Asymmetric Synthesis, Antifungal Activity and Molecular Modeling of Iodiconazole Isomers

Iodiconazole is a novel antifungal agent that was developed in its racemic form. In order to investigate the ef- fects of the chiral center on the antifungal activity, R- and S-isomers of iodiconazole were prepared on the basis of the asymmetric Sharpless epoxidation. （S）-Iodiconazole was proved to have better antifungal activity than the （R）- isomer. The binding modes of the two isomers with lanosterol 14~z-demethylase were clarified by molecular dock- ing.     

Synthesis of Optically Active Aromatic Ether Ketone Macrocycles Containing 2,2′-Dimethoxy-1,1′-binaphthyl-6,6′-diyl Moieties

Optically active aromatic ether ketone macrocycles containing 2,2′-dimethoxy-1,1′-binaphthyl-6,6′-diyl moieties were synthesized through electrophilic aromatic substitution reaction and stepwise nucleophilic aromatic substitution reactions. Structures of the resulting macrocycles were confirmed by NMR and matrix assisted laser desorption/ionization time of flight (MALDI-TOF) mass measurements.     

Azobenzene‐Functionalized Metal–Organic Polyhedra for the Optically Responsive Capture and Release of Guest Molecules

Stimuli‐responsive metal–organic polyhedra (srMOPs) functionalized with azobenzene showed UV‐irradiation‐induced isomerization from the insoluble trans‐srMOP to the soluble cis‐srMOP, whereas irradiation with blue light reversed this process. Guest molecules were trapped and released upon cis‐to‐trans and trans‐to‐cis isomerization of the srMOPs, respectively. This study provides a new direction in the ever‐diversifying field of MOPs, while laying the groundwork for a new class of optically responsive materials.     

理论研究电流注入对垂直腔面发射激光器多横模行为的影响

从包含时空变量的速率方程出发,针对弱折射率导引垂直腔面发射激光器(VCSELs),利用空间积分法分析了典型电注入参数对VCSELs多横模行为的影响,在不降低模型准确性的前提下提高了仿真效率。仿真结果表明,注入盘孔径和注入环越小、注入强度越低以及电流扩散越弱时,VCSELs更易实现单横模工作;反之,VCSELs高阶横模开始出现并呈现较强的模式竞争,引发了载流子空间烧孔效应,并导致基模强度降低。进一步得出,在环形注入方式下,高阶模式更容易出现且彼此间的竞争较盘形注入时强。     

Wide viewing optically clear adhesives using PMMA/TiO2 core-shell micro/nanoparticles

Abstract

Optically clear adhesives (OCAs) are widely used in optoelectronic displays because of their high outdoor visibility. Here, we develop new transparent adhesive films with wide-viewing-angle characteristics using poly(methyl methacrylate) (PMMA)/TiO₂ core–shell micro/nanoparticles. TiO₂ nanoparticles are embedded in the shell of PMMA microparticles, forming an organic–inorganic hybrid structure. To examine the optical transmittance of the films in the visible wavelength region, ultraviolet-visible spectroscopy is performed and light diffusion is evaluated. The TiO₂ nanoparticles in the shell of the PMMA microparticles exhibit improved light scattering, and the new functional OCAs are expected to provide wide-viewing-angle characteristics for future flexible displays.     

基于微燃机的空气湿化循环构建与分析

基于同一微燃机,构建了注水回热(RWI)、HAT、部分空气湿化(PHAT)、压气机入口喷雾冷却的HAT(AHAT)循环模型,对各循环的性能进行了模拟分析并对比了效率和比功.结果表明,在可比条件下,空气湿化循环功率和效率较回热循环分别提高40%以上和5个百分点左右.研究结果为微燃机改造为空气湿化循环提供了依据和理论指导.     

High-performance 850 nm vertical-cavity surface-emitting laser in Gigabit Ethernet network

High-performance oxide vertical-cavity surface-emitting (VCSEL) laser is fabricated, and its usefulness is demonstrated as a suitable transmitting light source at 850 nm operating wavelength for Gigabit Ethernet application. Utilization of barrier reduction layers reveals low-threshold current requirement for operation at high modulation bandwidth. The electrical and optical characteristics, measured from the fabricated VCSEL, are simulated for Gigabit Ethernet transmission. Data rates of 1.25 Gbps with a bit error rate of 10⁻¹¹ are achieved by the use of a specific multimode network simulator.     

The Dependence of IRSL Intensity on Radiation Dose for Samples of Chlorides Contained in Feldspars

The intensity of the luminescence generally increases with radiation dose and measurement of these phenomena can be used to characterise the degree of dependence on beta doses. In this study, in order to test whether this is a significant problem on the optically stimulated luminescence (OSL) studies, the radiation dose response of the OSL signal from samples of chlorides contained in feldspars have been investigated by irradiating the samples with beta doses. The infrared-emitting diodes were used with a wavelength of (880±80) nm, and an IRSL (infrared stimulated luminescence) intensity parametres, m, was described and found m = 1±0.03.     

Interaction of multi-raman-processes in miniature optically pumped NH3 fir laser

The principle of Raman gain superposition was introduced to the theory of multi-Raman- processes interaction. Spectral characteristics of Raman lines from miniature NH₃-optically pumped FiR lasers were studied and measured.supported by the National Nature Science Foundation of P.R.C. and the Special Research Foundation of Doctorate Stations of P.R.C.     

注入离子漂移管技术测量原子团簇结构

团簇结构测量是团簇科学研究中的一个重要课题。文章对近几年发展的注入离子漂移管技术进行了详细介绍与分析，该技术是上前测量团簇结构近似程度最高的技术，已在Ｃ，Ｓｉ，Ｇｅ及Ａｌ等原子团簇的结构研究中获得广泛应用，并取得了许多重要结果。