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91.
Wenbing Hu Alexander Buzin Jar‐Shyong Lin Bernhard Wunderlich 《Journal of Polymer Science.Polymer Physics》2003,41(4):403-417
The annealing at 373 K of ultrastrong, gel‐spun polyethylene (PE) has been studied. At this temperature, the fibers show no significant shrinkage. Still, a significant decrease in the mechanical properties is observed. The fibers have been analyzed with differential scanning calorimetry (DSC), temperature‐modulated differential scanning calorimetry (TMDSC), atomic force microscopy (AFM), and small‐angle X‐ray scattering (SAXS). During the annealing, the glass transition of the intermediate phase is exceeded, as shown by DSC. When split for structure analysis by AFM, the annealed fibers undergo plastic deformation around the base fibrils instead of brittle fracture. The quasi‐isothermal TMDSC experiments are compared to the minor structural changes seen with SAXS and AFM. The loss of performance of the PE fibers at 373 K is suggested to be caused by the oriented intermediate phase, and not by major changes in the structure or morphology. The overall metastable, semicrystalline structure is shown by TMDSC to posses local regions that can melt reversibly. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 403–417, 2003 相似文献
92.
The dielectric constant, ε, and the d.c. conductivity, σ, were measured along the a-, b- and c-axes of (NH4)2ZnCl4 (AZC) crystal in the 300-450 K temperature range. Crystals of AZC grown from aqueous solutions containing excess of ZnCl2 were used. The value of the dielectric permittivity of AZC is extremely small compared to other ferroelectric crystals. Pronounced broad or step-like peaks at the phase transition temperatures were detected along the a- and b-axes, while ε along the c-axis is temperature independent up to the end of the measuring range. Reciprocal of the dielectric permittivity in the range of the commensurate to incommensurate phase transition obeys a relation similar to the Curie-Weiss law that is valid for second order ferroelectric/paraelectric phase transitions. The constants of the proposed relationship applied to the cooling run are given. The J-E characteristics along the three crystallographic axes were measured in the normal, incommensurate, commensurate and antiferroelectric phases. Hence, the type of conduction mechanism has been estimated. Parameters of Poole-Frenkel and Richardson-Schottky types of conduction mechanism have been determined. The effect of applied electric field on the conductivity measurement was also tested. Conductivity anomalies with different character were observed at the phase transition temperatures. The lnσ−1000/T dependence revealed thermal activation energy of conduction along the a-, b- and c-axes with different values in different phases of AZC. 相似文献
93.
V.B. Nalbandyan 《Journal of Physics and Chemistry of Solids》2004,65(6):1201
The irreproducibility of electrical properties of Na0.88Li0.12NbO3 solid solution on thermal cycling reported by M.A.L. Nobre and S. Lanfredi is explained by gradual decomposition of the supersaturated solid solution below ca. 800 °C. 相似文献
94.
Deependra Das Mulmi Nozomi Kamiya Yutaka Murakami 《Journal of Physics and Chemistry of Solids》2004,65(6):1181-1185
Nb-doped anatase TiO2 single crystal has been grown by chemical vapour transport method. Raman spectra shows that the obtained crystal with Nb of 0.08 wt% has typical anatase structure. An absorption band was observed at around 2.2 eV, which seems to be due to the d-d transition in the conduction band. The electron paramagnetic resonance and electric resistivity measurements show that the doped niobium makes quite shallow donor level whose orbital is dxy-like centered at the titanium position of anatase. 相似文献
95.
Electron paramagnetic resonance (EPR) investigations has been carried out on the new family of molybdenum doped vanadium sesquioxides (V1−xMox)2−δO3. The oxidation effects were monitored from the rate of paramagnetic V4+ created when the sample is exposed to the air. The effects of the oxidation time, sample temperature, and annealing at 1000 °C under a diluted hydrogen atmosphere on the EPR signal features are analyzed. The V4+ concentration in the oxidized samples is determined and the relaxation effects driven by the conduction electrons are pointed out from the thermal behaviour of the EPR line features. EPR spectra of all the oxidized samples also reveal a small ferromagnetic contribution strongly correlated with the V4+ content. 相似文献
96.
97.
Data on the proteinase complex from Carica papaya latex were reviewed. The properties and applications of the domestic preparation cucumazyme and known medicinal preparations based on papaya proteinases (caripazyme, lecozyme, lecopain) were compared. 相似文献
98.
As predicted by Haldane, spin, S=1 one-dimensional (1D) Heisenberg antiferromagnet (HAF) has an energy gap between the singlet ground state and first excited triplet. On application of magnetic field, the triplet state Zeeman splits and the energy of one of the triplet state becomes zero at a critical field, Hc. Above Hc the system recovers magnetism. Then, we expect that a quasi-1D HAF will show a magnetic long-range ordering (LRO) at low temperatures due to the inter-chain coupling. This field-induced LRO has not been observed before due to complication of the crystal structure in the materials studied so far and/or technical difficulty.From a heat capacity measurement on a single crystal of an S=1 quasi-Q1D HAF, Ni(C5H14N2)2N3(PF6), we found an anomaly at a temperature in finite fields indicating a field-induced phase transition. A magnetic LRO is confirmed by a neutron diffraction measurement on the same sample. The temperature versus magnetic field phase diagram of this compound is constructed and discussed. 相似文献
99.
本文利用比较原理以及一种特殊变换研究了一类非线性退化方程的混合问题,得到了这类复杂问题解的渐进性质。 相似文献
100.
用气压浸渗工艺制备了体积分数40%~50%Al2O3颗粒增强纯铝基复合材料,使用了4种不同尺寸的Al2O3颗粒,其平均粒径分别为5μm、10μm、30μm和60μm.测定了这些复合材料的静、动态压缩性能,并通过材料压缩前后密度变化的测量定量表征了材料的累计损伤,结果表明,与基体材料相似,这些复合材料表现出明显的应变率敏感性;当增强颗粒平均粒径小于60μm时,材料的累计损伤基本与应变率无关,而主要取决于材料的应变.材料中颗粒的破裂主要是由颗粒间的相互作用引起的.较小尺寸颗粒增强的复合材料具有较高的流动应力和较小的累计损伤,并随着颗粒体积分数的增加,材料的流动应力和损伤率都相应增加. 相似文献