found to be true for both constant K_max, constant R ratio load increasing, and compression-compression pre-cracking tests in the L-T, T-L and the S-T directions.     

Theory of Microbial Carbonate Precipitation and Its Application in Restoration of Cement-based Materials Defects

Bacterial induced carbonate mineralization has been demonstrated as a new potential method for restoration of limestones in historic buildings and monuments. We claim here the formation of calcium carbonate was controlled by extracellular polymeric substances (EPS) isolated from Bacillus pasteurii. The process of crystallization nucleation was accelerated in the presence of cells and inhibited in the presence of EPS. The CaCO₃ film deposited on cement paste surface was about 100 µm after 7 d treatment. The results of various restoring methods showed that higher decrease of water absorption of cement paste was gained in brushing application in the presence of agar, which could maintain urease with high activity in long term compared to spraying method. The coefficient of capillary suction of cement paste treated with brushing method was reduced by 90%. Mixed media consisted of sands, urea, Ca²⁺ and concentrated biomass, was injected into artificial cracks of cement paste followed by continual nutrient supplement, and CaCO₃ particles were precipitated gradually between sands particles which were combined with cement matrix. The results showed that the compressive strength of recovered specimens was restored to 84%, which demonstrated that this kind of bio‐restoration method is effective in repairing surface defects of cement‐based materials.     

薄膜层状外延生长的光学原位实时监测方法

综述了几种用于监控薄膜外延生长的光学原位实时监测方法的进展。其中光反射差法／光反射各向异性谱（ＲＤＳ／ＲＡＳ）和ｐ偏振反射谱（ＰＲＳ），表面光吸收（ＳＰＡ），椭偏仪（ＳＥ）等。在外延过程中已观测到了薄膜层状外延周期振荡。     

Existence of Neighboring Feasible Trajectories: Applications to Dynamic Programming for State-Constrained Optimal Control Problems

In this paper, the value function for an optimal control problem with endpoint and state constraints is characterized as the unique lower semicontinuous generalized solution of the Hamilton-Jacobi equation. This is achieved under a constraint qualification (CQ) concerning the interaction of the state and dynamic constraints. The novelty of the results reported here is partly the nature of (CQ) and partly the proof techniques employed, which are based on new estimates of the distance of the set of state trajectories satisfying a state constraint from a given trajectory which violates the constraint.     

碰撞过程的瞬态数字测量

提出了一种对碰撞过程进行瞬态数字测量的方法和仪器装置。它可以用来显示冲击力的时间过程，计算出碰撞过程的冲量从而可以在气轨实验中验证的动量定理。     

A parametric view on the Mangasarian–Fromovitz constraint qualification

The growth of the multipliers, when the parameter approaches such a critical parameter, is characterized by a parametric constraint qualification which is introduced here. It is equivalent to a bound on the growth of the multipliers. Received May 8, 1995 / Revised version received February 12, 1998 Published online February 25, 1999